Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless to pale yellow clear liquid (est) |
Assay: | 95.00 to 100.00 % sum of isomers
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Food Chemicals Codex Listed: | No |
Boiling Point: | 197.00 to 198.00 °C. @ 760.00 mm Hg
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Boiling Point: | 113.00 to 114.00 °C. @ 50.00 mm Hg
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Vapor Pressure: | 0.515000 mmHg @ 25.00 °C. (est) |
Flash Point: | 150.00 °F. TCC ( 65.56 °C. )
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logP (o/w): | 3.200 (est) |
Soluble in: |
| alcohol | | water, 137.2 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Organoleptic Properties:
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Odor Type: green |
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Odor Strength: | medium |
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| green citrus fruity |
Odor Description: at 100.00 %. | green citrus fruity |
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Odor and/or flavor descriptions from others (if found). |
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Cosmetic Information:
Suppliers:
Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | None - None found. |
S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
oral-mouse LD50 2700 ul/kg
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for dextro-limonene oxide usage levels up to: | | 2.0000 % in the fragrance concentrate.
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Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 24 |
Click here to view publication 24 |
| average usual ppm | average maximum ppm |
baked goods: | - | - |
beverages(nonalcoholic): | 0.10000 | 0.50000 |
beverages(alcoholic): | 0.20000 | 1.00000 |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | 1.00000 | 5.00000 |
condiments / relishes: | - | - |
confectionery froastings: | - | - |
egg products: | - | - |
fats / oils: | - | - |
fish products: | - | - |
frozen dairy: | - | - |
fruit ices: | - | - |
gelatins / puddings: | 0.20000 | 1.00000 |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | 0.50000 | 2.50000 |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | - |
meat products: | - | - |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | - | - |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
Safety References:
References:
| (4R)-1-methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptane |
NIST Chemistry WebBook: | Search Inchi |
Canada Domestic Sub. List: | 203719-54-4 |
Pubchem (cid): | 441245 |
Pubchem (sid): | 9480 |
Other Information:
Potential Blenders and core components note
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For Odor |
No odor group found for these |
| tagete oil rwanda | |
aldehydic |
| dodecanal (aldehyde C-12 lauric) | FL/FR |
(Z)-4- | dodecenal | FL/FR |
| green hexanal | FL/FR |
| undecanal | FL/FR |
anisic |
| amyl furoate | FL/FR |
citrus |
| citral diethyl acetal | FL/FR |
| citral dimethyl acetal | FL/FR |
(R)- | citronellyl nitrile | FR |
| citronitrile (Symrise) | FR |
iso | decyl acetate | FR |
2- | dodecanone | FL/FR |
| lemon verbena oil | |
| limonene aldehyde | FR |
| limonene oxide | FL/FR |
| litsea cubeba fruit oil | FL/FR |
| methyl heptenone | FL/FR |
(Z+E)-2- | methyl-2-(4-methyl-3-pentenyl) cyclopropane carbaldehyde | FL/FR |
1- | methyl-4-methyl ethenyl cyclohexene sulfurized | FL/FR |
alpha- | methylene citronellal | FR |
| petitgrain specialty | FR |
| tangerine acetate | FR |
creamy |
3- | heptyl dihydro-5-methyl-2(3H)-furanone | FL/FR |
