Articles:
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ethyl cis-3-hexenoate
Notes:
Used as a food additive [EAFUS]
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BOC Sciences Best of Chemicals Supplier Quality supplier of research chemicals and biochemicals including inhibitors, building blocks, GMP Products, impurities and metabolites, APIs for Veterinary, Natural Compounds, ADCs, Stem Cell Molecule and chiral compounds. BOC Sciences provides a wide range of services to support the pharmaceutical industry through all stages of drug discovery including Custom Synthesis of those chemicals that are not in stock, Isotope Labeling Service, Chiral Synthesis and Resolution, Bioconjugation, PEGylation services, analytical services. BOC Sciences is a brand of BOCSCI Inc. We leverage our wide spectrum of business in the fields of development, manufacturing, marketing, and distribution to help you make best-informed decisions tailored to your evolving needs for premium chemicals. Our complete suite of CRO services spans the entire molecule development pipeline including contract research for target identification, building blocks, compound synthesis, biochemical and cellular analysis, preclinical animal tests, and clinical studies. Email: Marketing US Email: Marketing Email: Sales US Email: Sales Voice: 1-631-485-4226 Fax: 1-631-614-7828 US Voice: 1-631-485-4226 US Fax: 1-631-614-7828 Europe 44-203-286-1088 Facebook Twitter Linkedin Blog Get the App! Product(s): 64187-83-3 Ethyl (Z)hex-3-enoate
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Penta International Corporation Chemistry innovation At Penta, our products and services help businesses do business better. For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes. US Email: Technical Services US Email: Sales US Voice: (973) 740-2300 US Fax: (973) 740-1839 Product(s): 05-38300 ETHYL CIS-3-HEXENOATE 05-38310 ETHYL CIS-3-HEXENOATE NATURAL
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| CAS Number: | 64187-83-3 |  3D/inchi
|
| ECHA EINECS - REACH Pre-Reg: | 264-724-0 | |
| FDA UNII: | R35DY1229O | |
| Nikkaji Web: | J126.494J | |
| XlogP3-AA: | 1.90 (est) | |
| Molecular Weight: | 142.19798000 | |
| Formula: | C8 H14 O2 | |
| NMR Predictor: | Predict (works with chrome or firefox) | |
Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
| Google Scholar: | Search |
| Google Books: | Search |
| Google Scholar: with word "volatile" | Search |
| Google Scholar: with word "flavor" | Search |
| Google Scholar: with word "odor" | Search |
| Perfumer and Flavorist: | Search |
| Google Patents: | Search |
| US Patents: | Search |
| EU Patents: | Search |
| Pubchem Patents: | Search |
| PubMed: | Search |
| NCBI: | Search |
| JECFA Food Flavoring: | 1626 ethyl (Z)-3-hexenoate |
| DG SANTE Food Flavourings: | 09.939 ethyl (3Z)-hexenoate |
| FEMA Number: | 4112 ethyl cis-3-hexenoate |
| FDA: | No longer provide for the use of these seven synthetic flavoring substances |
| FDA Mainterm (SATF): | 64187-83-3 ; ETHYL CIS-3-HEXENOATE |
Physical Properties:
| Appearance: | colorless to pale yellow clear liquid (est) |
| Assay: | 96.00 to 100.00 % |
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.89300 to 0.90300 @ 25.00 °C. |
| Pounds per Gallon - (est).: | 7.431 to 7.514 |
| Refractive Index: | 1.42000 to 1.42900 @ 20.00 °C. |
| Boiling Point: | 90.00 °C. @ 50.00 mm Hg |
| Boiling Point: | 169.00 to 170.00 °C. @ 760.00 mm Hg |
| Vapor Pressure: | 1.553000 mmHg @ 25.00 °C. (est) |
| Vapor Density: | >1 ( Air = 1 ) |
| Flash Point: | 130.00 °F. TCC ( 54.44 °C. ) |
| logP (o/w): | 2.590 (est) |
| Shelf Life: | 36.00 month(s) or longer if stored properly. |
| Soluble in: | |
| alcohol | |
| water, slightly | |
| water, 480.5 mg/L @ 25 °C (est) | |
| Insoluble in: | |
