Category: fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless to pale yellow clear liquid (est) |
Assay: | 98.00 to 100.00 % sum of isomers
|
Food Chemicals Codex Listed: | No |
Boiling Point: | 308.80 °C. @ 760.00 mm Hg (est)
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Vapor Pressure: | 0.001000 mmHg @ 25.00 °C. (est) |
Flash Point: | 284.00 °F. TCC ( 140.00 °C. )
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logP (o/w): | 4.007 (est) |
Soluble in: |
| alcohol | | water, 4.73 mg/L @ 25 °C (est) |
Stability: |
| alcoholic - good | | antiperspirant spray - moderate | | APC (pH = 10) - good | | candles - untested | | damp fabric - moderate | | dry fabric - poor | | liquid bleach - poor | | pH = 2 - good | | powder detergent - moderate | | powder detergent + activator - moderate | | soap - good | | toiletries - good |
Organoleptic Properties:
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Odor Type: green |
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Odor Strength: | medium |
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Substantivity: | 32 hour(s) at 100.00 % |
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| floral green milky privet cortex woody |
Odor Description: at 100.00 %. | floral green milky privet cortex woody Luebke, William tgsc, (1985) |
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Odor and/or flavor descriptions from others (if found). |
|
Givaudan |
Glycolierral |
Odor Description: | Soft Floral, Green, Milky, Ivy leaves, Woody Glycolierral offers a powerful yet soft, green, milky nuance when used as a green top note modifier. |
|
Moellhausen |
GLYCOLIERRAL |
Odor Description: | fresh, herbaceous, soft floral-green, reminiscent of ivy leaves, woody |
Taste Description: | fresh, herbaceous, somewhat floral, slightly woody |
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|
Cosmetic Information:
Suppliers:
BOC Sciences |
For experimental / research use only. |
1,3-Dioxolane,2-[5-methyl-7-(1-methylethyl)bicyclo[2.2.2]oct-5-en-2-yl]- 95%
|
Givaudan |
Glycolierral
Odor: Soft Floral, Green, Milky, Ivy leaves, Woody Use: Glycolierral offers a powerful yet soft, green, milky nuance when used as a green top note modifier. |
Global Essence |
Glycolierral
|
Indukern F&F |
GLYCOLIERRAL
Odor: FLORAL, FRUITY, GREEN |
Moellhausen |
GLYCOLIERRAL
Odor: fresh, herbaceous, soft floral-green, reminiscent of ivy leaves, woody Flavor: fresh, herbaceous, somewhat floral, slightly woody |
Penta International |
ETHYL-2,3,6,6-TETRAMETHYL-2-CYCLOHEXENECARBOXYLATE (MIXED ISOMERS
|
Vigon International |
Glycolierral
Odor: Soft Floral, Green, Milky, Ivy leaves, Woody |
Safety Information:
European information : |
Most important hazard(s): | Xi - Irritant |
R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.
