2-methyl-5-ethoxypyrazine
5-ethoxy-2-methylpyrazine
 
Notes:
Flavouring ingredient with roast, chocolate odour. Component of FEMA 3183, together with its regioisomers
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      Product(s):
      67845-34-5 Pyrazine,2-ethoxy-5-methyl-
       
  • CSA
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CAS Number: 67845-34-5Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 267-309-2
FDA UNII: 8TD8256VKE
Nikkaji Web: J429.650H
XlogP3: 0.80 (est)
Molecular Weight: 138.16990000
Formula: C7 H10 N2 O
NMR Predictor: Predict (works with chrome, Edge or firefox)
Category: flavoring agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
FEMA Number: 3569 2-methyl-5-ethoxypyrazine
FDA:No longer provide for the use of these seven synthetic flavoring substances
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Physical Properties:
Appearance: colorless to pale yellow clear liquid (est)
Assay: 95.00 to 100.00 % 
Food Chemicals Codex Listed: No
Boiling Point: 189.00 to  191.00 °C. @ 760.00 mm Hg
Vapor Pressure: 0.802000 mmHg @ 25.00 °C. (est)
Flash Point: 154.00 °F. TCC ( 67.78 °C. )
logP (o/w): 1.703 (est)
Soluble in:
 alcohol
 water
 water, 1824 mg/L @ 25 °C (est)
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Organoleptic Properties:
 
Odor Type: nutty
 
 nutty  roasted  
Odor Description:
at 0.10 % in propylene glycol. 		nutty roasted
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
None found
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Suppliers:
BOC Sciences
For experimental / research use only.
Pyrazine,2-ethoxy-5-methyl-
Parchem
2-methyl-5-ethoxypyrazine
Chemical Sources Association
Need This Item for Flavor/Food?: You can contact the CSA
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Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: flavoring agents
Recommendation for 2-methyl-5-ethoxypyrazine usage levels up to:
 not for fragrance use.
 
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 11
Click here to view publication 11
 average usual ppmaverage maximum ppm
baked goods: --
beverages(nonalcoholic): -0.50000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: -2.00000
egg products: --
fats / oils: --
fish products: --
frozen dairy: -0.50000
fruit ices: --
gelatins / puddings: -3.00000
granulated sugar: --
gravies: --
hard candy: --
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
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Safety References:
Flavor & Extract Manufacturers Association (FEMA) reference(s):
The FEMA GRAS assessment of pyrazine derivatives used as flavor ingredients. View pdf
EPI System: View
AIDS Citations: Search
Cancer Citations: Search
Toxicology Citations: Search
EPA Substance Registry Services (TSCA): 67845-34-5
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 105758
National Institute of Allergy and Infectious Diseases: Data
 2-ethoxy-5-methylpyrazine
Chemidplus: 0067845345
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References:
 2-ethoxy-5-methylpyrazine
NIST Chemistry WebBook: Search Inchi
Pubchem (cid): 105758
Pubchem (sid): 135063235
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): HMDB40142
FooDB: FDB019839
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
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Potential Blenders and core components note
 
