(Z)-cinnamaldehyde
(2Z)-3-phenylacrylaldehyde
 
Notes:
Cinnamaldehyde is the organic compound that gives cinnamon its flavor and odor. This pale yellow viscous liquid occurs naturally in the bark of cinnamon trees and other species of the genus Cinnamomum. The essential oil of cinnamon bark is about 90% cinnamaldehyde. (Wikipedia)
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CAS Number: 57194-69-1Picture of molecule3D/inchi
FDA UNII: W3HD274KF5
Nikkaji Web: J918.664F
XlogP3: 1.90 (est)
Molecular Weight: 132.16196000
Formula: C9 H8 O
NMR Predictor: Predict (works with chrome or firefox)
Category: flavor and fragrance agents
 
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Physical Properties:
Appearance: pale yellow to yellow clear liquid (est)
Assay: 94.00 to 100.00 % 
Food Chemicals Codex Listed: No
Boiling Point: 245.00 to  246.00 °C. @ 760.00 mm Hg
Vapor Pressure: 0.027000 mmHg @ 25.00 °C. (est)
Flash Point: 160.00 °F. TCC ( 71.11 °C. )
logP (o/w): 2.123 (est)
Soluble in:
 alcohol
 water, very slightly
 water, 2150 mg/L @ 25 °C (est)
Insoluble in:
 water
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Organoleptic Properties:
 
Odor Type: spicy
 
Odor Strength: medium ,
recommend smelling in a 10.00 % solution or less
 
 spicy  cinnamon  
Odor Description:
at 10.00 % in dipropylene glycol. 
spicy cinnamon
 
 
Flavor Type: spicy
 
 cinnamon  
Taste Description:
cinnamon
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
None found
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Suppliers:
 None found
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Safety Information:
European information :
Most important hazard(s):
Xn - Harmful.
R 21/41 - Harmful in contact with skin, risk of serious damage to eyes.
R 38 - Irritating to skin.
R 43 - May cause sensitisation by skin contact.
S 02 - Keep out of the reach of children.
S 24 - Avoid contact with skin.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: flavor and fragrance agents
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
IFRA Critical Effect: Sensitization
IFRA fragrance material specification:
 The concentration of Cinnamic aldehyde in the finished cosmetic product should not exceed 0.1%.
View IFRA Standards Library for complete information.
Please review Amendment 49 IFRA documentation for complete information.
IFRA RESTRICTION LIMITS IN THE FINISHED PRODUCT (%):
Category 1: Products applied to the lips
0.02 %
Category 2: Products applied to the axillae
0.02 %
Category 3: Products applied to the face/body using fingertips
0.05 %
Category 4: Products related to fine fragrance
0.05 %
 Category 5: Products applied to the face and body using the hands (palms), primarily leave-on
Category 5A: Body lotion products applied to the body using the hands (palms), primarily leave-on
0.05 %
Category 5B: Face moisturizer products applied to the face using the hands (palms), primarily leave-on
Category 5C: Hand cream products applied to the hands using the hands (palms), primarily leave-on
Category 5D: Baby Creams, baby Oils and baby talc
Category 6: Products with oral and lip exposure
0.40 %
 Category 7: Products applied to the hair with some hand contact
Category 7A: Rinse-off products applied to the hair with some hand contact
0.40 %
Category 7B: Leave-on products applied to the hair with some hand contact
Category 8: Products with significant anogenital exposure
0.05 %
Category 9: Products with body and hand exposure, primarily rinse off
0.05 %
 Category 10: Household care products with mostly hand contact
Category 10A: Household care excluding aerosol products (excluding aerosol/spray products)
0.05 %
Category 10B: Household aerosol/spray products
 Category 11: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate
Category 11A: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
See Note %
Category 11B: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
Category 12: Products not intended for direct skin contact, minimal or insignificant transfer to skin
 Notes:
IFRA FLAVOR REQUIREMENTS:

Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards.

 

For this material, for pragmatic reasons, restrictive levels allowed by the QRA for certain categories but actually being higher than those already in place before applying the QRA, will temporarily not be implemented until the end of a 5 year monitoring phase. At the end of the 5 years the position will be reevaluated again.

 

(1) IFRA would recommend that any material used to impart perfume or flavour in products intended for human ingestion should consist of ingredients that are in compliance with appropriate regulations for foods and food flavourings in the countries of planned distribution and, where these are lacking, with the recommendations laid down in the Code of Practice of IOFI (International Organisation of the Flavor Industry). Further information about IOFI can be found on its website (www.iofi.org).

 

(2) Category 11 includes all non-skin contact or incidental skin contact products. Due to the negligible skin contact from these types of products there is no justification for a restriction of the concentration of this fragrance ingredient in the finished product.