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Hazards identification |
|
Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
oral-rat LD50 8000 mg/kg
|
Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
|
Safety in Use Information:
Safety References:
References:
| 2-(2-methyl-5-propan-2-yl-7-bicyclo[2.2.2]oct-2-enyl)-1,3-dioxolane |
NIST Chemistry WebBook: | Search Inchi |
Canada Domestic Sub. List: | 68901-32-6 |
Pubchem (cid): | 111418 |
Pubchem (sid): | 135068141 |
| 2-(2-methyl-5-propan-2-yl-8-bicyclo[2.2.2]oct-2-enyl)-1,3-dioxolane |
NIST Chemistry WebBook: | Search Inchi |
Canada Domestic Sub. List: | 94087-23-7 |
Pubchem (cid): | 44152860 |
Pubchem (sid): | 3796315 |
Other Information:
Potential Blenders and core components note
|
For Odor |
aldehydic |
iso | butyraldehyde | FL/FR |
| citrus carbaldehyde | FR |
6,7,8- | decen-1-ol | FR |
| dodecanal (aldehyde C-12 lauric) | FL/FR |
3- | methyl-4-hexyl oxybutyraldehyde | FR |
animal |
para- | cresyl caprylate | FL/FR |
para- | cresyl isobutyrate | FL/FR |
para- | cresyl phenyl acetate | FL/FR |
anise |
sweet | fennel seed oil | FL/FR |
anisic |
| ocimum basilicum herb oil | FL/FR |
balsamic |
iso | amyl benzoate | FL/FR |
| benzyl salicylate | FL/FR |
| cinnamyl alcohol | FL/FR |
| cinnamyl formate | FL/FR |
| ethyl cinnamate | FL/FR |
3- | phenyl propyl alcohol | FL/FR |
berry |
| raspberry ketone methyl ether | FL/FR |
citrus |
| bergamot oil | FL/FR |
| bergamot oil bergaptene reduced italy | FL/FR |
| bergamot oil turkey | FL/FR |
| citral dimethyl acetal | FL/FR |
| citrus floral green fragrance | FR |
| dihydromyrcenol | FL/FR |
2,4- | dimethyl-3-cyclohexene-1-methanyl acetate | FR |
| grapefruit pentanol | FR |
| mandarin oil (citrus reticulata var. ponkan) | FL/FR |
| methyl heptenone | FL/FR |
| nonanal dimethyl acetal | FL/FR |
blood | orange oil italy | FL/FR |
(E)-2- | tetradecenal | FL/FR |
2- | tetradecenal | FL/FR |
| tetrahydromyrcenol | FR |
fatty |
2- | decenal | FL/FR |
floral |
| acetaldehyde dibutyl acetal | FL/FR |
| amyl benzoate | FL/FR |
alpha- | amyl cinnamaldehyde | FL/FR |
| amyl salicylate | FL/FR |
iso | amyl salicylate | FL/FR |
| anisyl propanal / methyl anthranilate schiff's base | FR |
| benzyl acetate | FL/FR |
| benzyl alcohol | FL/FR |
| benzyl isobutyrate | FL/FR |
| bois de rose oil brazil | FL/FR |
| boronia concrete | FL/FR |
alpha- | butyl cinnamaldehyde | FL/FR |
iso | butyl salicylate | FL/FR |
| citronellol | FL/FR |
| citronellyl acetate | FL/FR |
| citronellyl propionate | FL/FR |
| coriander seed oil | FL/FR |
| coriander seed oil CO2 extract | FL/FR |
para- | cresyl acetate | FL/FR |
| cumin carbinol | FR |
| cyclamen aldehyde | FL/FR |
| cyclohexyl ethyl alcohol | FL/FR |
| dictamnus hispanicus oil | FR |
| dihydrocarvyl acetate | FL/FR |
(±)-2,3- | dihydrofarnesol | FL/FR |
| dihydroisojasmonate methyl ester | FR |
| dihydrojasmone | FL/FR |
| dimethyl anthranilate | FL/FR |