For Odor
No odor group found for these
 sulfuryl octanoateFL/FR
 sulfuryl butyrateFL/FR
 sulfuryl decanoateFL/FR
 sulfuryl hexanoateFL/FR
 sulfuryl isobutyrateFL/FR
 sulfuryl propionateFL/FR
 valeraldehyde dibutyl acetalFL/FR
 valeraldehyde propylene glycol acetalFL/FR
animal
 costus valerolactoneFR
balsamic
2-acetyl furanFL/FR
 amyl cinnamateFL/FR
isoamyl cinnamateFL/FR
 amyl phenyl acetateFL/FR
 butyl cinnamateFL/FR
 prenyl benzoateFL/FR
 propyl benzoateFL/FR
 terpinyl cinnamateFL/FR
bready
 coffee furanoneFL/FR
buttery
 acetyl propionylFL/FR
3,4-hexane dioneFL/FR
camphoreous
 bornyl isobutyrateFL/FR
 butyrophenoneFL/FR
caramellic
 ethyl 2-hydroxy-2-methyl butyrateFL/FR
 fenugreek oleoresinFL/FR
cheesy
2-heptanoneFL/FR
chocolate
isoamyl phenyl acetateFL/FR
isobutyl phenyl acetateFL/FR
 chocolate pyrazine AFL/FR
 cocoa hexenalFL/FR
 cocoa oleoresinFL/FR
 cocoa pentenalFL/FR
2,5-dimethyl pyrazineFL/FR
2,6-dimethyl pyrazineFL/FR
2-methoxy-3-methyl pyrazineFL/FR
2-methoxypyrazineFL/FR
2,4,5-trimethyl thiazoleFL/FR
cocoa
2-isobutyl-3,5-(and 3,6)-dimethyl pyrazineFL/FR
2-methyl butyraldehydeFL/FR
coconut
alpha-angelica lactoneFL/FR
 coconut decanone methylFR
 coconut naphthalenoneFL/FR
delta-decalactoneFL/FR
delta-2-dodecenolactoneFL/FR
delta-heptalactoneFL/FR
gamma-heptalactoneFL/FR
delta-nonalactoneFL/FR
gamma-nonalactone (aldehyde C-18 (so-called))FL/FR
delta-octalactoneFL/FR
gamma-octalactoneFL/FR
 propyl octanoateFL/FR
 tetrahydrojasmoneFR
delta-undecalactoneFL/FR
 wine lactoneFL/FR
 popcorn pyrimidineFL/FR
coumarinic
 coumaneFL/FR
 phthalideFL/FR
 tonka bean resinoidFR
creamy
 creamy lactoneFL/FR
earthy
2-ethyl-3-methoxypyrazineFL/FR
 nutty pyrazineFL/FR
isopropyl formateFL/FR
fatty
 coconut absoluteFL/FR
 lauric acidFL/FR
(Z)-2-octenal 
fermented
3-methyl-1-pentanolFL/FR
 valeraldehydeFL/FR
floral
alpha-amyl cinnamyl acetateFL/FR
 amyl salicylateFL/FR
 boronia butenalFR
para-cresyl laurateFL/FR
 dihydrojasmone lactoneFL/FR
 ethyl phenyl acetateFL/FR
 heliotropinFL/FR
 hexenyl cyclopentanoneFR
 jasmin lactone (IFF)FL/FR
2-pentyl cyclopentanoneFR
2-phenyl propionaldehyde dimethyl acetalFL/FR
fruity
 allyl 2-ethyl butyrateFL/FR
 amyl heptanoateFL/FR
isoamyl nonanoateFL/FR
isoamyl octanoateFL/FR
 butyl 2-methyl butyrateFL/FR
gamma-decalactoneFL/FR
4-hydroxybenzyl alcoholFL/FR
 methyl (Z)-5-octenoateFL/FR
 methyl valerateFL/FR