 
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Safety References:
EPI System: View
AIDS Citations: Search
Cancer Citations: Search
Toxicology Citations: Search
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 6428995
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 3
 (Z)-3-phenylprop-2-enal
Chemidplus: 0057194691
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References:
 (Z)-3-phenylprop-2-enal
NIST Chemistry WebBook: Search Inchi
Pubchem (cid): 6428995
Pubchem (sid): 135157648
Pherobase: View
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
CHEBI: View
CHEMBL: View
HMDB (The Human Metabolome Database): HMDB32072
FooDB: FDB008783
Export Tariff Code: 2912.29.5000
Typical G.C.
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
Wikipedia: View
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Potential Blenders and core components note
 
For Odor
aldehydic
aldehydic
 dodecanal (aldehyde C-12 lauric)FL/FR
10-undecenal (aldehyde C-11 undecylenic)FL/FR
anisic
para-anisaldehydeFL/FR
balsamic
isoamyl benzoateFL/FR
 amyris wood oilFL/FR
siam benzoin resinoidFL/FR
 benzyl cinnamateFL/FR
 benzyl salicylateFL/FR
isobornyl acetateFL/FR
 cinnamyl cinnamateFL/FR
 cinnamyl formateFL/FR
 ethyl cinnamateFL/FR
 linalyl cinnamateFL/FR
 peru balsam oilFL/FR
 peru balsam resinoidFL/FR
2-phenoxyethyl formateFR
3-phenyl propyl alcoholFL/FR
berry
 raspberry ketoneFL/FR
caramellic
 strawberry furanoneFL/FR
citrus
 bergamot oil bergaptene reduced italyFL/FR
 citronitrile (Symrise)FR
blood orange oil italyFL/FR
coconut
gamma-nonalactone (aldehyde C-18 (so-called))FL/FR
gamma-octalactoneFL/FR
floral
 acetophenoneFL/FR
alpha-amyl cinnamaldehydeFL/FR
 benzyl acetateFL/FR
 citronellolFL/FR
 floral pyranolFR
 heliotropinFL/FR
 leerallFR
 ocean propanalFL/FR
 petitgrain oil paraguayFL/FR
 phenethyl alcoholFL/FR
 phenethyl propionateFL/FR
3-phenyl propionic acidFL/FR
3-phenyl propyl formateFL/FR
fruity
 benzyl propionateFL/FR
gamma-decalactoneFL/FR
para-tolualdehydeFL/FR
green
 biphenyl 
3-hexenalFL/FR
 sorbyl isobutyrateFL/FR
herbal
 carum carvi fruit oilFL/FR
 lavender absolute bulgariaFL/FR
honey
 methyl hydrocinnamateFL/FR
mossy
 veramoss (IFF)FR
phenolic
2'-hydroxyacetophenoneFL/FR
powdery
para-anisyl alcoholFL/FR
spicy
 allspice berry absoluteFL/FR
 allspice leaf oilFL/FR
 allspice leaf oil terpenelessFL/FR
 allspice oilFL/FR
 allspice oleoresinFL/FR
 apple spice fragranceFR
 canella bark oilFR
 canella winterana 
 cassia bark concreteFR
saigon cassia bark oilFL/FR
 cassia bark oil chinaFL/FR
 cassia bark oil CO2 extractFL/FR
 cassia bark oil indonesiaFL/FR
 cassia bark oil replacerFL/FR
 cassia bark oleoresinFL/FR
 cassia buds 
 cassia fragranceFR
 cassia leaf oilFL/FR
 cassia oil terpenesFR
 cinnamaldehydeFL/FR
(E)-cinnamaldehydeFL/FR
 cinnamaldehyde / methyl anthranilate schiff's baseFR
 cinnamaldehyde butylene glycol acetal 
 cinnamaldehyde diethyl acetalFL/FR
 cinnamaldehyde dimethyl acetalFL/FR
 cinnamaldehyde ethylene glycol acetalFL/FR
 cinnamaldehyde propylene glycol acetalFL/FR
 cinnamomum cassia bark absoluteFL/FR
 cinnamomum cassia bark extractFL/FR
 cinnamomum cassia leaf extractFR
 cinnamomum cassia oilFL/FR
 cinnamomum cassia tinctureFL/FR
 cinnamomum verum bark extract ceylonFL/FR
 cinnamomum verum waterFL/FR
 cinnamomum zeylanicum bark powderCS
 cinnamomum zeylanicum leaf extract ceylonFR
 cinnamon acroleinFL/FR
 cinnamon bark oilFL/FR
 cinnamon bark oil (cinnamomum zeylanicum) indiaFL/FR
 cinnamon bark oil (cinnamomum zeylanicum) sri laukaFL/FR
 cinnamon bark oil ceylonFL/FR
 cinnamon bark oil CO2 extractFL/FR
 cinnamon bark oil replacerFR
 cinnamon cookie fragranceFR
 cinnamon fragranceFR
 cinnamon fruit oil indiaFR
 cinnamon infusionsFL/FR
 cinnamon leaf oil ceylonFL/FR
 cinnamon leaf oil replacerFR
 cinnamon oleoresin ceylonFL/FR
 cinnamon twig oil indiaFL/FR
 cinnamyl acetateFL/FR
(E)-cinnamyl nitrileFR
 cinnamyl nitrileFR
 clove bud oilFL/FR
 croton eluteria bark oilFL/FR
 eugenolFL/FR
3-(2-furyl) acroleinFL/FR
 levisticum officinale root oilFL/FR
para-methoxy-alpha-methyl cinnamaldehydeFL/FR
para-methoxycinnamaldehydeFL/FR
ortho-methoxycinnamaldehydeFL/FR
(E)-para-methoxycinnamaldehydeFL/FR
alpha-methyl cinnamaldehydeFL/FR
 methyl eugenolFR
 methyl heptadienoneFL/FR
 methyl isoeugenolFL/FR
alpha-methyl-(E)-cinnamaldehydeFL/FR
 myrtenalFL/FR
 spicy acetoacetateFL/FR
 tonka bean absoluteFR
vanilla
 ethyl vanillinFL/FR
 vanillinFL/FR
woody
 cyperus root oil (cyperus scariosus)FR
 guaiacwood oilFL/FR
 patchouli ethanoneFR
 patchouli oilFL/FR
 santallFR
 