| dimethyl benzyl carbinol | FL/FR |
| dimethyl benzyl carbinyl butyrate | FL/FR |
6,8- | dimethyl-2-nonanol | FR |
| ethyl phenoxyacetate | FR |
| farnesol | FL/FR |
| farnesyl acetate | FL/FR |
| floral butanal | FR |
| floral pyranol | FR |
| floral undecenone | FR |
| gardenia absolute | FR |
| gardenia acetal | FR |
| gardenia concrete | FR |
| geraniol | FL/FR |
| geranium oil | FL/FR |
| geranium oil africa | FL/FR |
| geranyl acetate | FL/FR |
| geranyl acetone | FL/FR |
| geranyl formate | FL/FR |
| heliotropyl acetone | FL/FR |
(Z)-4- | hepten-2-yl salicylate | FR |
(Z)-3- | hexen-1-yl salicylate | FL/FR |
alpha- | hexyl cinnamaldehyde | FL/FR |
| hexyl lactate | FL/FR |
| hyacinth ether | FR |
| hyacinth oil | FR |
| hydrangea fragrance | FR |
| hydroxycitronellal diethyl acetal | FL/FR |
| hydroxycitronellal propylene glycol acetal | FL/FR |
| jasmin cyclopentanol | FR |
| jonquil absolute | FR |
| leerall | FR |
| lilac absolute | FR |
| lily fragrance | FR |
| lily propanol | FR |
laevo- | linalool | FL/FR |
| linalool | FL/FR |
| linalool oxide | FL/FR |
| linalyl phenyl acetate | FL/FR |
| lotus fragrance | FR |
| magnolia indene | FR |
(2- | methoxy-1-methyl propyl) benzene | FR |
(3- | methoxy-2-methyl propyl) benzene | FR |
1-(2- | methyl allyl oxy)-2-methyl butane | FR |
| methyl dihydrojasmonate | FL/FR |
| mimosa absolute | FL/FR |
| mimosa absolute france | FL/FR |
| mimosa absolute india | FL/FR |
| muguet dienal | FR |
| muguet octadienol | FR |
| nerol | FL/FR |
| neroli oil CO2 extract | FL/FR |
(E)- | nerolidol | FL/FR |
| nerolidol | FL/FR |
| neryl acetate | FL/FR |
| ocean propanal | FL/FR |
| ocean propanal / methyl anthranilate schiff's base | FR |
| orange leaf absolute | FL/FR |
bitter | orangeflower absolute tunisia | FL/FR |
| orchid specialty | FR |
| orris pyridine 25% IPM | FR |
| papaya isobutyrate | FL/FR |
| peony alcohol | FR |
| petitgrain oil paraguay | FL/FR |
| phenethyl acetate | FL/FR |
| phenethyl propionate | FL/FR |
| phenyl acetaldehyde dicitronellyl acetal | FR |
| phenyl acetaldehyde diisobutyl acetal | FL/FR |
2- | phenyl propionaldehyde ethylene glycol acetal | FR |
| rhodinol | FL/FR |
| rhodinyl formate | FL/FR |
| rose butanoate | FL/FR |
laevo- | rose oxide | FL/FR |
(Z)- | rose oxide | FL/FR |
| rose pyran | FR |
| styralyl formate | FL/FR |
| sweet pea absolute | FR |
| terpinyl isobutyrate | FL/FR |
| tetrahydrolinalool | FL/FR |
5- | tricyclodecenyl acetate | FR |
| tuberose absolute (from pommade) | FL/FR |
| verdyl acetate | FR |
| violet methyl carbonate | FR |
| ylang ylang flower oil | FL/FR |
| ylang ylang flower oil III | FL/FR |
fresh |
3-(3- | propen-2-yl phenyl) butanal | FR |
fruity |
| allyl amyl glycolate | FR |
| allyl cyclohexyl propionate | FL/FR |
| benzyl methyl ether | FL/FR |
| benzyl propionate | FL/FR |
| citronellyl isobutyrate | FL/FR |
| cyclohexyl crotonate | FR |
gamma- | decalactone | FL/FR |
| dimethyl succinate | FL/FR |
