Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless clear liquid (est) |
Assay: | 95.00 to 100.00 %
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 1.01600 to 1.02500 @ 25.00 °C.
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Pounds per Gallon - (est).: | 8.454 to 8.529
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Specific Gravity: | 1.02000 to 1.02800 @ 20.00 °C.
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Pounds per Gallon - est.: | 8.497 to 8.564
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Refractive Index: | 1.51400 to 1.52100 @ 20.00 °C.
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Boiling Point: | 109.00 to 111.00 °C. @ 2.00 mm Hg
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Boiling Point: | 280.00 to 281.00 °C. @ 760.00 mm Hg
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Vapor Pressure: | 0.004000 mmHg @ 25.00 °C. (est) |
Flash Point: | 210.00 °F. TCC ( 98.89 °C. )
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logP (o/w): | 3.818 (est) |
Soluble in: |
| alcohol | | water, 38.64 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Stability: |
| alcoholic lotion | | antiperspirant | | deo stick | | detergent perborate | | fabric softener | | hard surface cleaner | | shampoo | | soap |
Organoleptic Properties:
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Odor Type: balsamic |
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Odor Strength: | medium |
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Substantivity: | 96 hour(s) at 100.00 % |
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| balsamic fruity chocolate ylang tea |
Odor Description: at 100.00 %. | balsam fruity chocolate ylang tea |
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Odor and/or flavor descriptions from others (if found). |
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Bedoukian Research |
PRENYL BENZOATE ≥98.0%, Kosher |
Odor Description: | A sweet, balsamic odor with tea-like quality and natural connotations Has uses where balsamic notes are needed such as chocolate, vanilla. Has tuberose and tea notes. |
Taste Description: | balsamic This is a good blender for chocolate, vanilla and fruit flavors that need sweet balsamic notes. |
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Taytonn ASCC |
Proflora |
Odor Description: | Balsamic, Chocolate, Floral, Fruity, Metallic/ Metal, Ozone/Ozonic, Tea, Tuberose |
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Cosmetic Information:
Suppliers:
Azelis UK |
PROFLORA
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Berjé |
Prenyl Benzoate
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Media |
BOC Sciences |
For experimental / research use only. |
PRENYL BENZOATE 98.0%
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Creatingperfume.com |
Proflora (IFF)
Odor: sweet, balsamic odor with tea-like |
Ernesto Ventós |
PROFLORA IFF
Odor: FRUITY, BALSAMIC, CHOCOLATE, YLANG |
Lluch Essence |
PRENYL BENZOATE
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M&U International |
Proflora
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Moellhausen |
BENZOATO PRENILE
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Penta International |
PRENYL BENZOATE
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Perfumery Laboratory |
PROFLORA® IFF (Proflora® IFF)
Odor: Sweet balsamic fragrance with tea notes, shades of tuberose and chocolate |
Sigma-Aldrich: Aldrich |
For experimental / research use only. |
3-Methyl-2-butenyl benzoate
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Synerzine |
Prenyl Benzoate
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Taytonn ASCC |
Proflora
Odor: Balsamic, Chocolate, Floral, Fruity, Metallic/ Metal, Ozone/Ozonic, Tea, Tuberose |
TCI AMERICA |
For experimental / research use only. |
3-Methyl-2-butenyl Benzoate >98.0%(GC)
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The John D. Walsh Company |
Proflora
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Tianjin Danjun International |
3-Methylbut-2-enyl benzoate
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Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | Xi - Irritant |
R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
oral-rat LD50 4700 mg/kg Food and Chemical Toxicology. Vol. 20, Pg. 819, 1982.
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Dermal Toxicity: |
skin-rabbit LD50 > 5000 mg/kg Food and Chemical Toxicology. Vol. 20, Pg. 819, 1982.
