Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless to pale yellow clear liquid (est) |
Assay: | 95.00 to 100.00 % sum of isomers
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 0.89600 to 0.90400 @ 25.00 °C.
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Pounds per Gallon - (est).: | 7.456 to 7.522
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Specific Gravity: | 0.89700 to 0.90500 @ 20.00 °C.
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Pounds per Gallon - est.: | 7.473 to 7.539
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Refractive Index: | 1.46400 to 1.46800 @ 20.00 °C.
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Boiling Point: | 216.00 °C. @ 760.00 mm Hg
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Vapor Pressure: | 0.458000 mmHg @ 25.00 °C. (est) |
Flash Point: | 180.00 °F. TCC ( 82.22 °C. )
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logP (o/w): | 3.540 |
Shelf Life: | 24.00 month(s) or longer if stored properly. |
Storage: | store in cool, dry place in tightly sealed containers, protected from heat and light. |
Soluble in: |
| alcohol | | water, 22.61 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Stability: |
| alcoholic lotion | | antiperspirant | | bleach | | deo stick | | detergent | | fabric softener | | shampoo | | soap |
Organoleptic Properties:
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Odor Type: citrus |
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Odor Strength: | medium |
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Substantivity: | < 4 hour(s) at 100.00 % |
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| citrus grapefruit bergamot orangeflower vegetable celery spicy earthy |
Odor Description: at 100.00 %. | citrus grapefruit bergamot orangeflower vegetable celery spicy earthy |
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Flavor Type: woody |
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| woody celery earthy sweet spicy |
Taste Description:
| woody celery earthy sweet spicy |
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Odor and/or flavor descriptions from others (if found). |
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IFF |
Orange Flower Ether |
Odor Description: | Citrus (grapefruit) note also reminiscent of bergamot. Occurs naturally in orange flowers |
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Taytonn ASCC |
Orange Flower Ether |
Odor Description: | citrus grapefruit bergamot orangeflower |
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Pell Wall Perfumes |
Orange Flower Ether |
Odor Description: | Citrus-grapefruit and bergamot, fresh, neroli, orange flower Very nice top-note that adds a floral quality as well as citrus: distinctly grapefruit in character.
Original IFF material “Description from IFF: Citrus (grapefruit) note also reminiscent of bergamot. Occurs naturally in orange flowers.” |
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Cosmetic Information:
Suppliers:
Azelis UK |
ORANGE FLOWER ETHER
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BOC Sciences |
For experimental / research use only. |
4-(1-Methoxy-1-methylethyl)-1-methylcyclohexene
|
Creatingperfume.com |
Orange Flower Ether (IFF)
Odor: Citrus (grapefruit) note also reminiscent of bergamot |
Ernesto Ventós |
ORANGE FLOWER ETHER IFF
Odor: CITRIC, GRAPEFRUIT, FLORAL, NEROLI |
Ernesto Ventós |
TERPINYL METHYL ETHER
Odor: FLORAL, ORANGE BLOSSOM |
IFF |
Orange Flower Ether
Odor: Citrus (grapefruit) note also reminiscent of bergamot. Occurs naturally in orange flowers |
Indukern F&F |
ORANGE FLOWER ETHER
Odor: CITRUS, GRAPEFRUIT, FLORAL, NEROLI |
Kun Shan P&A |
Orange flower ether
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Lluch Essence |
TERPINYL METHYL ETHER
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M&U International |
Orange Flower Ether(IFF# : 202929)
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Pell Wall Perfumes |
Orange Flower Ether
Odor: Citrus-grapefruit and bergamot, fresh, neroli, orange flower Use: Very nice top-note that adds a floral quality as well as citrus: distinctly grapefruit in character.
