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methane, thiocyanato-
Notes:
None found
| CAS Number: | 556-64-9 |  3D/inchi
|
| ECHA EINECS - REACH Pre-Reg: | 209-134-6 | |
| FDA UNII: | 55I23VY6IE | |
| Nikkaji Web: | J3.296D | |
| Beilstein Number: | 1098357 | |
| MDL: | MFCD00001830 | |
| XlogP3-AA: | 0.90 (est) | |
| Molecular Weight: | 73.11791000 | |
| Formula: | C2 H3 N S | |
| BioActivity Summary: | listing | |
| NMR Predictor: | Predict (works with chrome, Edge or firefox) | |
Category: natural substances and extractives
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
| Google Scholar: | Search |
| Google Books: | Search |
| Google Scholar: with word "volatile" | Search |
| Google Scholar: with word "flavor" | Search |
| Google Scholar: with word "odor" | Search |
| Google Patents: | Search |
| US Patents: | Search |
| EU Patents: | Search |
| Pubchem Patents: | Search |
| PubMed: | Search |
| NCBI: | Search |
Physical Properties:
| Appearance: | colorless to pale yellow clear liquid (est) |
| Assay: | 95.00 to 100.00 % |
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 1.06800 @ 25.00 °C. |
| Boiling Point: | 132.00 to 133.00 °C. @ 760.00 mm Hg |
| Vapor Pressure: | 12.100000 mmHg @ 25.00 °C. |
| Flash Point: | 101.00 °F. TCC ( 38.33 °C. ) |
| logP (o/w): | 0.502 (est) |
| Soluble in: | |
| alcohol | |
| water, 3.22e+004 mg/L @ 25 °C (est) | |
Organoleptic Properties:
| Odor Description: at 0.01 % in propylene glycol. | sulfury onion |
| Odor and/or flavor descriptions from others (if found). | |
Cosmetic Information:
| None found |
Suppliers:
| EMD Millipore |
| For experimental / research use only. |
| Methyl Thiocyanate |
| Sigma-Aldrich: Aldrich |
| For experimental / research use only. |
| Methyl thiocyanate 97% |
Safety Information:
| Preferred SDS: View | |
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| None found. | |
| GHS Label elements, including precautionary statements | |
| Pictogram | |
| Hazard statement(s) | |
| None found. | |
| Precautionary statement(s) | |
| None found. | |
| Oral/Parenteral Toxicity: | |
|
oral-rat LD50 60 mg/kg "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1036, 1986. intravenous-mouse LD50 18 mg/kg U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02864 intraperitoneal-mouse LD50 23 mg/kg Pesticide Biochemistry and Physiology. Vol. 2, Pg. 95, 1972. oral-cat LDLo 8500 ug/kg GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Journal of Industrial Hygiene and Toxicology. Vol. 18, Pg. 310, 1936. | |
| Dermal Toxicity: | |
|
subcutaneous-mouse LDLo 64 mg/kg LUNGS, THORAX, OR RESPIRATION: CYANOSIS LUNGS, THORAX, OR RESPIRATION: DYSPNEA BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Journal of Industrial Hygiene and Toxicology. Vol. 18, Pg. 310, 1936. subcutaneous-rabbit LDLo 20 mg/kg BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS" Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 150, Pg. 257, 1930. skin-rat LDLo 2670 mg/kg BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Journal of Industrial Hygiene and Toxicology. Vol. 18, Pg. 310, 1936. subcutaneous-rat LDLo 30 mg/kg BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD LUNGS, THORAX, OR RESPIRATION: DYSPNEA LUNGS, THORAX, OR RESPIRATION: CYANOSIS Journal of Industrial Hygiene and Toxicology. Vol. 18, Pg. 310, 1936. | |
| Inhalation Toxicity: | |
| Not determined | |
Safety in Use Information:
| Category: | natural substances and extractives | ||
| Recommendation for methyl thiocyanate usage levels up to: | |||
| not for fragrance use. | |||
| Recommendation for methyl thiocyanate flavor usage levels up to: | |||
| not for flavor use. | |||
Safety References:
| EPI System: | View |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA Substance Registry Services (TSCA): | 556-64-9 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 11168 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WGK Germany: | 3 |
| methyl thiocyanate | |
| Chemidplus: | 0000556649 |
| EPA/NOAA CAMEO: | hazardous materials |
| RTECS: | XL1575000 for cas# 556-64-9 |
References:
| methyl thiocyanate | |
| NIST Chemistry WebBook: | Search Inchi |
| Pubchem (cid): | 11168 |
| Pubchem (sid): | 134976879 |
| Flavornet: | 556-64-9 |
Other Information:
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| CHEBI: | View |
| HMDB (The Human Metabolome Database): | Search |
| FooDB: | FDB013885 |
| Export Tariff Code: | 2930.90.5050 |
| VCF-Online: | VCF Volatile Compounds in Food |
| ChemSpider: | View |
| Wikipedia: | View |
| Formulations/Preparations: 99% colorless liquid grade | |
Potential Blenders and core components note
| None Found | ||
Potential Uses:
| None Found |
Occurrence (nature, food, other): note
| papaya fruit Search Trop Picture |
Synonyms:
| methane, thiocyanato- | |
| methyl rhodanate | |
| methyl sulfocyanate | |
| ( | methyl thio) cyanate |
| ( | methylthio)cyanate |
| methylthiocyanate | |
| thiocyanatomethane | |
| thiocyanic acid methyl ester | |
| thiocyanic acid, methyl ester |