| ethyl methyl-para-tolyl glycidate | FL/FR |
| green acetate | FR |
| peach pivalate | FR |
| strawberry glycidate 1 (aldehyde C-16 (so-called)) | FL/FR |
| tropical ionone | FL/FR |
gamma- | undecalactone (aldehyde C-14 (so-called)) | FL/FR |
fungal |
| jasmin nonane | FR |
green |
iso | amyl 3-(2-furan) propionate | FL/FR |
iso | butyl benzyl carbinol | FL/FR |
| chrysanthemum oxide | FL/FR |
| cortex pyridine | FL/FR |
para- | dimethyl hydroquinone | FL/FR |
3,7- | dimethyl-6-octenoic acid | FL/FR |
| diphenyl oxide | FL/FR |
| earthy acetal | FL/FR |
| flower hexene | FR |
| galbanum oil | FL/FR |
| green cyclopropionate | FR |
(Z)-3- | hexen-1-ol | FL/FR |
(Z)-3- | hexen-1-yl acetate | FL/FR |
(Z)-3- | hexen-1-yl acetoacetate | FL/FR |
(Z)-3- | hexen-1-yl angelate | FR |
(Z)-3- | hexen-1-yl benzoate | FL/FR |
(Z)-3- | hexen-1-yl formate | FL/FR |
| hexen-1-yl oxypropane nitrile | FR |
(Z)-3- | hexen-1-yl tiglate | FL/FR |
| hexyl (Z)-tiglate | FL/FR |
| hexyl 2-methyl butyrate | FL/FR |
| hexyl tiglate | FL/FR |
| hyacinth absolute | FL/FR |
2,4- | ivy carbaldehyde | FL/FR |
(Z)- | leaf acetal | FL/FR |
| melon nonenoate | FL/FR |
(2- | methoxy-1-methyl butyl) benzene | FR |
[(4E,4Z)-5- | methoxy-3-methyl-4-penten-1-yl] benzene | FR |
| methyl cyclocitrone (IFF) | FR |
para- | methyl hydratropaldehyde | FL/FR |
| methyl octine carbonate | FL/FR |
4- | methyl-4-phenyl pentanone | FR |
(E,Z)-2,6- | nonadien-1-ol | FL/FR |
(Z)-5- | octen-1-ol | FL/FR |
| octyl oxyacetaldehyde | FR |
| pelargonium graveolens stem leaf extract | FR |
| phenyl acetaldehyde dimethyl acetal | FL/FR |
| phenyl acetaldehyde solution | FL/FR |
| privetone | FR |
| rose leaf absolute (rosa centifolia) | FL/FR |
| styralyl acetate | FL/FR |
| violet leaf absolute | FL/FR |
herbal |
| carum carvi fruit oil | FL/FR |
| chrysanthemum ketone | FR |
| clary acetate | FR |
| clary sage absolute | FL/FR |
| clary sage oil france | FL/FR |
| coriander oleoresin | FL/FR |
| dihexyl (E)-fumarate | FR |
| linalyl acetate | FL/FR |
2- | methyl butyl salicylate | FL/FR |
(1S,5R)- | myrtenyl acetate | FL/FR |
| phenyl acetaldehyde diisoamyl acetal | FR |
marine |
green | algae absolute | FL/FR |
medicinal |
| kunzea ericoides leaf oil | FR |
melon |
| melon heptenal | FL/FR |
(Z)-6- | nonenal | FL/FR |
naphthyl |
para- | methyl anisole | FL/FR |
powdery |
para- | anisyl alcohol | FL/FR |
spicy |
| cinnamyl propionate | FL/FR |
iso | cyclogeraniol (IFF) | FR |
| pimenta acris leaf oil | FL/FR |
| spicy carbonate | FR |
tea |
| camellia oleifera leaf extract | FL/FR |
terpenic |
alpha- | terpineol | FL/FR |
waxy |
3- | decanone | FL/FR |
| ethyl laurate | FL/FR |
woody |
| santall | FR |
(Z)- | woody amylene | FR |
|
For Flavor |
|
No flavor group found for these |
| acetaldehyde dibutyl acetal | FL/FR |
green | algae absolute | FL/FR |
| amyl benzoate | FL/FR |
| boronia concrete | FL/FR |
3- | decanone | FL/FR |
| earthy acetal | FL/FR |