| water | |
Organoleptic Properties:
| Odor Type: tropical | |
| green pear apple tropical | |
| Odor Description: at 10.00 % in dipropylene glycol. | green pear apple tropical |
| Odor and/or flavor descriptions from others (if found). | |
| Bedoukian Research | |
| ETHYL CIS-3-HEXENOATE (NATURAL) ≥98.0%, Kosher | |
| Odor Description: | Sharp, pear, green, apple, tropical, good for rind notes, pineapple Use for rind or green notes in fruity applications. |
| Taste Description: | green Use in strawberry or in tropicals such as carambola/star fruit, pineapple, fruit punch, rind notes, kiwi, brandy/cognac or wine. |
Cosmetic Information:
| None found |
Suppliers:
| BOC Sciences |
| For experimental / research use only. |
| Ethyl (Z)hex-3-enoate |
| Parchem |
| ethyl (Z)-3-hexenoate |
| Penta International |
| ETHYL CIS-3-HEXENOATE NATURAL |
| Penta International |
| ETHYL CIS-3-HEXENOATE |
Safety Information:
| European information : | |
| Most important hazard(s): | |
| Xi - Irritant | |
|
R 10 - Flammable. R 38 - Irritating to skin. S 02 - Keep out of the reach of children. S 24 - Avoid contact with skin. S 36 - Wear suitable protective clothing. | |
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| None found. | |
| GHS Label elements, including precautionary statements | |
| Pictogram | |
| Hazard statement(s) | |
| None found. | |
| Precautionary statement(s) | |
| None found. | |
| Oral/Parenteral Toxicity: | |
| Not determined | |
| Dermal Toxicity: | |
| Not determined | |
| Inhalation Toxicity: | |
| Not determined | |
Safety in Use Information:
| Category: | flavor and fragrance agents | ||
| RIFM Fragrance Material Safety Assessment: Search | |||
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
| Recommendation for ethyl (Z)-3-hexenoate usage levels up to: | |||
| 2.0000 % in the fragrance concentrate. | |||
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 120.00 (μg/capita/day) | ||
| Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 800 (μg/person/day) | ||
| Threshold of Concern: | 1800 (μg/person/day) | ||
| Structure Class: | I | ||
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). | |||
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library | |||
| publication number: 22 | |||
| Click here to view publication 22 | |||
| average usual ppm | average maximum ppm | ||
| baked goods: | 5.00000 | 20.00000 | |
| beverages(nonalcoholic): | 2.00000 | 10.00000 | |
| beverages(alcoholic): | 5.00000 | 20.00000 | |
| breakfast cereal: | 2.00000 | 10.00000 | |
| cheese: | - | - | |
| chewing gum: | 5.00000 | 25.00000 | |
| condiments / relishes: | 2.00000 | 20.00000 | |
| confectionery froastings: | 5.00000 | 25.00000 | |
| egg products: | - | - | |
| fats / oils: | - | - | |
| fish products: | - | - | |
| frozen dairy: | 5.00000 | 20.00000 | |
| fruit ices: | 5.00000 | 20.00000 | |
| gelatins / puddings: | 5.00000 | 20.00000 | |
| granulated sugar: | - | - | |
| gravies: | - | - | |
| hard candy: | 10.00000 | 40.00000 | |
| imitation dairy: | 2.00000 | 10.00000 | |
| instant coffee / tea: | 2.00000 | 10.00000 | |
| jams / jellies: | 5.00000 | 25.00000 | |
| meat products: | - | - | |
| milk products: | - | - | |
| nut products: | - | - | |
| other grains: | - | - | |
| poultry: | - | - | |
| processed fruits: | 1.00000 | 10.00000 | |
| processed vegetables: | - | - | |
| reconstituted vegetables: | - | - | |
| seasonings / flavors: | 25.00000 | 100.00000 | |
| snack foods: | - | - | |
| soft candy: | 10.00000 | 40.00000 | |
| soups: | - | - | |
| sugar substitutes: | - | - | |
| sweet sauces: | 2.00000 | 10.00000 | |
| Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). | |||
| Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. | |||
| average usage mg/kg | maximum usage mg/kg | ||