3-methyl-2-butenalFL/FR
 nonyl isovalerateFL/FR
isopropyl octanoateFL/FR
 tropical thiazoleFL/FR
green
alpha-decalactoneFL/FR
2-heptyl furanFL/FR
(E,Z)-2,6-nonadien-1-yl acetateFL/FR
 phenyl acetaldehydeFL/FR
herbal
 saffron pyranoneFR
gamma-valerolactoneFL/FR
honey
 butyl phenyl acetateFL/FR
 phenyl acetic acidFL/FR
medicinal
meta-dimethyl hydroquinoneFL/FR
milky
laevo-glutamineCS
musty
2-acetyl pyrroleFL/FR
3-acetyl-2,5-dimethyl furanFL/FR
 cocoa butenalFL/FR
 hazelnut pyrazineFL/FR
 menthofuranFL/FR
naphthyl
para-methyl anisoleFL/FR
ortho-methyl anisoleFL/FR
nutty
3-acetyl pyridineFL/FR
2-acetyl-3-ethyl pyrazineFL/FR
2-acetyl-3-methyl pyrazineFL/FR
2-acetyl-3,5-dimethyl pyrazineFL/FR
2-acetyl-3,5(or 6)-dimethyl pyrazineFL/FR
2-acetyl-5-methyl furanFL/FR
3,5-cocoa pyrazineFL/FR
3,6-cocoa pyrazineFL/FR
2,3-dimethyl pyrazineFL/FR
4,5-dimethyl-2-ethyl-3-thiazolineFL/FR
2-ethyl pyrazineFL/FR
2-ethyl-4-methyl thiazoleFL/FR
 filbert heptenoneFL/FR
 filbert pyrazineFL/FR
2,6-lutidineFL/FR
 maraniolCS
2-methyl pyrazineFL/FR
5-methyl quinoxalineFL/FR
2-methyl thio-3,5 or 6-methyl pyrazineFL/FR
2-methyl-3-(methyl thio) pyrazineFL/FR
2-methyl-3-ethoxypyrazineFL/FR
2-methyl-3-pentenoic acidFL/FR
2-methyl-3-propyl pyrazineFL/FR
 nutty cyclohexenoneFL/FR
 nutty quinoxalineFL/FR
 shoyu pyrazineFL/FR
2,3,5,6-tetramethyl pyrazineFL/FR
2,3,5-trimethyl pyrazineFL/FR
 vinyl sulfurolFL/FR
popcorn
2-acetyl pyrazineFL/FR
2-acetyl thiazoleFL/FR
roasted
2-acetyl-2-pyrroline 
 fenugreek resinoidFL/FR
soapy
 ethyl undecanoateFL/FR
spicy
3-(2-furyl) acroleinFL/FR
 mace absoluteFL/FR
 mace oilFL/FR
 mace oleoresinFL/FR
 methyl heptadienoneFL/FR
 nutmeg oilFL/FR
 nutmeg oil CO2 extractFL/FR
 nutmeg oil terpenelessFL/FR
 nutmeg oleoresinFL/FR
 furfuryl thioacetateFL/FR
terpenic
 cassis bud oilFL/FR
tobacco
 veltonal (Bedoukian)FR
tonka
6-amyl-alpha-pyroneFL/FR
gamma-hexalactoneFL/FR
7-methyl coumarinCS
 mint lactoneFL/FR
 tonka bean absoluteFR
 whiskey lactoneFL/FR
tropical
delta-dodecalactoneFL/FR
 glyceryl 5-hydroxydecanoateFL/FR
 glyceryl 5-hydroxydodecanoateFL/FR
vanilla
 ethyl vanillin isobutyrateFL/FR
 vanillinFL/FR
 vanillyl isobutyrateFL/FR
waxy
 butyl laurateFL/FR
1-dodecanolFL/FR
 methyl laurateFL/FR
 myristyl alcoholFL/FR
 phenethyl octanoateFL/FR
2-tridecanoneFL/FR
 undecanoic acidFL/FR
woody
 cedrenyl acetateFR
2-methoxy-4-vinyl phenolFL/FR
 sandalwood oilFL/FR
 
