Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless to orange clear liquid (est) |
Assay: | 99.00 to 100.00 % sum of isomers
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 0.91700 to 0.92300 @ 25.00 °C.
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Pounds per Gallon - (est).: | 7.630 to 7.680
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Refractive Index: | 1.50400 to 1.51300 @ 20.00 °C.
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Boiling Point: | 180.00 °C. @ 1.00 mm Hg
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Boiling Point: | 331.00 to 333.00 °C. @ 760.00 mm Hg
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Acid Value: | 3.00 max. KOH/g
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Vapor Pressure: | 0.000137 mmHg @ 25.00 °C. (est) |
Flash Point: | 312.00 °F. TCC ( 155.56 °C. )
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logP (o/w): | 4.624 (est) |
Soluble in: |
| alcohol | | oils | | water, 0.4912 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Organoleptic Properties:
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Odor Type: citrus |
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| orange sweet fresh waxy juicy |
Odor Description: at 10.00 % in dipropylene glycol. | orange sweet fresh waxy juicy |
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Odor and/or flavor descriptions from others (if found). |
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Ernesto Ventós |
SINENSAL NATURAL (EX ORANGE) |
Odor Description: | CITRIC, SWEET, FRESH, WAXY |
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Prodasynth |
SINENSAL, NATURAL (EX-ORANGE) (ALPHA+BETA > 20%) |
Odor Description: | CITRIC, SWEET, FRESH, WAXY |
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Cosmetic Information:
Suppliers:
Artiste |
Sinensal Natural
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BOC Sciences |
For experimental / research use only. |
2,6-Dimethyl-10-methylenedodeca-2,6,11-trien-1-al
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Citrus and Allied Essences |
Sinensal 18/20% ex orange (natural)
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Market Report |
Ernesto Ventós |
SINENSAL NATURAL (EX ORANGE)
Odor: CITRIC, SWEET, FRESH, WAXY |
Florida Chemical |
Sinensals
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Frutarom |
Natural Sinensal 20%
KOSHER Flavor: fatty, reminiscent of orange |
IFF |
Natural Sinensal 20%
KOSHER Flavor: fatty, reminiscent of orange |
Lluch Essence |
SINENSAL NATURAL EX-ORANGE
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Penta International |
SINENSAL ALPHA NATURAL
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Penta International |
SINENSAL NATURAL MIXTURE OF ALPHA AND BETA
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Prodasynth |
SINENSAL, NATURAL (EX-ORANGE)
(ALPHA+BETA > 20%) Odor: CITRIC, SWEET, FRESH, WAXY |
Reincke & Fichtner |
beta-Sinensal natural
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SRS Aromatics |
SINENSAL NATURAL EX ORANGE
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Safety Information:
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
Not determined
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for beta-sinensal usage levels up to: | | 4.0000 % in the fragrance concentrate.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.91 (μg/capita/day) |
Maximised Survey-derived Daily Intakes (MSDI-USA): | 0.50 (μg/capita/day) |
Structure Class: | I |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 4. Update in publication number(s): 18 |
Click here to view publication 4 |
| average usual ppm | average maximum ppm |
baked goods: | - | - |
beverages(nonalcoholic): | - | 10.00000 |
beverages(alcoholic): | - | - |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | - | - |
condiments / relishes: | - | - |
confectionery froastings: | - | - |
egg products: | - | - |
fats / oils: | - | - |
fish products: | - | - |
frozen dairy: | - | 10.00000 |
fruit ices: | - | 10.00000 |
gelatins / puddings: | - | - |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | - | 10.00000 |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | - |
meat products: | - | - |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | - | - |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
Safety References:
European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
List of apha, beta-Unsaturated Aldehydes and Ketones representative of FGE.19 substances for Genotoxicity Testing [1] - Statement of the Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF) View page or View pdf |
Flavouring Group Evaluation 201: 2-Alkylated aliphatic acyclic alpha,beta-unsaturated aldehydes and precursors with or without additional double bonds from chemical subgroup 1.1.2 of FGE.19[1] View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 201 Revision 1 (FGE.201Rev1): 2-Alkylated, aliphatic, acyclic alpha,beta-unsaturated aldehydes and precursors, with or without additional double-bonds, from chemical subgroup 1.1.2 of FGE.19. View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 201 Revision 2 (FGE.201Rev2): 2-alkylated, aliphatic, acyclic alpha,beta-unsaturated aldehydes and precursors, with or without additional double-bonds, from chemical subgroup 1.1.2 of FGE.19 View page or View pdf |
EPI System: | View |
AIDS Citations: | Search |
Cancer Citations: | Search |
Toxicology Citations: | Search |
EPA Substance Registry Services (TSCA): | 60066-88-8 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 5281535 |
National Institute of Allergy and Infectious Diseases: | Data |
| (2E,6E)-2,6-dimethyl-10-methylidenedodeca-2,6,11-trienal |
Chemidplus: | 0060066888 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
2,6- | dimethyl-10-methylene dodeca-2,6,11-trien-1-al | 2,6- | dimethyl-10-methylene-2,6,11-dodecatrien-1-al | 2,6- | dimethyl-10-methylene-2,6,11-dodecatrienal | 2,6- | dimethyl-10-methylenedodeca-2,6,11-trien-1-al | (2E,6E)-2,6- | dimethyl-10-methylidenedodeca-2,6,11-trienal | 2,6,11- | dodecatrienal, 2,6-dimethyl-10-methylene- | | sinensal 18/20% ex orange (natural) | beta- | sinensal natural | | sinensal natural, mixture of alpha & beta | | sinensals |
Articles:
US Patents: | 3,963,783 - 4-Methyl-8-vinyl-4,7- and -4,8-nonadienals |
PubMed: | Repellent effect of santalol from sandalwood oil against Tetranychus urticae (Acari: Tetranychidae). |
US Patents: | 3,974,225 - Process for the preparation of unsaturated aldehydes |
PubMed: | Acaricidal and oviposition deterring effects of santalol identified in sandalwood oil against two-spotted spider mite, Tetranychus urticae Koch (Acari: Tetranychidae). |
US Patents: | 3,979,425 - Process for the preparation of unsaturated aldehydes |
PubMed: | California Lomatiums, Part X. Comparison of composition of the hydrodistilled oils from two subspecies of Lomatium mohavense. |
PubMed: | Citrus fruit flavor and aroma biosynthesis: isolation, functional characterization, and developmental regulation of Cstps1, a key gene in the production of the sesquiterpene aroma compound valencene. |
PubMed: | Identification of aroma active compounds in orange essence oil using gas chromatography-olfactometry and gas chromatography-mass spectrometry. |
PubMed: | Volatile constituents of redblush grapefruit (Citrus paradisi) and pummelo (Citrus grandis) peel essential oils from Kenya. |
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