Articles:
| None found yet. Try the PubMed Search. |
L-menthylmethylether
Notes:
Used as a food additive [EAFUS]
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Chemical sources Association Inc Exchange of knowledge Need This Item for Flavor? You can contact the Chemical Sources Association. Events Links Product(s):
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| Fragrance Demo Formulas | ||
| CAS Number: | 1565-76-0 |  3D/inchi
|
| ECHA EINECS - REACH Pre-Reg: | 216-365-6 | |
| FDA UNII: | 89677W03FF | |
| Nikkaji Web: | J819.525K | |
| XlogP3-AA: | 3.60 (est) | |
| Molecular Weight: | 170.29554000 | |
| Formula: | C11 H22 O | |
| NMR Predictor: | Predict (works with chrome, Edge or firefox) | |
Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
| Google Scholar: | Search |
| Google Books: | Search |
| Google Scholar: with word "volatile" | Search |
| Google Scholar: with word "flavor" | Search |
| Google Scholar: with word "odor" | Search |
| Perfumer and Flavorist: | Search |
| Google Patents: | Search |
| US Patents: | Search |
| EU Patents: | Search |
| Pubchem Patents: | Search |
| PubMed: | Search |
| NCBI: | Search |
| JECFA Food Flavoring: | 1415 L-menthyl methyl ether |
| DG SANTE Food Flavourings: | 16.088 L-menthylmethylether |
| FEMA Number: | 4054 L-menthyl methyl ether |
| FDA: | No longer provide for the use of these seven synthetic flavoring substances |
| FDA Mainterm (SATF): | 1565-76-0 ; 1-MENTHYL METHYL ETHER |
Physical Properties:
| Appearance: | colorless clear liquid (est) |
| Assay: | 99.00 to 100.00 % |
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.85600 to 0.86200 @ 25.00 °C. |
| Pounds per Gallon - (est).: | 7.123 to 7.173 |
| Refractive Index: | 1.44100 to 1.44700 @ 20.00 °C. |
| Boiling Point: | 81.00 °C. @ 10.50 mm Hg |
| Boiling Point: | 191.00 to 192.00 °C. @ 760.00 mm Hg |
| Vapor Pressure: | 0.713000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 142.00 °F. TCC ( 61.11 °C. ) |
| logP (o/w): | 3.928 (est) |
| Soluble in: | |
| alcohol | |
| water, 20.08 mg/L @ 25 °C (est) | |
| Insoluble in: | |
| water | |
Organoleptic Properties:
| Odor Description: at 100.00 %. | minty |
| Odor and/or flavor descriptions from others (if found). | |
Cosmetic Information:
| None found |
Suppliers:
| Axsyn |
| For experimental / research use only. |
| Cyclohexane,2-methoxy-4-methyl-1-(1-methylethyl)-, (1S,2R,4R)- |
| Parchem |
| laevo-menthyl methyl ether |
| Chemical Sources Association |
| Need This Item for Flavor/Food?: You can contact the CSA |
Safety Information:
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| None found. | |
| GHS Label elements, including precautionary statements | |
| Pictogram | |
| Hazard statement(s) | |
| None found. | |
| Precautionary statement(s) | |
| None found. | |
| Oral/Parenteral Toxicity: | |
| Not determined | |
| Dermal Toxicity: | |
| Not determined | |
| Inhalation Toxicity: | |
| Not determined | |
Safety in Use Information:
| Category: | flavor and fragrance agents | ||
| RIFM Fragrance Material Safety Assessment: Search | |||
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
| Recommendation for laevo-menthyl methyl ether usage levels up to: | |||
| 2.0000 % in the fragrance concentrate. | |||
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 1.20 (μg/capita/day) | ||
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 53.00 (μg/capita/day) | ||
| Structure Class: | III | ||
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). | |||
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library | |||
| publication number: 21 | |||
| Click here to view publication 21 | |||
| average usual ppm | average maximum ppm | ||
| baked goods: | 50.00000 | 250.00000 | |
| beverages(nonalcoholic): | 1.00000 | 10.00000 | |
| beverages(alcoholic): | 4.00000 | 20.00000 | |
| breakfast cereal: | 1.00000 | 10.00000 | |
| cheese: | - | - | |
| chewing gum: | 500.00000 | 2000.00000 | |
| condiments / relishes: | - | - | |
| confectionery froastings: | 2.00000 | 20.00000 | |
| egg products: | 2.00000 | 20.00000 | |
| fats / oils: | 2.00000 | 20.00000 | |
| fish products: | - | - | |
| frozen dairy: | 20.00000 | 100.00000 | |
| fruit ices: | 10.00000 | 50.00000 | |
| gelatins / puddings: | 10.00000 | 50.00000 | |
| granulated sugar: | 10.00000 | 50.00000 | |
| gravies: | - | - | |
| hard candy: | 10.00000 | 50.00000 | |
| imitation dairy: | 5.00000 | 10.00000 | |
| instant coffee / tea: | 2.00000 | 10.00000 | |
| jams / jellies: | 10.00000 | 50.00000 | |
| meat products: | - | - | |
| milk products: | 2.00000 | 10.00000 | |
| nut products: | - | - | |
| other grains: | - | - | |
| poultry: | - | - | |
| processed fruits: | 2.00000 | 10.00000 | |
| processed vegetables: | - | - | |
| reconstituted vegetables: | - | - | |
| seasonings / flavors: | 1000.00000 | 30000.00000 | |
| snack foods: | - | - | |
| soft candy: | 3.00000 | 50.00000 | |
| soups: | 4.00000 | 40.00000 | |
| sugar substitutes: | 3.00000 | 50.00000 | |
| sweet sauces: | - | - | |
Safety References:
| European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): | |
| Scientific Opinion on Flavouring Group Evaluation 59, Revision 1 (FGE.59Rev1): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting and 63rd meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 Rev2 (2010) View page or View pdf | |
| EPI System: | View |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA Substance Registry Services (TSCA): | 1565-76-0 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 102648 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WGK Germany: | 2 |
| 2-methoxy-4-methyl-1-propan-2-ylcyclohexane | |
| Chemidplus: | 0001565760 |
References:
| 2-methoxy-4-methyl-1-propan-2-ylcyclohexane | |
| NIST Chemistry WebBook: | Search Inchi |
| Pubchem (cid): | 102648 |
| Pubchem (sid): | 135059826 |
Other Information:
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| FDA Substances Added to Food (formerly EAFUS): | View |
| HMDB (The Human Metabolome Database): | HMDB32371 |
| FooDB: | FDB009785 |
| ChemSpider: | View |
Potential Blenders and core components note
| None Found | ||
Potential Uses:
| cornmint | FL/FR | |
| herbal | FL | |
| mint | FL | |
| peppermint | FL |
Occurrence (nature, food, other): note
| not found in nature |
Synonyms:
| L- | menthyl methyl ether |
| L- | menthylmethylether |
| laevo- | menthylmethylether |
| (1S,2R,4R)2- | methoxy-4-methyl-1-(1-methyl ethyl) cyclohexane |
| 2- | methoxy-4-methyl-1-(propan-2-yl)cyclohexane |
| 2- | methoxy-4-methyl-1-propan-2-ylcyclohexane |
| 1-iso | propyl-2-methoxy-4-methylcyclohexane |
| 2-iso | propyl-5-methyl cyclohexyl methyl ether |
| 2-iso | propyl-5-methylcyclohexyl methyl ether |
| (1R-(1alpha,2beta,5alpha))-1-(iso | propyl)-2-methoxy-4-methyl cyclohexane |