For Flavor
 
No flavor group found for these
 cinnamaldehyde butylene glycol acetal 
2-furfurylidene butyraldehydeFL
3-(2-furyl) acroleinFL/FR
para-methoxy-alpha-methyl cinnamaldehydeFL/FR
(E)-para-methoxycinnamaldehydeFL/FR
 methyl hydrocinnamateFL/FR
3-phenyl propionic acidFL/FR
3-phenyl propyl formateFL/FR
 sorbyl isobutyrateFL/FR
balsamic
siam benzoin resinoidFL/FR
 benzyl salicylateFL/FR
 ethyl cinnamateFL/FR
 peru balsam oilFL/FR
 peru balsam resinoidFL/FR
berry
 raspberry ketoneFL/FR
caramellic
 strawberry furanoneFL/FR
cherry
 heliotropinFL/FR
para-methoxycinnamaldehydeFL/FR
citrus
 bergamot oil bergaptene reduced italyFL/FR
blood orange oil italyFL/FR
coconut
gamma-nonalactone (aldehyde C-18 (so-called))FL/FR
cookie
cinnamon sugar cookie flavorFL
creamy
para-anisaldehydeFL/FR
 dihydrocoumarinFL
fatty
10-undecenal (aldehyde C-11 undecylenic)FL/FR
floral
 biphenyl 
 citronellolFL/FR
 ocean propanalFL/FR
 phenethyl alcoholFL/FR
 phenethyl propionateFL/FR
fruity
isoamyl benzoateFL/FR
para-anisyl alcoholFL/FR
 benzyl acetateFL/FR
 benzyl propionateFL/FR
gamma-decalactoneFL/FR
 linalyl cinnamateFL/FR
green
3-hexenalFL/FR
 methyl heptadienoneFL/FR
herbal
 carum carvi fruit oilFL/FR
 lavender absolute bulgariaFL/FR
 petitgrain oil paraguayFL/FR
lactonic
gamma-octalactoneFL/FR
minty
 myrtenalFL/FR
(1R)-(-)-myrtenalFL
naphthyl
2'-hydroxyacetophenoneFL/FR
nutty
 furfural acetoneFL
powdery
 acetophenoneFL/FR
soapy
 dodecanal (aldehyde C-12 lauric)FL/FR
spicy
 allspice berry absoluteFL/FR
 allspice flavorFL
 allspice leaf oilFL/FR
 allspice leaf oil terpenelessFL/FR
 allspice oilFL/FR
 allspice oleoresinFL/FR
 apple cinnamon french toast flavorFL
 benzyl cinnamateFL/FR
 benzylidene acetoneFL
 blueberry cinnamon crumble flavorFL
 canella winterana 
saigon cassia bark oilFL/FR
 cassia bark oil chinaFL/FR
 cassia bark oil CO2 extractFL/FR
 cassia bark oil indonesiaFL/FR
 cassia bark oil replacerFL/FR
 cassia bark oleoresinFL/FR
 cassia buds 
 cassia flavorFL
 cassia leaf oilFL/FR
 chocolate cinnamon hazelnut flavorFL
 cinnamaldehydeFL/FR
(E)-cinnamaldehydeFL/FR
 cinnamaldehyde diethyl acetalFL/FR
 cinnamaldehyde dimethyl acetalFL/FR
 cinnamaldehyde ethylene glycol acetalFL/FR
 cinnamaldehyde propylene glycol acetalFL/FR
 cinnamomum burmannii extract padang or bataviaFL
 cinnamomum cassia bark absoluteFL/FR
 cinnamomum cassia bark extractFL/FR
 cinnamomum cassia bark powderFL
 cinnamomum cassia oilFL/FR
 cinnamomum cassia tinctureFL/FR
saigon cinnamomum loureirii bark extractFL
 cinnamomum verum bark extract ceylonFL/FR
 cinnamomum verum waterFL/FR
 cinnamonFL
 cinnamon acroleinFL/FR
 cinnamon bark oilFL/FR
 cinnamon bark oil (cinnamomum zeylanicum) indiaFL/FR
 cinnamon bark oil (cinnamomum zeylanicum) sri laukaFL/FR
 cinnamon bark oil ceylonFL/FR
 cinnamon bark oil CO2 extractFL/FR
 cinnamon butter pecan flavorFL
toasted cinnamon cashew flavorFL
 cinnamon flavorFL
red hot cinnamon flavorFL
 cinnamon hazelnut cappuccino flavorFL
 cinnamon hazelnut cream flavorFL
 cinnamon infusionsFL/FR
 cinnamon leaf oil ceylonFL/FR
 cinnamon nut butter rum flavorFL
 cinnamon nut cream flavorFL
 cinnamon oleoresin ceylonFL/FR
toasted cinnamon pecan flavorFL
 cinnamon powderFL
 cinnamon twig oil indiaFL/FR
 cinnamyl acetateFL/FR
 cinnamyl cinnamateFL/FR
 cinnamyl formateFL/FR
 clove bud oilFL/FR
 croton eluteria bark oilFL/FR
 eugenolFL/FR
 levisticum officinale root oilFL/FR
ortho-methoxycinnamaldehydeFL/FR
alpha-methyl cinnamaldehydeFL/FR
 methyl isoeugenolFL/FR
alpha-methyl-(E)-cinnamaldehydeFL/FR
3-phenyl propyl alcoholFL/FR
 spicy acetoacetateFL/FR
cinnamon tea flavorFL
para-tolualdehydeFL/FR
tropical
alpha-amyl cinnamaldehydeFL/FR
vanilla
 ethyl vanillinFL/FR
 vanillinFL/FR
woody
 amyris wood oilFL/FR
isobornyl acetateFL/FR
 guaiacwood oilFL/FR
 patchouli oilFL/FR
 
