Articles:
(E)-2-methyl-2-butenal
Notes:
None found
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BOC Sciences Best of Chemicals Supplier Quality supplier of research chemicals and biochemicals including inhibitors, building blocks, GMP Products, impurities and metabolites, APIs for Veterinary, Natural Compounds, ADCs, Stem Cell Molecule and chiral compounds. BOC Sciences provides a wide range of services to support the pharmaceutical industry through all stages of drug discovery including Custom Synthesis of those chemicals that are not in stock, Isotope Labeling Service, Chiral Synthesis and Resolution, Bioconjugation, PEGylation services, analytical services. BOC Sciences is a brand of BOCSCI Inc. We leverage our wide spectrum of business in the fields of development, manufacturing, marketing, and distribution to help you make best-informed decisions tailored to your evolving needs for premium chemicals. Our complete suite of CRO services spans the entire molecule development pipeline including contract research for target identification, building blocks, compound synthesis, biochemical and cellular analysis, preclinical animal tests, and clinical studies. Email: Marketing US Email: Marketing Email: Sales US Email: Sales Voice: 1-631-485-4226 Fax: 1-631-614-7828 US Voice: 1-631-485-4226 US Fax: 1-631-614-7828 Europe 44-203-286-1088 Facebook Twitter Linkedin Blog Get the App! Product(s): 497-03-0 Tiglic aldehyde 95%
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Chemical sources Association Inc Exchange of knowledge Need This Item for Flavor? You can contact the Chemical Sources Association. Events Links Product(s):
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Penta International Corporation Chemistry innovation At Penta, our products and services help businesses do business better. For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes. US Email: Technical Services US Email: Sales US Voice: (973) 740-2300 US Fax: (973) 740-1839 Product(s): 13-30305 2-METHYL-2-BUTENAL
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Synerzine, Inc. Innovation. Customization. Aroma Ingredients. Synerzine is a leading supplier of flavor and fragrance ingredients. Synerzine expresses what we have grown to embody as an organization - the synergy and connection between raw ingredients, science, technology, and the final product. Our experienced team is passionate about bringing our customers high-quality innovative ingredients that they can trust. Building upon our 44 year history, the Synerzine team provides customers around the globe with convenient access to over 1200 high-quality aroma ingredients. We actively engage with customers to add a wide array of new products and services on a regular basis. Our aim is to delight every customer with our exceptional services, large product selection, customization and the highest quality and safety standards. We provide our customers with true value designed to help them bring their products to market faster. US Email: Customer Service US Email: Sales US Voice: (404) 524-6744 US Fax: (404) 577-1651 Inquiry Products List: View Product(s): W1321 2-Methyl-2-butenal
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TCI AMERICA Moving Your Chemistry Forward We continuously strive to advance our technology. With East & West Coast distribution centers, count on TCI to deliver products quickly and reliably. Over 30,000 Reagents available today in benchtop to bulk quantities. We also offer custom synthesis solutions. Sign up for a TCI account today for fast and free shipping! Tokyo Chemical Industry Co., Ltd. (TCI) is a leading worldwide manufacturer of specialty organic chemicals founded in 1946. TCI provides organic laboratory chemicals as well as pharmaceutical, cosmetic and functional materials. More than 70 years of synthesis experience and multi-purpose plants enable TCI to offer more than 30,000 products as well as custom synthesis. US Email: Sales Email: Technical Support Voice: 1-800-423-8616 Fax: 1- 888-520-1075 Facebook Twitter Instagram Linkedin Product(s): T1003 trans-2-Methyl-2-butenal >95.0%(GC) SDS
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WholeChem, LLC Connecting Innovators To the Building Blocks Of the Universe Custom manufacturer and distributor of specialty ingredients. We make global local. SQF-Certified Supplier We owe our success to our integrity, our dedication to the industry, and our commitment to our clients. We invite your inquiries regarding our current product list and any other products you may be having trouble sourcing. Email: Info Email: Orders Voice: +1 (262) 995.8668 Certification Our Services Products List: View Product(s): Tiglic Aldehyde