(Z)-3- | hexen-1-yl acetoacetate | FL/FR |
| hexyl (Z)-tiglate | FL/FR |
| hyacinth absolute | FL/FR |
| hydroxycitronellal propylene glycol acetal | FL/FR |
| linalyl phenyl acetate | FL/FR |
2- | methyl butyl salicylate | FL/FR |
| phenyl acetaldehyde solution | FL/FR |
| styralyl formate | FL/FR |
| terpinyl isobutyrate | FL/FR |
2- | tetradecenal | FL/FR |
|
iso | amyl 3-(2-furan) propionate | FL/FR |
alpha- | butyl cinnamaldehyde | FL/FR |
aldehydic |
iso | butyraldehyde | FL/FR |
amber |
iso | butyl benzyl carbinol | FL/FR |
animal |
para- | cresyl caprylate | FL/FR |
anise |
sweet | fennel seed oil | FL/FR |
apple |
(E,Z)-2,6- | nonadien-1-ol | FL/FR |
aromatic |
| amyl salicylate | FL/FR |
para- | cresyl acetate | FL/FR |
para- | cresyl isobutyrate | FL/FR |
balsamic |
| benzyl salicylate | FL/FR |
| ethyl cinnamate | FL/FR |
berry |
| heliotropyl acetone | FL/FR |
| raspberry ketone methyl ether | FL/FR |
citrus |
| bergamot oil | FL/FR |
| bergamot oil bergaptene reduced italy | FL/FR |
| bergamot oil turkey | FL/FR |
| citral dimethyl acetal | FL/FR |
laevo- | linalool | FL/FR |
| linalool | FL/FR |
| mandarin oil (citrus reticulata var. ponkan) | FL/FR |
| nerol | FL/FR |
blood | orange oil italy | FL/FR |
alpha- | terpineol | FL/FR |
cooling |
iso | butyl salicylate | FL/FR |
creamy |
gamma- | undecalactone (aldehyde C-14 (so-called)) | FL/FR |
fatty |
2- | decenal | FL/FR |
(Z)-3- | hexen-1-yl benzoate | FL/FR |
floral |
| bois de rose oil brazil | FL/FR |
| cinnamyl propionate | FL/FR |
| citronellol | FL/FR |
| citronellyl acetate | FL/FR |
| citronellyl propionate | FL/FR |
| dihydrocarvyl acetate | FL/FR |
(±)-2,3- | dihydrofarnesol | FL/FR |
| dihydrojasmone | FL/FR |
| dimethyl benzyl carbinyl butyrate | FL/FR |
3,7- | dimethyl-6-octenoic acid | FL/FR |
| farnesol | FL/FR |
| farnesyl acetate | FL/FR |
| geraniol | FL/FR |
| geranium oil | FL/FR |
| geranium oil africa | FL/FR |
| geranyl acetone | FL/FR |
| linalyl acetate | FL/FR |
| methyl dihydrojasmonate | FL/FR |
| neroli oil CO2 extract | FL/FR |
| neryl acetate | FL/FR |
| ocean propanal | FL/FR |
| orange leaf absolute | FL/FR |
bitter | orangeflower absolute tunisia | FL/FR |
| phenethyl propionate | FL/FR |
| rhodinol | FL/FR |
laevo- | rose oxide | FL/FR |
| tetrahydrolinalool | FL/FR |
| tropical ionone | FL/FR |
| tuberose absolute (from pommade) | FL/FR |
| ylang ylang flower oil | FL/FR |
| ylang ylang flower oil III | FL/FR |
fruity |
| allyl cyclohexyl propionate | FL/FR |
iso | amyl benzoate | FL/FR |
para- | anisyl alcohol | FL/FR |
| benzyl acetate | FL/FR |
| benzyl alcohol | FL/FR |
| benzyl isobutyrate | FL/FR |
| benzyl methyl ether | FL/FR |
| benzyl propionate | FL/FR |
| citronellyl isobutyrate | FL/FR |
gamma- | decalactone | FL/FR |
| dimethyl anthranilate | FL/FR |
| dimethyl succinate | FL/FR |
| ethyl methyl-para-tolyl glycidate | FL/FR |
| hexyl lactate | FL/FR |
| rhodinyl formate | FL/FR |
| rose butanoate | FL/FR |