| Dairy products, excluding products of category 02.0 (01.0): | 0.02000 | 0.40000 | |
| Fats and oils, and fat emulsions (type water-in-oil) (02.0): | 0.20000 | 0.40000 | |
| Edible ices, including sherbet and sorbet (03.0): | 0.20000 | 4.00000 | |
| Processed fruit (04.1): | 0.02000 | 0.40000 | |
| Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | 0.02000 | 0.40000 | |
| Confectionery (05.0): | 2.00000 | 40.00000 | |
| Chewing gum (05.0): | - | - | |
| Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 0.40000 | 8.00000 | |
| Bakery wares (07.0): | 0.20000 | 4.00000 | |
| Meat and meat products, including poultry and game (08.0): | 0.02000 | 0.40000 | |
| Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | 0.02000 | 0.40000 | |
| Eggs and egg products (10.0): | - | - | |
| Sweeteners, including honey (11.0): | - | - | |
| Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 0.02000 | 0.40000 | |
| Foodstuffs intended for particular nutritional uses (13.0): | - | - | |
| Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | 2.00000 | 40.00000 | |
| Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 2.00000 | 40.00000 | |
| Ready-to-eat savouries (15.0): | 0.02000 | 0.40000 | |
| Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | 0.02000 | 0.40000 | |
Safety References:
| European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): | |
| Flavouring Group Evaluation 6, Revision 1 (FGE.06Rev1) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) View page or View pdf | |
| Scientific Opinion on Flavouring Group Evaluation 06, Revision 2 (FGE.06Rev2): Straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters from chemical groups 1 and 4 View page or View pdf | |
| Scientific Opinion on Flavouring Group Evaluation 06, Revision 3 (FGE.06Rev3): Straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters from chemical groups 1 and 4 View page or View pdf | |
| Scientific Opinion on Flavouring Group Evaluation 06, Revision 4 (FGE.06Rev4): Straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids and esters from chemical groups 1, 3 and 4 View page or View pdf | |
| EPI System: | View |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 5362623 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WISER: | UN 3272 |
| WGK Germany: | 2 |
| ethyl (Z)-hex-3-enoate | |
| Chemidplus: | 0064187833 |
References:
| ethyl (Z)-hex-3-enoate | |
| NIST Chemistry WebBook: | Search Inchi |
| Pubchem (cid): | 5362623 |
| Pubchem (sid): | 135073259 |
| Pherobase: | View |
Other Information:
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| FDA Substances Added to Food (formerly EAFUS): | View |
| HMDB (The Human Metabolome Database): | HMDB32266 |
| FooDB: | FDB009389 |
| Export Tariff Code: | 2916.19.6000 |
| Typical G.C. | |
| VCF-Online: | VCF Volatile Compounds in Food |
| ChemSpider: | View |
Potential Blenders and core components note
Potential Uses:
| fruit | FR | |
| green | FR | |
| tropical | FL |
Occurrence (nature, food, other): note
| acerola fruit Search Trop Picture | |
| brandy grape brandy Search PMC Picture | |
| guava fruit Search Trop Picture | |
| mango fruit Search Trop Picture | |
| mastic leaf oil @ 0.07% Data GC Search Trop Picture | |
| passion fruit juice - up to 0.15 mg/kg Search Trop Picture | |
| pear fruit Search Trop Picture | |
| pineapple fruit Search Trop Picture | |
| strawberry guava fruit Search Trop Picture | |
| tea leaf Search Trop Picture |
Synonyms:
| ethyl (3Z)-3-hexenoate | |
| ethyl (3Z)-hex-3-enoate | |
| ethyl (3Z)-hexenoate | |
| ethyl (Z)-hex-3-enoate | |
| ethyl cis-3-hexenoate | |
| ethyl cis-3-hexenoate (natural) | |
| ethyl cis-3-hexenoate natural | |
| cis- | hex-3-enoic acid ethyl ester |
| 3- | hexenoic acid, ethyl ester, (3Z)- |
| 3- | hexenoic acid, ethyl ester, (Z)- |