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bitter citrus aurantium peel oil rectified (furo coumarin reduced)
Notes:
tsca definition 2008: extractives and their physically modified derivatives. citrus aurantium, var. amara, citrus.
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Fleurchem, Inc. Have A Flavorful Day A leading global manufacturer and supplier of ingredients for Flavors, Fragrances, AromaTherapy, Foods, Beverages, Personal Care Products, and other uses. Operating out of the 200,000 sq. ft., former Hercules/PFW facility in Middletown, NY; Fleurchem produces a full range of natural isolates, synthetic chemicals & specialities, essential oils and flavors. Additionally, the company performs toll manufacturing, as well as custom chemical synthesis for a wide range of clients. Email: Information US Voice: 845-341-2100 US Fax: 845-341-2121 Product(s): bitter orange oil (furo coumarin free)
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| Fragrance Demo Formulas Flavor Demo Formulas | ||
| Name: | citrus aurantium l. peel oil bitter rectified (furo coumarin reduced) | |
| CAS Number: | 68916-04-1 | |
Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
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| FEMA Number: | 2823 bitter orange peel oil rectified (furo coumarin reduced) |
| FDA: | No longer provide for the use of these seven synthetic flavoring substances |
| FDA Mainterm (SATF): | 68916-04-1 ; ORANGE PEEL, BITTER, OIL (CITRUS AURANTIUM L.) |
| FDA Regulation: | |
| FDA PART 182 -- SUBSTANCES GENERALLY RECOGNIZED AS SAFE Subpart A--General Provisions Sec. 182.20 Essential oils, oleoresins (solvent-free), and natural extractives (including distillates). | |
Physical Properties:
| Appearance: | colorless clear liquid (est) |
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.83580 to 0.84580 @ 25.00 °C. |
| Pounds per Gallon - (est).: | 6.955 to 7.038 |
| Refractive Index: | 1.46600 to 1.47600 @ 20.00 °C. |
| Optical Rotation: | +93 to +99.75 |
| Flash Point: | 120.00 °F. TCC ( 48.89 °C. ) |
| Soluble in: | |
| alcohol | |
| paraffin oil | |
| water, 4.581 mg/L @ 25 °C (est) | |
| Insoluble in: | |
| water | |
| propylene glycol | |
Organoleptic Properties:
| Odor Type: citrus | |
| Odor Strength: | medium |
| fresh citrus bitter orange floral orange peel | |
| Odor Description: at 100.00 %. | fresh citrus bitter orange floral Luebke, William tgsc, (1998) |
| Flavor Type: citrus | |
| orange orange peel | |
| Taste Description: | orange |
| Odor and/or flavor descriptions from others (if found). | |
Cosmetic Information:
| CosIng: | cosmetic data |
| Cosmetic Uses: |
fragrance skin conditioning tonic |
Suppliers:
Safety Information:
| European information : | |
| Most important hazard(s): | |
| Xi - Irritant | |
|
R 10 - Flammable. R 38 - Irritating to skin. S 02 - Keep out of the reach of children. S 16 - Keep away from sources of ignition - No Smoking. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing. | |
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| Flammable liquids (Category 3), H226 Skin irritation (Category 2), H315 | |
| GHS Label elements, including precautionary statements | |
| Pictogram |   |
| Signal word | Warning |
| Hazard statement(s) | |
| H226 - Flammable liquid and vapour H315 - Causes skin irritation | |
| Precautionary statement(s) | |
| P210 - Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/…/equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P264 - Wash skin thouroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P321 - Specific treatment (see supplemental first aid instructions on this label). P332 + P313 - IF SKIN irritation occurs: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P403 + P235 - Store in a well-ventilated place. Keep cool. P501 - Dispose of contents/ container to an approved waste disposal plant. | |
| Oral/Parenteral Toxicity: | |
|
oral-rat LD50 > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 12, Pg. 735, 1974. | |
| Dermal Toxicity: | |
|
skin-rabbit LD50 > 10000 mg/kg Food and Cosmetics Toxicology. Vol. 12, Pg. 735, 1974. | |
| Inhalation Toxicity: | |
| Not determined | |
Safety in Use Information:
| Category: | flavor and fragrance agents | ||
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
| IFRA Critical Effect: | Phototoxicity | ||
| IFRA fragrance material specification: | |||
| Where the bergapten (5-methoxypsoralen) content of all relevant oils present in a compound has been determined, it is recommended that for applications on areas of skin exposed to sunshine, excluding bath preparations, soaps and other products which are washed off the skin, the total level of bergapten in the consumer products should not exceed 0.0015% (15 ppm). This is equivalent to 0.0075% (75 ppm) in a fragrance compound used at 20% in the consumer product. Where the level of bergapten has not been determined by appropriate methods, the limits specified in the guidelines on individual oils should apply. In those cases, where such oils are used in combination with other phototoxic ingredients, the additive effect has to be taken into consideration and the use levels have to be reduced accordingly. The sum of the concentrations of all phototoxic fragrance ingredients, expressed in % of their recommended maximum level in the consumer product, shall not exceed 100. | |||
| contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only) | |||
| citral | Max. Found: 0.1 % and Reason: Sensitization | ||