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Potential Uses:
 allspiceFR
 almondFR
 apricotFR
 aramis 
 balsamFR
 bananaFR
 brut 
 bubble gumFR
 butterscotchFR
 canoe 
 carnationFR
 cassiaFR
 catsupFL
 cherryFR
 cherry wild cherryFL
 chocolate cacaoFL
 cinnabar 
 cinnamonFR
 colaFL
 cranberryFR
 dateFR
 floralFR
 florida soapFR
 foliageFR
 grenadineFL
 halston 
 herbalFR
 hyacinthFR
 l'air du temps 
 l'origan 
 millefleursFR
 mintFR
 myrrhFR
 norell 
 old spice 
 opium 
 orientalFR
 paco rabanne 
 patchouliFR
 pierre cardin 
 plumFR
 potpourriFR
 raspberryFR
 roseFR
 sassafrasFR
 sensen 
 sesameFL
 spiceFR
 strawberryFR
 tonka beanFR
 tuberoseFR
 valerianFL/FR
 vanillaFR
 windsor soapFR
 youth dew 
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Occurrence (nature, food, other): note
 cinnamomum fragrans baillon leaf oil madagascar @ 0.90%
Data  GC  Search Trop  Picture
 cinnamon bark oil (cinnamomum zeylanicum blume) sri lauka @ 0.12-0.98%
Data  GC  Search Trop  Picture
 cinnamon ceylon cinnamon leaf
Search Trop  Picture
 cinnamon fruit oil india @ 0.2-0.3%
Data  GC  Search Trop  Picture
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Synonyms:
cis-cinnamaldehyde
(Z)-cinnamic aldehyde
cis-cinnamic aldehyde
(2Z)-3-phenylacrylaldehyde
(Z)-3-phenylprop-2-enal
2-propenal, 3-phenyl-, (2Z)-
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