| strawberry glycidate 1 (aldehyde C-16 (so-called)) | FL/FR |
| styralyl acetate | FL/FR |
green |
iso | amyl salicylate | FL/FR |
| chrysanthemum oxide | FL/FR |
| cinnamyl alcohol | FL/FR |
| cortex pyridine | FL/FR |
| cyclamen aldehyde | FL/FR |
| cyclohexyl ethyl alcohol | FL/FR |
| dihydromyrcenol | FL/FR |
para- | dimethyl hydroquinone | FL/FR |
| diphenyl oxide | FL/FR |
| galbanum oil | FL/FR |
| geranyl acetate | FL/FR |
| geranyl formate | FL/FR |
(Z)-3- | hexen-1-ol | FL/FR |
(Z)-3- | hexen-1-yl acetate | FL/FR |
(Z)-3- | hexen-1-yl formate | FL/FR |
(Z)-3- | hexen-1-yl salicylate | FL/FR |
(Z)-3- | hexen-1-yl tiglate | FL/FR |
| hexyl 2-methyl butyrate | FL/FR |
| hexyl tiglate | FL/FR |
2,4- | ivy carbaldehyde | FL/FR |
(Z)- | leaf acetal | FL/FR |
| linalool oxide | FL/FR |
| melon heptenal | FL/FR |
| melon nonenoate | FL/FR |
| methyl heptenone | FL/FR |
para- | methyl hydratropaldehyde | FL/FR |
| methyl octine carbonate | FL/FR |
(E)- | nerolidol | FL/FR |
| nerolidol | FL/FR |
| nonanal dimethyl acetal | FL/FR |
(Z)-6- | nonenal | FL/FR |
(Z)-5- | octen-1-ol | FL/FR |
| papaya isobutyrate | FL/FR |
| phenyl acetaldehyde diisobutyl acetal | FL/FR |
| phenyl acetaldehyde dimethyl acetal | FL/FR |
| rose leaf absolute (rosa centifolia) | FL/FR |
(Z)- | rose oxide | FL/FR |
| violet leaf absolute | FL/FR |
herbal |
| carum carvi fruit oil | FL/FR |
| clary sage absolute | FL/FR |
| clary sage oil france | FL/FR |
| coriander oleoresin | FL/FR |
| coriander seed oil | FL/FR |
| coriander seed oil CO2 extract | FL/FR |
| ocimum basilicum herb oil | FL/FR |
| petitgrain oil paraguay | FL/FR |
honey |
| phenethyl acetate | FL/FR |
medicinal |
| dimethyl benzyl carbinol | FL/FR |
melon |
| hydroxycitronellal diethyl acetal | FL/FR |
naphthyl |
para- | methyl anisole | FL/FR |
phenolic |
para- | cresyl phenyl acetate | FL/FR |
soapy |
| dodecanal (aldehyde C-12 lauric) | FL/FR |
spicy |
| cinnamyl formate | FL/FR |
3- | phenyl propyl alcohol | FL/FR |
| pimenta acris leaf oil | FL/FR |
tea |
| camellia oleifera leaf extract | FL/FR |
tropical |
alpha- | amyl cinnamaldehyde | FL/FR |
waxy |
| ethyl laurate | FL/FR |
alpha- | hexyl cinnamaldehyde | FL/FR |
| mimosa absolute | FL/FR |
| mimosa absolute france | FL/FR |
| mimosa absolute india | FL/FR |
(E)-2- | tetradecenal | FL/FR |
woody |
(1S,5R)- | myrtenyl acetate | FL/FR |
|
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| glycolierral (Givaudan) | | ivy dioxolane | 2-(2- | methyl-5-propan-2-yl-7-bicyclo[2.2.2]oct-2-enyl)-1,3-dioxolane | 2(6)- | methyl-8-(1-methyl ethyl) bicyclo(2.2.2)oct-5-en-2(3)-yl-1,3-dioxolane | 2-(7-iso | propyl-5-methyl bicyclo(2.2.2)oct-5-en-2-yl)-1,3-dioxolane | 7-iso | propyl-5-methyl bicyclooctenyl dioxolane | 2-(8-iso | propyl-6-methyl bicyclo(2.2.2)oct-5-en-2-yl)-1,3-dioxolane addition | 8-iso | propyl-6-methyl bicyclooctenyl dioxolane |
Articles:
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