Original IFF material “Description from IFF: Citrus (grapefruit) note also reminiscent of bergamot. Occurs naturally in orange flowers.” |
Penta International |
ORANGE FLOWER ETHER
|
Perfumer Supply House |
Orange Flower Ether (Terpinyl Methyl Ether)
Odor: Citrus, floral, grapefruit, bergamot, orange blossom |
Reincke & Fichtner |
Terpinyl Methyl Ether
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Taytonn ASCC |
Orange Flower Ether
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The John D. Walsh Company |
Orange Flower Ether
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Tianjin Danjun International |
Alpha-terpinyl methyl ether
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Safety Information:
European information : |
Most important hazard(s): | Xi - Irritant |
R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
Not determined
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for alpha-terpinyl methyl ether usage levels up to: | | 5.0000 % in the fragrance concentrate.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 4.10 (μg/capita/day) |
Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 3200 (μg/person/day) |
Threshold of Concern: | 90 (μg/person/day) |
Structure Class: | III |
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Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). |
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. |
| average usage mg/kg | maximum usage mg/kg |
Dairy products, excluding products of category 02.0 (01.0): | 3.00000 | 15.00000 |
Fats and oils, and fat emulsions (type water-in-oil) (02.0): | 2.00000 | 10.00000 |
Edible ices, including sherbet and sorbet (03.0): | 3.00000 | 15.00000 |
Processed fruit (04.1): | 2.00000 | 10.00000 |
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | - | - |
Confectionery (05.0): | 10.00000 | 50.00000 |
Chewing gum (05.0): | - | - |
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 5.00000 | 25.00000 |
Bakery wares (07.0): | 10.00000 | 50.00000 |
Meat and meat products, including poultry and game (08.0): | 2.00000 | 10.00000 |
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | 2.00000 | 10.00000 |
Eggs and egg products (10.0): | - | - |
Sweeteners, including honey (11.0): | - | - |
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 5.00000 | 25.00000 |
Foodstuffs intended for particular nutritional uses (13.0): | 10.00000 | 50.00000 |
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | 3.00000 | 15.00000 |
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 10.00000 | 50.00000 |
Ready-to-eat savouries (15.0): | 15.00000 | 75.00000 |
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | 5.00000 | 25.00000 |
Safety References:
European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 23 (FGE.23): Aliphatic, alicyclic and aromatic ethers including anisole derivatives From chemical groups 15, 16 and 26 (Commission Regulation (EC) No 1565/2000 of 18 July 2000 View page or View pdf |
Flavouring Group Evaluation 59 (FGE.59): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 (2006) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) View page or View pdf |