For Flavor
 
No flavor group found for these
 acetyl acetaldehyde dimethyl acetalFL
2-acetyl-2-pyrroline 
 amyl phenyl acetateFL/FR
 bornyl isobutyrateFL/FR
 butyl cinnamateFL/FR
2-isobutyl-3,5-(and 3,6)-dimethyl pyrazineFL/FR
2(4)-isobutyl-4(2),6-dimethyl dihydro-4H-1,3,5-dithiazineFL
 butyramideFL
 butyrophenoneFL/FR
 chocolate pyrazine AFL/FR
 coconut naphthalenoneFL/FR
 coumaneFL/FR
 cyclohexyl methyl pyrazineFL
alpha-decalactoneFL/FR
2,5-diethyl thiazoleFL
2,5-diethyl-4-methyl thiazoleFL
6,7-dihydro-2,3-dimethyl-5H-cyclopentapyrazineFL
 dimethyl benzofuranoneFL
 dimethyl dihydrocyclopentapyrazineFL
2,5-dimethyl thiazoleFL
4,5-dimethyl-2-ethyl thiazoleFL
delta-2-dodecenolactoneFL/FR
 ethyl 2-hydroxy-2-methyl butyrateFL/FR
2-ethyl-3-methoxypyrazineFL/FR
(Z+E)-5-ethyl-4-methyl-2-(2-butyl) thiazolineFL
(Z+E)-5-ethyl-4-methyl-2-(2-methyl propyl) thiazolineFL
3-(2-furyl) acroleinFL/FR
(E,E)-2,4-heptadien-1-olFL
2-hexyl-5 or 6-keto-1,4-dioxaneFL
 jasmin lactone (IFF)FL/FR
 lauric acidFL/FR
2-methoxypyrazineFL/FR
 methyl 2-(methyl thio) acetateFL
2-methyl-3-(methyl thio) pyrazineFL/FR
2-methyl-3-ethoxypyrazineFL/FR
2-methyl-3-pentenoic acidFL/FR
 myristyl alcoholFL/FR
 nonyl isovalerateFL/FR
(Z)-2-octenal 
 peanut dithiazineFL
 prenyl benzoateFL/FR
 propyl octanoateFL/FR
2-propyl pyridineFL
para-salicylic acidFL
 sulfuryl butyrateFL/FR
 sulfuryl decanoateFL/FR
 sulfuryl hexanoateFL/FR
 sulfuryl isobutyrateFL/FR
(R)-tonka furanoneFL
 valeraldehyde propylene glycol acetalFL/FR
 wine lactoneFL/FR
5-acetyl-2,3-dihydro-1,4-thiazineFL
 sulfuryl formateFL
 sulfuryl octanoateFL/FR
 sulfuryl propionateFL/FR
 valeraldehyde dibutyl acetalFL/FR
alliaceous
 dicyclohexyl disulfideFL
2-methyl thioacetaldehydeFL
 tropical thiazoleFL/FR
aromatic
 amyl salicylateFL/FR
balsamic
 amyl cinnamateFL/FR
bitter
 methyl ethoxypyrazineFL
bready
2-propionyl thiazoleFL
brown
 fenugreek oleoresinFL/FR
burnt
2-methyl quinoxalineFL
buttery
 butyroinFL
3,4-hexane dioneFL/FR
camphoreous
ortho-methyl anisoleFL/FR
caramellic
 fenugreek resinoidFL/FR
cheesy
2-heptanoneFL/FR
chemical
meta-dimethyl hydroquinoneFL/FR
cherry
 heliotropinFL/FR
chocolate
 cocoa oleoresinFL/FR
 cocoa propanalFL
cocoa
isobutyl phenyl acetateFL/FR
 butyraldehydeFL
 cocoa hexenalFL/FR
2-methyl furanFL
coconut
delta-decalactoneFL/FR
(R)-massoia lactoneFL
6-methyl coumarinFL
gamma-nonalactone (aldehyde C-18 (so-called))FL/FR
delta-octalactoneFL/FR
coffee
 difurfuryl etherFL
2-ethyl-4-methyl thiazoleFL/FR
2-isopropyl pyrazineFL
corn chip
2-acetyl thiazoleFL/FR
2-acetyl-2-thiazolineFL
 popcorn pyrimidineFL/FR
coumarinic
 phthalideFL/FR
creamy
6-amyl-alpha-pyroneFL/FR
alpha-angelica lactoneFL/FR
 creamy lactoneFL/FR
5,5-dibutyl dihydrofuran-2(3H)-oneFL
delta-dodecalactoneFL/FR
 glyceryl 5-hydroxydecanoateFL/FR
 glyceryl 5-hydroxydodecanoateFL/FR
gamma-hexalactoneFL/FR
 mint lactoneFL/FR
delta-nonalactoneFL/FR
delta-undecalactoneFL/FR
dairy
 methyl (Z)-5-octenoateFL/FR
earthy
alpha-amyl cinnamyl acetateFL/FR
2-methyl-3-propyl pyrazineFL/FR
ethereal
 allyl 2-ethyl butyrateFL/FR
fatty
 coconut absoluteFL/FR
(E,E)-2,4-decadienalFL
2-heptyl furanFL/FR
(E,E)-2,4-nonadienalFL
2-tridecanoneFL/FR
fishy
4,5-dimethyl thiazoleFL
floral
isoamyl cinnamateFL/FR
isoamyl phenyl acetateFL/FR
 cocoa pentenalFL/FR
 phenyl acetic acidFL/FR
fruity