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| CAS Number: | 497-03-0 |  3D/inchi
|
| ECHA EINECS - REACH Pre-Reg: | 207-833-0 | |
| FDA UNII: | 27ZVE2K81C | |
| Nikkaji Web: | J102.093E | |
| Beilstein Number: | 1698207 | |
| MDL: | MFCD00006977 | |
| XlogP3-AA: | 0.90 (est) | |
| Molecular Weight: | 84.11796000 | |
| Formula: | C5 H8 O | |
| NMR Predictor: | Predict (works with chrome, Edge or firefox) | |
| EFSA/JECFA Comments: | Mainly E-isomer (> 95%). Secondary components: acetic acid (up to 0.1%), tiglic acid (up to 0.5%) and paraldehyde (up to 1%) (i.e. 2,4,6-trimethyl-1,3,5-trioxane, which is a condensation product – cyclic ether) | |
Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
| Google Scholar: | Search |
| Google Books: | Search |
| Google Scholar: with word "volatile" | Search |
| Google Scholar: with word "flavor" | Search |
| Google Scholar: with word "odor" | Search |
| Perfumer and Flavorist: | Search |
| Google Patents: | Search |
| US Patents: | Search |
| EU Patents: | Search |
| Pubchem Patents: | Search |
| PubMed: | Search |
| NCBI: | Search |
| DG SANTE Food Flavourings: | 05.095 (E)-2-methylcrotonaldehyde |
| FDA Mainterm (SATF): | 497-03-0 ; 2-METHYL-2-BUTENAL |
Physical Properties:
| Appearance: | colorless clear liquid (est) |
| Assay: | 95.00 to 100.00 % |
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.86800 to 0.87300 @ 20.00 °C. |
| Pounds per Gallon - (est).: | 7.231 to 7.273 |
| Refractive Index: | 1.44500 to 1.45000 @ 20.00 °C. |
| Boiling Point: | 117.00 to 118.00 °C. @ 760.00 mm Hg |
| Acid Value: | 3.00 max. KOH/g |
| Vapor Pressure: | 17.107000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 70.00 °F. TCC ( 21.11 °C. ) |
| logP (o/w): | 1.065 (est) |
| Soluble in: | |
| alcohol | |
| water, 2.50E+04 mg/L @ 25 °C (exp) | |
| Insoluble in: | |
| water | |
| Similar Items: note | |
| tiglaldehyde | |
| (Z)-tiglaldehyde | |
Organoleptic Properties:
| Odor Description: at 0.10 % in dipropylene glycol. | strong green fruit |
| Odor and/or flavor descriptions from others (if found). | |
Cosmetic Information:
| None found |
Suppliers:
| BOC Sciences |
| For experimental / research use only. |
| Tiglic aldehyde 95% |
| Parchem |
| (E)-tiglaldehyde |
| Penta International |
| 2-METHYL-2-BUTENAL |
| Santa Cruz Biotechnology |
| For experimental / research use only. |
| Tiglic aldehyde |
| Sigma-Aldrich: Aldrich |
| For experimental / research use only. |
| Tiglic aldehyde ≥96% |
| Synerzine |
| 2-Methyl-2-butenal |
| TCI AMERICA |
| For experimental / research use only. |
| trans-2-Methyl-2-butenal >95.0%(GC) |
| WholeChem |
| Tiglic Aldehyde |
| Chemical Sources Association |
| Need This Item for Flavor/Food?: You can contact the CSA |
Safety Information:
| Preferred SDS: View | |
| European information : | |
| Most important hazard(s): | |
| Xi - Irritant | |
|
R 11 - Highly flammable. R 36/37/38 - Irritating to eyes, respiratory system, and skin. S 02 - Keep out of the reach of children. S 16 - Keep away from sources of ignition - No Smoking. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 - Wear suitable gloves and eye/face protection. | |
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| None found. | |
| GHS Label elements, including precautionary statements | |
| Pictogram | |
| Hazard statement(s) | |
| None found. | |
| Precautionary statement(s) | |
| None found. | |
| Oral/Parenteral Toxicity: | |
| Not determined | |
| Dermal Toxicity: | |
| Not determined | |
| Inhalation Toxicity: | |
| Not determined | |
Safety in Use Information:
| Category: | flavor and fragrance agents | ||
| RIFM Fragrance Material Safety Assessment: Search | |||
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
| Recommendation for (E)-tiglaldehyde usage levels up to: | |||
| 0.0500 % in the fragrance concentrate. | |||
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.24 (μg/capita/day) | ||
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 0.20 (μg/capita/day) | ||
| Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 1700 (μg/person/day) | ||
| Threshold of Concern: | 1800 (μg/person/day) | ||
| Structure Class: | I | ||
| Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). | |||
| Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. | |||
| average usage mg/kg | maximum usage mg/kg | ||
| Dairy products, excluding products of category 02.0 (01.0): | 5.03000 | 11.86000 | |
| Fats and oils, and fat emulsions (type water-in-oil) (02.0): | 0.50000 | 4.00000 | |
| Edible ices, including sherbet and sorbet (03.0): | 0.50000 | 2.75000 | |