Flavouring Group Evaluation 23, Revision 1 (FGE.23Rev1): Aliphatic, alicyclic and aromatic ethers including anisole derivatives from chemical groups 15, 16, 26 and 30[1] - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 23, Revision 2 (FGE.23Rev2): Aliphatic, alicyclic and aromatic ethers including anisole derivatives from chemical groups 15, 16, 22, 26 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 59, Revision 1 (FGE.59Rev1): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting and 63rd meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 Rev2 (2010) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 23, Revision 3 (FGE.23Rev3): Aliphatic, alicyclic and aromatic ethers including anisole derivatives from chemical groups 15, 16, 22, 26 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 23, Revision 4 (FGE.23Rev4): Aliphatic, alicyclic and aromatic ethers including anisole derivatives from chemical groups 15, 16, 22, 26 and 30 View page or View pdf |
EPI System: | View |
AIDS Citations: | Search |
Cancer Citations: | Search |
Toxicology Citations: | Search |
EPA Substance Registry Services (TSCA): | 14576-08-0 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 85755 |
National Institute of Allergy and Infectious Diseases: | Data |
WGK Germany: | 2 |
| 4-(2-methoxypropan-2-yl)-1-methylcyclohexene |
Chemidplus: | 0014576080 |
References:
Other Information:
Potential Blenders and core components note
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For Odor |
No odor group found for these |
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(Z)-2- | penten-1-yl hexanoate | FL/FR |
aldehydic |
| decanal (aldehyde C-10) | FL/FR |
| tridecanal | FL/FR |
balsamic |
| ethyl cinnamate | FL/FR |
3- | phenyl propyl cinnamate | FL/FR |
citrus |
| benzyl anthranilate | FR |
| bergamot acetoacetate | FR |
| bergamot oil bergaptene reduced italy | FL/FR |
beta- | bisabolol | FL/FR |
| citral / methyl anthranilate schiff's base | FR |
(Z)-4- | decenal | FL/FR |
| dihydromyrcenyl acetate | FR |
| dimethyl octenone | FR |
2,4- | dimethyl-3-cyclohexene-1-methanyl acetate | FR |
2- | dodecanone | FL/FR |
2- | ethyl-1-hexanol | FL/FR |
| grapefruit indene | FR |
| grapefruit mercaptan | FL/FR |
| grapefruit nitrile | FR |
| grapefruit oil c.p. (citrus paradisi var. duncan) italy | |
| grapefruit oil c.p. california | FL/FR |
| grapefruit oil CO2 extract (citrus paradisi macf. var. falvedo) | FL/FR |
| grapefruit oil terpeneless | FL/FR |
| grapefruit pentanol | FR |
| lemon oil residues | FL/FR |
| mandarin oil (citrus reticulata nova var. mandarin) uruguay | FL/FR |
4- | methyl-2-(1-methyl propyl)-1,3-oxathiane | |
alpha- | methylene citronellal | FR |
| myrcenyl acetate | FL/FR |
| myrmac aldehyde | FR |
(+)- | nootkatone | FL/FR |
| pamplemousse specialty | FR |
| philodendron solimoesense specialty | FR |
| rhubafuran | FR |
(±)-2,4,8- | trimethyl-7-nonen-2-ol | FL/FR |
10- | undecen-1-ol | FL/FR |
| valencene | FL/FR |
clean |
| clean nitrile | FR |
coumarinic |
| tonka ketone | FR |
dry |
3,4- | xylenol | FL/FR |
earthy |
| bornyl methyl ether | |
floral |
| cassis oxime 10% | FR |
| champaca absolute | FR |
| citronellyl formate | FL/FR |
| cyclamen aldehyde / methyl anthranilate schiff's base | FR |
| decanal / methyl anthranilate schiff's base | FR |
| decyl formate | FR |
| ethyl anthranilate | FL/FR |
| ethyl linalool | FR |
| gardenia amide | FR |
| gardenia decalone | FR |
| gardenia pentyl acetate | FR |
| honeysuckle absolute | FR |
| hydroxycitronellal / methyl anthranilate schiff's base | FR |
| leerall / methyl anthranilate schiff's base | FR |
| lilyall / methyl anthranilate schiff's base | FR |
| linalyl anthranilate | FL/FR |