earthy |
| spathulenol | |
ethereal |
| ethyl 4-pentenoate | FL/FR |
fatty |
6- | methyl-5-hepten-2-one propylene glycol acetal | FL/FR |
floral |
| aglaia odorata absolute | FR |
iso | amyl angelate | FL/FR |
alpha- | amyl cinnamaldehyde | FL/FR |
| bursera graveolens wood oil | FL/FR |
| cassis cyclohexene | FR |
| citronellol | FL/FR |
| citronellyl acetate | FL/FR |
| coriander seed oil terpeneless | FL/FR |
| dihydrocitronellyl ethyl ether | FR |
| dimethyl benzyl carbinyl butyrate | FL/FR |
| geranyl tiglate | FL/FR |
| jasmin absolute egypt (from concrete) | FL/FR |
| magnolia flower oil CO2 extract | FL/FR |
| menthadienyl formate | FR |
| methyl benzyl acetate (mixed ortho-,meta-,para-) | FL/FR |
| methyl nerate | |
| muguet specialty | FR |
(E)- | nerolidol | FL/FR |
| nonan-3-yl acetate | FL/FR |
| petitgrain fragrance | FR |
| petitgrain oil paraguay | FL/FR |
| terpinyl formate | FL/FR |
(E)-2,5,9- | trimethyl-4,9-decadien-1-al | FR |
fruity |
iso | amyl 2-methyl butyrate | FL/FR |
para- | anisyl propionate | FL/FR |
| balsam specialty | FR |
iso | butyl 2-methyl butyrate | FL/FR |
| ethyl citronellate | FL/FR |
| methyl acetoacetate | FL/FR |
2- | methyl butyl isovalerate | FL/FR |
sesqui | phellandrene | |
| tropical specialty | FR |
green |
iso | butyl heptanoate | FL/FR |
iso | butyl methyl ketone | FL/FR |
| citrus carbaldehyde / methyl anthranilate schiff's base | FR |
black | currant bud absolute replacer | FL/FR |
| dicyclopentadiene propionate | FR |
| green carboxylate | FR |
| herbal cyclohexane | FR |
| hexyl tiglate | FL/FR |
(2- | methoxy-1-methyl butyl) benzene | FR |
| octanal diethyl acetal | FL/FR |
| octanal dimethyl acetal | FL/FR |
(E)-2- | octen-1-ol | FL/FR |
herbal |
iso | amyl heptanoate | FL/FR |
| artemisia ludoviciana oil | FR |
| buchu mercaptan acetate | FL/FR |
| bursera graveolens wood | |
| butyl levulinate | FL/FR |
| chamomile propionate | FR |
| chamomile valerate | FR |
| dimethyl benzyl carbinyl crotonate | FL/FR |
2- | dodecenal | FL/FR |
| linalyl formate | FL/FR |
| marigold absolute (tagetes patula) | FR |
1-para- | menthen-9-yl acetate | FL/FR |
6- | methoxy-2,6-dimethyl octanal | FR |
(1S,5R)- | myrtenyl acetate | FL/FR |
| myrtle oil | FL/FR |
3- | octanon-1-ol | FL/FR |
beta-sesqui | phellandrene | |
| rue flower oil colombia | |
| rue oil | FL/FR |
| rue oil cuba | FL/FR |
| tagete oil CO2 extract | FL/FR |
| tagete oil egypt | FL/FR |
| tagete oil turkey | FL/FR |
| tagete oil zambia | FL/FR |
| tricyclodecenyl isobutyrate | FR |
| tricyclodecenyl propionate | FR |
minty |
laevo- | carvone | FL/FR |
| carvyl acetate | FL/FR |
| dihydrocarveol | FL/FR |
orris |
| orris capronate | FL/FR |
terpenic |
alpha- | phellandrene | FL/FR |
waxy |
| decanal dimethyl acetal | FL/FR |
3- | decanone | FL/FR |
woody |
| bamboo fragrance | FR |
2- | decalinyl acetate | FR |
| humulus lupulus extract | FL/FR |
| patchouli absolute | FR |
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For Flavor |
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No flavor group found for these |
iso | amyl angelate | FL/FR |
| amyl furoate | FL/FR |
para- | anisyl propionate | FL/FR |
| benzyl methyl tiglate | FL |
| bursera graveolens wood | |
| bursera graveolens wood oil | FL/FR |
iso | butyl heptanoate | FL/FR |
beta- | cubebene | FL |
| decanal dimethyl acetal | FL/FR |
3- | decanone | FL/FR |
(±)-(cis+trans)-1,2- | dihydroperillaldehyde | FL |
| dimethyl benzyl carbinyl crotonate | FL/FR |
(Z)-4- | dodecenal | FL/FR |
| ethyl 4-pentenoate | FL/FR |
| lemon verbena oil | |
| limonene oxide | FL/FR |