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for prenyl benzoate usage levels up to: | | 15.0000 % in the fragrance concentrate.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.012 (μg/capita/day) |
Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 4900 (μg/person/day) |
Threshold of Concern: | 1800 (μg/person/day) |
Structure Class: | I |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 22 |
Click here to view publication 22 |
| average usual ppm | average maximum ppm |
baked goods: | 10.00000 | 100.00000 |
beverages(nonalcoholic): | 0.30000 | 3.00000 |
beverages(alcoholic): | 1.50000 | 15.00000 |
breakfast cereal: | 0.30000 | 1.50000 |
cheese: | - | - |
chewing gum: | 15.00000 | 100.00000 |
condiments / relishes: | - | - |
confectionery froastings: | 1.50000 | 10.00000 |
egg products: | 1.50000 | 10.00000 |
fats / oils: | 1.50000 | 10.00000 |
fish products: | - | - |
frozen dairy: | 6.00000 | 60.00000 |
fruit ices: | 3.00000 | 30.00000 |
gelatins / puddings: | 3.00000 | 30.00000 |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | 5.00000 | 50.00000 |
imitation dairy: | - | - |
instant coffee / tea: | 0.60000 | 6.00000 |
jams / jellies: | 3.00000 | 30.00000 |
meat products: | - | - |
milk products: | 0.60000 | 60.00000 |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | 1.50000 | 15.00000 |
snack foods: | - | - |
soft candy: | 3.00000 | 30.00000 |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
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Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). |
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. |
| average usage mg/kg | maximum usage mg/kg |
Dairy products, excluding products of category 02.0 (01.0): | 7.00000 | 35.00000 |
Fats and oils, and fat emulsions (type water-in-oil) (02.0): | 5.00000 | 25.00000 |
Edible ices, including sherbet and sorbet (03.0): | 10.00000 | 50.00000 |
Processed fruit (04.1): | 7.00000 | 35.00000 |
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | - | - |
Confectionery (05.0): | 10.00000 | 50.00000 |
Chewing gum (05.0): | - | - |
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 5.00000 | 25.00000 |
Bakery wares (07.0): | 10.00000 | 50.00000 |
Meat and meat products, including poultry and game (08.0): | 2.00000 | 10.00000 |
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | 2.00000 | 10.00000 |
Eggs and egg products (10.0): | - | - |
Sweeteners, including honey (11.0): | - | - |
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 5.00000 | 25.00000 |
Foodstuffs intended for particular nutritional uses (13.0): | 20.00000 | 100.00000 |
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | 5.00000 | 25.00000 |
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 10.00000 | 50.00000 |
Ready-to-eat savouries (15.0): | - | - |
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | 5.00000 | 25.00000 |
Safety References:
European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 202: 3-Alkylated aliphatic acyclic alpha,beta-unsaturated aldehydes and precursors with or without additional double bonds from chemical subgroup 1.1.3 of FGE.19[1] View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 20, Revision 2 (FGE.20Rev2): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 20, Revision 3(FGE.20Rev3): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 20, Revision 4 (FGE.20Rev4): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30 View page or View pdf |
EPI System: | View |
AIDS Citations: | Search |
Cancer Citations: | Search |
Toxicology Citations: | Search |
EPA Substance Registry Services (TSCA): | 5205-11-8 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 21265 |
National Institute of Allergy and Infectious Diseases: | Data |
WGK Germany: | 2 |
| 3-methylbut-2-enyl benzoate |
Chemidplus: | 0005205118 |
RTECS: | EM9473900 for cas# 5205-11-8 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| benzoato prenile | | benzoic acid 3-methyl-2-butenyl ester | | benzoic acid, 3-methyl-2-butenyl ester | 2- | buten-1-ol, 3-methyl-, benzoate | 3- | methyl but-2-enyl benzoate | 3- | methyl-2-buten-1-yl benzoate | 3- | methyl-2-butenyl benzoate | 3- | methylbut-2-en-1-yl benzoate | 3- | methylbut-2-enyl benzoate | | prenol benzoate | | proflora (IFF) |
Articles:
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