 amyl heptanoateFL/FR
isoamyl octanoateFL/FR
 butyl 2-methyl butyrateFL/FR
 cassis bud oilFL/FR
gamma-decalactoneFL/FR
2,4-hexadien-1-olFL
4-hydroxybenzyl alcoholFL/FR
 methyl valerateFL/FR
3-methyl-2-butenalFL/FR
 phenethyl octanoateFL/FR
2-phenyl propionaldehyde dimethyl acetalFL/FR
 propyl benzoateFL/FR
isopropyl formateFL/FR
isopropyl octanoateFL/FR
 terpinyl cinnamateFL/FR
fusel
2-methyl butyraldehydeFL/FR
green
 cocoa butenalFL/FR
 dihydroxyacetophenone (mixed isomers)FL
2,5-dimethyl thiopheneFL
2-ethyl butyraldehydeFL
 methyl heptadienoneFL/FR
4-methyl thiazoleFL
2-methyl-5-isopropyl pyrazineFL
(E,Z)-2,6-nonadien-1-yl acetateFL/FR
2-vinyl pyrazineFL
herbal
 massoia bark oilFL
honey
 butyl phenyl acetateFL/FR
 ethyl phenyl acetateFL/FR
 phenyl acetaldehydeFL/FR
lactonic
delta-heptalactoneFL/FR
gamma-heptalactoneFL/FR
gamma-octalactoneFL/FR
meaty
2,6-dimethyl pyrazineFL/FR
musty
2,5-dimethyl pyrazineFL/FR
2-ethoxythiazoleFL
 hazelnut pyrazineFL/FR
 menthofuranFL/FR
 shoyu pyrazineFL/FR
2,3,5-trimethyl pyrazineFL/FR
naphthyl
para-methyl anisoleFL/FR
nutty
2-acetyl furanFL/FR
3-acetyl pyridineFL/FR
2-acetyl pyrroleFL/FR
3-acetyl-2,5-dimethyl furanFL/FR
2-acetyl-3-ethyl pyrazineFL/FR
2-acetyl-3-methyl pyrazineFL/FR
2-acetyl-3,5-dimethyl pyrazineFL/FR
2-acetyl-3,5(or 6)-dimethyl pyrazineFL/FR
2-acetyl-5-methyl furanFL/FR
3,5-cocoa pyrazineFL/FR
3,6-cocoa pyrazineFL/FR
 coffee furanoneFL/FR
3,5-diethyl-2-methyl pyrazineFL
2,5-diethyl-3-methyl pyrazineFL
2,3-dimethyl pyrazineFL/FR
4,5-dimethyl-2-ethyl-3-thiazolineFL/FR
2,4-dimethyl-5-vinyl thiazoleFL
2-ethyl pyrazineFL/FR
1-ethyl-2-acetyl pyrroleFL
 filbert heptenoneFL/FR
 filbert pyrazineFL/FR
european hazelnut oleoresinFL
2,6-lutidineFL/FR
2-methoxy-3-methyl pyrazineFL/FR
2-methyl pyrazineFL/FR
5-methyl quinoxalineFL/FR
2-methyl thio-3,5 or 6-methyl pyrazineFL/FR
 nutty cyclohexenoneFL/FR
 nutty pyrazineFL/FR
 nutty quinoxalineFL/FR
 nutty thiazoleFL
 peanut oxazoleFL
2,3,5,6-tetramethyl pyrazineFL/FR
2,4,5-trimethyl thiazoleFL/FR
 vinyl sulfurolFL/FR
popcorn
2-propionyl-2-thiazolineFL
roasted
2-acetyl pyrazineFL/FR
 furfuryl thioacetateFL/FR
smoky
2-methoxy-4-vinyl phenolFL/FR
soapy
1-dodecanolFL/FR
spicy
 mace absoluteFL/FR
 mace oilFL/FR
 mace oleoresinFL/FR
 nutmeg oilFL/FR
 nutmeg oil CO2 extractFL/FR
 nutmeg oil terpenelessFL/FR
 nutmeg oleoresinFL/FR
toasted
 acetyl propionylFL/FR
tonka
gamma-valerolactoneFL/FR
vanilla
 ethyl vanillin isobutyrateFL/FR
 vanillinFL/FR
 vanillyl isobutyrateFL/FR
waxy
 butyl laurateFL/FR
para-cresyl laurateFL/FR
 dihydrojasmone lactoneFL/FR
 ethyl undecanoateFL/FR
 methyl laurateFL/FR
 undecanoic acidFL/FR
whiskey
3-methyl-1-pentanolFL/FR
winey
isoamyl nonanoateFL/FR
5-ethyl-2-methyl pyridineFL
 valeraldehydeFL/FR
 sandalwood oilFL/FR
 whiskey lactoneFL/FR
 
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Potential Uses:
 almond toasted almondFL
 earthFR
 hazelnutFL
 nutFL
 pineappleFL
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Occurrence (nature, food, other): note
 found in nature
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Synonyms:
5-ethoxy-2-methyl pyrazine
5-ethoxy-2-methylpyrazine
2-ethoxy-5-methyl pyrazine
2-ethoxy-5-methylpyrazine
 pyrazine, 2-ethoxy-5-methyl-
 pyrazine, 5-ethoxy-2-methyl
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