| linalyl benzoate | FL/FR |
| linalyl butyrate | FL/FR |
| linalyl propionate | FL/FR |
| magnolia indene | FR |
alpha- | naphthyl methyl ketone | FL/FR |
beta- | naphthyl methyl ketone | FL/FR |
| neroli oil bigarde | FL/FR |
| neroli oil CO2 extract | FL/FR |
| nerolin fragarol | FL/FR |
| neryl acetate | FL/FR |
| neryl isovalerate | FL/FR |
| nonanal / methyl anthranilate schiff's base | FR |
| ocean propanal / methyl anthranilate schiff's base | FR |
bitter | orangeflower absolute morocco | FL/FR |
| peony acetonitrile | FR |
| petitgrain bigarade oil | FL/FR |
| propyl anthranilate | FL/FR |
| surfleurs d'oranger oil | FL/FR |
alpha- | terpinyl anthranilate | FL/FR |
| terpinyl isobutyrate | FL/FR |
| tetrahydrolinalyl acetate | FR |
| tuberose absolute (from pommade) | FL/FR |
| undecanal dimethyl acetal | FR |
| wallflower absolute | FR |
fruity |
iso | butyl methyl anthranilate | FL/FR |
| cyclohexyl anthranilate | FL/FR |
| ethyl 3-(2-furyl) propanoate | FL/FR |
| grapefruit acetal | FR |
| hexyl (E)-tiglate | FL/FR |
| linalyl isobutyrate | FL/FR |
| methyl anthranilate | FL/FR |
| nerolidyl isobutyrate | FR |
| ocimen-1-yl acetate | FR |
para- | tolualdehyde | FL/FR |
dextro- | linalyl acetate | FL/FR |
laevo- | linalyl acetate | FL/FR |
(2- | methoxy-1-methyl butyl) benzene | FR |
| nerol oxide | FL/FR |
herbal |
6- | acetoxydihydrotheaspirane | FL/FR |
| bergamot mint herb oil | FR |
| cuminyl acetate | FL/FR |
| linalyl acetate | FL/FR |
| linalyl formate | FL/FR |
| linalyl isovalerate | FL/FR |
3- | octyl acetate | FL/FR |
| terpineol acetate | FL/FR |
naphthyl |
beta- | naphthyl ethyl ether | FL/FR |
beta- | naphthyl methyl ether | FL/FR |
2- | naphthyl phenyl ketone | |
spicy |
iso | butyl angelate | FL/FR |
| cassia bark oil china | FL/FR |
| cassia bark oil replacer | FL/FR |
| cinnamaldehyde | FL/FR |
| cinnamon bark absolute | FL/FR |
| cinnamon bark oil | FL/FR |
| cinnamon bark oil ceylon | FL/FR |
4- | ethyl guaiacol | FL/FR |
| eugenol | FL/FR |
iso | eugenol | FL/FR |
iso | eugenyl acetate | FL/FR |
iso | eugenyl phenyl acetate | FL/FR |
(E)- | propyl 2-furan acrylate | FL/FR |
sulfurous |
| grapefruit menthane | FL/FR |
5- | mercapto-5-methyl-3-hexanone | FL/FR |
terpenic |
alpha- | terpineol | FL/FR |
vanilla |
| vanillylidene acetone | FL/FR |
waxy |
1- | undecanol | FL/FR |
woody |
alpha- | farnesene | FL/FR |
| juniper berry oleoresin | FL/FR |
| labdanum ethanone | FR |
2- | methoxy-4-vinyl phenol | FL/FR |
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For Flavor |
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No flavor group found for these |
6- | acetoxydihydrotheaspirane | FL/FR |
iso | butyl methyl anthranilate | FL/FR |
| cuminyl acetate | FL/FR |
| dihydronootkatone | FL |
| grapefruit oil c.p. (citrus paradisi var. duncan) italy | |
| lemon oil residues | FL/FR |
laevo- | linalyl acetate | FL/FR |
dextro- | linalyl acetate | FL/FR |
4- | mercapto-4-methyl-2-pentanol | FL |
4- | methyl-2-(1-methyl propyl)-1,3-oxathiane | |
alpha- | naphthyl methyl ketone | FL/FR |
2- | naphthyl phenyl ketone | |
(Z)-2- | penten-1-yl hexanoate | FL/FR |
| propyl anthranilate | FL/FR |
| surfleurs d'oranger oil | FL/FR |
| terpineol acetate | FL/FR |
alpha- | terpinyl anthranilate | FL/FR |
| terpinyl isobutyrate | FL/FR |
10- | undecen-1-ol | FL/FR |
aldehydic |
1- | undecanol | FL/FR |
alliaceous |
| cyclopentyl mercaptan | FL |
balsamic |