| linalyl formate | FL/FR |
| magnolia flower oil CO2 extract | FL/FR |
3- | mercaptooctanal | FL |
| methyl acetoacetate | FL/FR |
| methyl benzyl acetate (mixed ortho-,meta-,para-) | FL/FR |
| methyl nerate | |
(Z+E)-2- | methyl-2-(4-methyl-3-pentenyl) cyclopropane carbaldehyde | FL/FR |
6- | methyl-5-hepten-2-one propylene glycol acetal | FL/FR |
| nonan-3-yl acetate | FL/FR |
3- | octanon-1-ol | FL/FR |
beta-sesqui | phellandrene | |
sesqui | phellandrene | |
| rue flower oil colombia | |
| spathulenol | |
| tagete oil rwanda | |
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| althaea officinalis root tincture | FL |
citrus |
| citral diethyl acetal | FL/FR |
| citral dimethyl acetal | FL/FR |
| dehydronootkatone | FL |
| litsea cubeba fruit oil | FL/FR |
1- | methyl-4-methyl ethenyl cyclohexene sulfurized | FL/FR |
creamy |
| althaea officinalis root extract | FL |
dusty |
| ethyl citronellate | FL/FR |
fatty |
2- | dodecanone | FL/FR |
2- | dodecenal | FL/FR |
(E)-2- | octen-1-ol | FL/FR |
floral |
| citronellol | FL/FR |
| citronellyl acetate | FL/FR |
| dimethyl benzyl carbinyl butyrate | FL/FR |
| geranyl tiglate | FL/FR |
| jasmin absolute egypt (from concrete) | FL/FR |
fruity |
iso | amyl 2-methyl butyrate | FL/FR |
| buchu mercaptan acetate | FL/FR |
iso | butyl 2-methyl butyrate | FL/FR |
black | currant bud absolute replacer | FL/FR |
3- | heptyl dihydro-5-methyl-2(3H)-furanone | FL/FR |
1-para- | menthen-9-yl acetate | FL/FR |
2- | methyl butyl isovalerate | FL/FR |
| tagete oil CO2 extract | FL/FR |
| tagete oil turkey | FL/FR |
| tagete oil zambia | FL/FR |
| terpinyl formate | FL/FR |
green |
iso | butyl methyl ketone | FL/FR |
| dihydrocarveol | FL/FR |
(E)-2- | heptenal | FL |
| hexyl tiglate | FL/FR |
| methyl heptenone | FL/FR |
(E)- | nerolidol | FL/FR |
(E,E)-2,6- | nonadienal | FL |
2,4- | octadienal | FL |
| octanal diethyl acetal | FL/FR |
| octanal dimethyl acetal | FL/FR |
herbal |
iso | amyl heptanoate | FL/FR |
| butyl levulinate | FL/FR |
| coriander seed oil terpeneless | FL/FR |
| green hexanal | FL/FR |
| petitgrain oil paraguay | FL/FR |
| rue oil | FL/FR |
| rue oil cuba | FL/FR |
| tagete oil egypt | FL/FR |
minty |
laevo- | carvone | FL/FR |
| carvyl acetate | FL/FR |
orris |
| orris capronate | FL/FR |
soapy |
| dodecanal (aldehyde C-12 lauric) | FL/FR |
spicy |
| myrtle oil | FL/FR |
terpenic |
alpha- | phellandrene | FL/FR |
tropical |
alpha- | amyl cinnamaldehyde | FL/FR |
waxy |
| undecanal | FL/FR |
woody |
| humulus lupulus extract | FL/FR |
(1S,5R)- | myrtenyl acetate | FL/FR |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
7-oxa | bicyclo[4.1.0]heptane, 1-methyl-4-(1-methylethenyl)-, (4R)- (9CI) | D-1,2- | epoxy-p-menth-8-ene | dextro-1,2- | epoxy-para-menth-8-ene | D-1,2- | epoxylimonene | dextro-1,2- | epoxylimonene | (+)- | limonene 1,2-epoxide | D- | limonene 1,2-epoxide | dextro- | limonene 1,2-epoxide | D- | limonene 1,2-oxide | dextro- | limonene 1,2-oxide | D- | limonene epoxide | dextro- | limonene epoxide | D- | limonene monoxide | dextro- | limonene monoxide | (+)- | limonene oxide | D- | limonene oxide | (4R)- | limonene-1,2-epoxide | D-8-p- | menthene-1,2-epoxide | dextro-8-para- | menthene-1,2-epoxide | L-8-p- | menthene-1,2-epoxide | (4R)-1- | methyl-3-(1-methyl ethenyl)-7-oxabicyclo(4.1.0)heptane | (4R)-1- | methyl-3-(1-methyl vinyl)-7-oxabicyclo(4.1.0)heptane | (4R)-1- | methyl-3-(prop-1-en-2-yl)-7-oxabicyclo(4.1.0)heptane | (4R)-1- | methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptane |
Articles:
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