| geraniol | Max. Found: 0.04 % and Reason: Sensitization | ||
| perillaldehyde | Max. Found: 0.02 % and Reason: Sensitization | ||
| IFRA: | View Standard | ||
| View IFRA Standards Library for complete information. | |||
| Please review Amendment 49 IFRA documentation for complete information. | |||
| IFRA RESTRICTION LIMITS IN THE FINISHED PRODUCT (%): | |||
| Category 1: Products applied to the lips | |||
| 1.25 % | |||
| Category 2: Products applied to the axillae | |||
| 1.25 % | |||
| Category 3: Products applied to the face/body using fingertips | |||
| 1.25 % | |||
| Category 4: Products related to fine fragrance | |||
| 1.25 % | |||
| Category 5: Products applied to the face and body using the hands (palms), primarily leave-on | |||
| Category 5A: Body lotion products applied to the body using the hands (palms), primarily leave-on | |||
| 1.25 % | |||
| Category 5B: Face moisturizer products applied to the face using the hands (palms), primarily leave-on | |||
| 1.25 % | |||
| Category 5C: Hand cream products applied to the hands using the hands (palms), primarily leave-on | |||
| 1.25 % | |||
| Category 5D: Baby Creams, baby Oils and baby talc | |||
| 1.25 % | |||
| Category 6: Products with oral and lip exposure | |||
| 1.25 % | |||
| Category 7: Products applied to the hair with some hand contact | |||
| Category 7A: Rinse-off products applied to the hair with some hand contact | |||
| No Restriction % | |||
| Category 7B: Leave-on products applied to the hair with some hand contact | |||
| 1.25 % | |||
| Category 8: Products with significant anogenital exposure | |||
| 1.25 % | |||
| Category 9: Products with body and hand exposure, primarily rinse off | |||
| No Restriction % | |||
| Category 10: Household care products with mostly hand contact | |||
| Category 10A: Household care excluding aerosol products (excluding aerosol/spray products) | |||
| No Restriction % | |||
| Category 10B: Household aerosol/spray products | |||
| 1.25 % | |||
| Category 11: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate | |||
| Category 11A: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure | |||
| No Restriction % | |||
| Category 11B: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure | |||
| 1.25 % | |||
| Category 12: Products not intended for direct skin contact, minimal or insignificant transfer to skin | |||
| No Restriction | |||
| Notes: | |||
| IFRA FLAVOR REQUIREMENTS: | |||
Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards. | |||
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). | |||
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library | |||
| publication number: 3 | |||
| Click here to view publication 3 | |||
| average usual ppm | average maximum ppm | ||
| baked goods: | - | 110.00000 | |
| beverages(nonalcoholic): | - | 67.00000 | |
| beverages(alcoholic): | - | 4.00000 | |
| breakfast cereal: | - | - | |
| cheese: | - | - | |
| chewing gum: | - | 500.00000 | |
| condiments / relishes: | - | - | |
| confectionery froastings: | - | - | |
| egg products: | - | - | |
| fats / oils: | - | - | |
| fish products: | - | - | |
| frozen dairy: | - | 71.00000 | |
| fruit ices: | - | 71.00000 | |
| gelatins / puddings: | - | 300.00000 | |
| granulated sugar: | - | - | |
| gravies: | - | - | |
| hard candy: | - | 150.00000 | |
| imitation dairy: | - | - | |
| instant coffee / tea: | - | - | |
| jams / jellies: | - | - | |
| meat products: | - | - | |
| milk products: | - | - | |
| nut products: | - | - | |
| other grains: | - | - | |
| poultry: | - | - | |
| processed fruits: | - | - | |
| processed vegetables: | - | - | |
| reconstituted vegetables: | - | - | |
| seasonings / flavors: | - | - | |
| snack foods: | - | - | |
| soft candy: | - | - | |
| soups: | - | - | |
| sugar substitutes: | - | - | |
| sweet sauces: | - | - | |
Safety References:
| EPI System: | View |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA Substance Registry Services (TSCA): | 68916-04-1 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| National Institute of Allergy and Infectious Diseases: | Data |
| WGK Germany: | 2 |
| citrus aurantium l. peel oil bitter rectified (furo coumarin reduced) | |
| Chemidplus: | 0068916041 |
References:
| citrus aurantium l. peel oil bitter rectified (furo coumarin reduced) | |
| Canada Domestic Sub. List: | 68916-04-1 |
| Pubchem (sid): | 135326045 |
Other Information:
| FDA Substances Added to Food (formerly EAFUS): | View |
| Export Tariff Code: | 3301.12.0000 |
| MedlinePlusSupp: | View |
| Wikipedia: | View |
| FAO: | BASIC PRINCIPLES OF STEAM DISTILLATION |
Potential Blenders and core components note
Potential Uses:
| aldehydic | FR | |
| amber | FR | |
| bergamot | FR | |
| cedrat | FR | |
| citrus | FR | |
| fern | FR | |
| fixer | ||
| floral | FR | |
| grapefruit | FR | |
| green | FR | |
| leaf | ||
| orange | FR | |
| oriental | FR | |
| tea | FL | |
| violet | FR | |
| wine madeira wine | FL | |
| woody | FR |
Occurrence (nature, food, other): note
| citrus aurantium Search Trop Picture |
Synonyms:
| bitter | citrus aurantium peel oil rectified (furo coumarin reduced) |
| oil bitter orange dominican rectified (furo coumarin reduced) | |
| bitter | orange (fruit) distilled oil |
| bitter | orange oil (furo coumarin free) |
| bitter | orange oil rectified (furo coumarin free) dominican |
| orange oil, bitter non-sensitizing | |
| bitter | orange peel oil rectified (furo coumarin reduced) |