| ethyl cinnamate | FL/FR |
| vanillylidene acetone | FL/FR |
citrus |
| bergamot oil bergaptene reduced italy | FL/FR |
beta- | bisabolol | FL/FR |
(Z)-4- | decenal | FL/FR |
| dehydronootkatone | FL |
| grapefruit mercaptan | FL/FR |
| grapefruit oil c.p. california | FL/FR |
| grapefruit oil CO2 extract (citrus paradisi macf. var. falvedo) | FL/FR |
| grapefruit oil terpeneless | FL/FR |
| mandarin oil (citrus reticulata nova var. mandarin) uruguay | FL/FR |
| myrcenyl acetate | FL/FR |
(+)- | nootkatone | FL/FR |
| petitgrain bigarade oil | FL/FR |
alpha- | terpineol | FL/FR |
(±)-2,4,8- | trimethyl-7-nonen-2-ol | FL/FR |
| valencene | FL/FR |
fatty |
(E,E)-2,4- | dodecadienal | FL |
2- | dodecanone | FL/FR |
2- | ethyl-1-hexanol | FL/FR |
floral |
pseudo | ionone | FL |
| linalyl acetate | FL/FR |
| linalyl anthranilate | FL/FR |
| linalyl butyrate | FL/FR |
| linalyl isobutyrate | FL/FR |
beta- | naphthyl methyl ketone | FL/FR |
| neroli oil bigarde | FL/FR |
| neroli oil CO2 extract | FL/FR |
| neryl acetate | FL/FR |
bitter | orangeflower absolute morocco | FL/FR |
| tuberose absolute (from pommade) | FL/FR |
fruity |
| citronellyl formate | FL/FR |
| cyclohexyl anthranilate | FL/FR |
| ethyl 3-(2-furyl) propanoate | FL/FR |
| ethyl anthranilate | FL/FR |
| linalyl benzoate | FL/FR |
| linalyl isovalerate | FL/FR |
| methyl anthranilate | FL/FR |
| nerolin fragarol | FL/FR |
| neryl isovalerate | FL/FR |
(E)- | propyl 2-furan acrylate | FL/FR |
green |
iso | butyl angelate | FL/FR |
alpha- | farnesene | FL/FR |
(E,E)-2,4- | hexadienal | FL |
| hexyl (E)-tiglate | FL/FR |
| nerol oxide | FL/FR |
3- | octyl acetate | FL/FR |
herbal |
| bornyl methyl ether | |
| coriander distillates | FL |
| coriander flavor | FL |
| linalyl formate | FL/FR |
| linalyl propionate | FL/FR |
naphthyl |
beta- | naphthyl methyl ether | FL/FR |
powdery |
beta- | naphthyl ethyl ether | FL/FR |
smoky |
| barbecue flavor | FL |
2- | methoxy-4-vinyl phenol | FL/FR |
3,4- | xylenol | FL/FR |
spicy |
| cassia bark oil china | FL/FR |
| cassia bark oil replacer | FL/FR |
| cassia flavor | FL |
| cinnamaldehyde | FL/FR |
| cinnamon bark absolute | FL/FR |
| cinnamon bark oil | FL/FR |
| cinnamon bark oil ceylon | FL/FR |
| cinnamon flavor | FL |
iso | eugenol | FL/FR |
| eugenol | FL/FR |
iso | eugenyl acetate | FL/FR |
iso | eugenyl phenyl acetate | FL/FR |
3- | phenyl propyl cinnamate | FL/FR |
para- | tolualdehyde | FL/FR |
sulfurous |
| grapefruit menthane | FL/FR |
5- | mercapto-5-methyl-3-hexanone | FL/FR |
sweet |
brown | sugar cinnamon flavor | FL |
waxy |
| decanal (aldehyde C-10) | FL/FR |
| tridecanal | FL/FR |
woody |
4- | ethyl guaiacol | FL/FR |
| juniper berry oleoresin | FL/FR |
| yerba mate concentrate | FL |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| cyclohexene, 4-(1-methoxy-1-methylethyl)-1-methyl- | p- | menth-1-en-8-yl methyl ether | para- | menth-1-en-8-yl methyl ether | 4-(1- | methoxy-1-methyl ethyl)-1-methyl cyclohexene | 4-(1- | methoxy-1-methylethyl)-1-methylcyclohexene | | methoxyisopropyl methyl cyclohexene | 4-(2- | methoxypropan-2-yl)-1-methylcyclohexene | | methyl 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl ether | | orange flower ether (IFF) | | orangeflower ether (IFF) | a- | terpineol methyl ether | a- | terpineol, methyl ether | | terpinyl methyl ether | alpha- | terpinyl methyl ether |
Articles:
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