| Processed fruit (04.1): | - | - | |
| Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | 4.78000 | 5.00000 | |
| Confectionery (05.0): | 5.00000 | 14.22000 | |
| Chewing gum (05.0): | 2.20000 | 9.56000 | |
| Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 3.79000 | 11.40000 | |
| Bakery wares (07.0): | 6.20000 | 17.17000 | |
| Meat and meat products, including poultry and game (08.0): | 0.79000 | 3.50000 | |
| Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | 0.50000 | 1.75000 | |
| Eggs and egg products (10.0): | 0.01000 | 3.00000 | |
| Sweeteners, including honey (11.0): | 0.51000 | 4.38000 | |
| Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 1.75000 | 5.00000 | |
| Foodstuffs intended for particular nutritional uses (13.0): | 0.01000 | 5.01000 | |
| Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | 2.00000 | 4.43000 | |
| Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 1.00000 | 2.00000 | |
| Ready-to-eat savouries (15.0): | 2.00000 | 3.00000 | |
| Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | 0.50000 | 0.50000 | |
Safety References:
| European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): | |
| Flavouring Group Evaluation 201: 2-Alkylated aliphatic acyclic alpha,beta-unsaturated aldehydes and precursors with or without additional double bonds from chemical subgroup 1.1.2 of FGE.19[1] View page or View pdf | |
| Scientific Opinion on Flavouring Group Evaluation 201 Revision 1 (FGE.201Rev1): 2-Alkylated, aliphatic, acyclic alpha,beta-unsaturated aldehydes and precursors, with or without additional double-bonds, from chemical subgroup 1.1.2 of FGE.19. View page or View pdf | |
| Scientific Opinion on Flavouring Group Evaluation 201 Revision 2 (FGE.201Rev2): 2-alkylated, aliphatic, acyclic alpha,beta-unsaturated aldehydes and precursors, with or without additional double-bonds, from chemical subgroup 1.1.2 of FGE.19 View page or View pdf | |
| Scientific Opinion on Flavouring Group Evaluation 72, Revision 2 (FGE.72Rev2): consideration of aliphatic, branched-chain saturated and unsaturated alcohols, aldehydes, acids and related esters evaluated by JECFA (61st, 68th and 69th meetings) and structurally related to flavouring substances in FGE.05Rev3 View page or View pdf | |
| EPI System: | View |
| Chemical Carcinogenesis Research Information System: | Search |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA Substance Registry Services (TSCA): | 497-03-0 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 5321950 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WISER: | UN 1989 |
| WGK Germany: | 3 |
| (E)-2-methylbut-2-enal | |
| Chemidplus: | 0000497030 |
References:
| (E)-2-methylbut-2-enal | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 497-03-0 |
| Pubchem (cid): | 5321950 |
| Pubchem (sid): | 134977393 |
| Pherobase: | View |
Other Information:
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| FDA Substances Added to Food (formerly EAFUS): | View |
| CHEMBL: | View |
| HMDB (The Human Metabolome Database): | HMDB31512 |
| Export Tariff Code: | 2912.19.5000 |
| Typical G.C. | |
| VCF-Online: | VCF Volatile Compounds in Food |
| ChemSpider: | View |
Potential Blenders and core components note
Potential Uses:
| almond | FR | |
| cheese | FL | |
| cherry | FR | |
| chicken | FL | |
| coffee | FR | |
| fruit tropical fruit | FL | |
| grape | FR | |
| green | FR | |
| tomato | FL | |
| vanilla | FR |
Occurrence (nature, food, other): note
| allium cepa bulb Search Trop Picture | |
| hyacinthus orientalis absolute @ 0.01% Data GC Search Trop Picture | |
| lavender oil spike spain @ 0.002% Data GC Search Trop Picture |
Synonyms:
| but-2-enal, (E)-2-methyl- | |
| 2- | butenal, 2-methyl-, (2E)- |
| 2- | butenal, 2-methyl-, (E)- |
| crotonaldehyde, 2-methyl-, (E)- | |
| (E)-alpha,beta- | dimethyl acrolein |
| trans-2,3- | dimethyl acrolein |
| trans-alpha,beta- | dimethyl acrolein |
| (E)-2,3- | dimethylacrolein |
| trans-2,3- | dimethylacrolein |
| 2- | methyl (E)-2-butenal |
| (E)-alpha- | methyl crotonaldehyde |
| trans-2- | methyl crotonaldehyde |
| trans-alpha- | methyl crotonaldehyde |
| (2E)-2- | methyl-2-butenal |
| (E)- | methyl-2-butenal |
| (E)-2- | methyl-2-butenal |
| trans- | methyl-2-butenal |
| trans-2- | methyl-2-butenal |
| 2- | methyl-2-butenal, (E)- |
| 2- | methyl-2-butenal, trans- |
| (E)-2- | methyl-but-2-enal |
| 2- | methylbut-2-en-1-al, (E)- |
| (2E)-2- | methylbut-2-enal |
| (E)-2- | methylbut-2-enal |
| trans-2- | methylbut-2-enal |
| (E)-2- | methylcrotonaldehyde |
| 2- | methylcrotonaldehyde, (E)- |
| tigaldehyde, trans- | |
| trans- | tiglaldehyde |
| trans- | tiglic aldehyde |