geranium dihydropyran
gyrane (Givaudan)
 
Notes:
None found
  • Augustus Oils
    • Augustus Oils Ltd
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      24237-00-1 2H-Pyran,6-butyl-3,6-dihydro-2,4-dimethyl-
       
  • Indukern F&F
  • Lluch Essence
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  • Penta International
    • Penta International Corporation
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  • Vigon International
    • Vigon International
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      Manufacturer and supplier of high quality flavor and fragrance ingredients.
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      503223 Gyrane
       
Synonyms   Articles   Notes   Search
Fragrance Demo Formulas
CAS Number: 24237-00-1Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 246-098-0
Nikkaji Web: J278.553F
XlogP3-AA: 2.90 (est)
Molecular Weight: 168.27960000
Formula: C11 H20 O
NMR Predictor: Predict (works with chrome or firefox)
Also(can) Contains: 2-butyl-3,6-dihydro-4,6-dimethyl-2H-pyran
 4-methylene-2,6-epoxydecane
Category: fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
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Physical Properties:
Appearance: colorless to pale yellow clear liquid (est)
Assay: 96.00 to 100.00 % sum of isomers
Food Chemicals Codex Listed: No
Boiling Point: 217.00 to  218.00 °C. @ 760.00 mm Hg
Vapor Pressure: 0.186000 mmHg @ 25.00 °C. (est)
Flash Point: 177.00 °F. TCC ( 80.56 °C. )
logP (o/w): 3.769 (est)
Soluble in:
 alcohol
 water, 21 mg/L @ 25 °C (est)
Insoluble in:
 water
Synonyms   Articles   Notes   Search   Top
Organoleptic Properties:
 
Odor Type: floral
 
Odor Strength: medium
 
Substantivity: < 4 hour(s) at 100.00 %
 
 floral  green  earthy  spicy  geranium  vegetable  
Odor Description:
at 100.00 %. 
floral green earthy spicy geranium vegetable
 
Odor and/or flavor descriptions from others (if found).
 
Givaudan
Gyrane
Odor Description: Geranium, Floral, Green
Gyrane is a radiant green floral with spicy geranium aspects. It supports the fresh green top-notes of a fragrance, and works well with materials such as Ligustral, Neofolione and cis-3 hexenol derivatives.
 
 
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Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
Synonyms   Articles   Notes   Search   Top
Suppliers:
Augustus Oils
Gyrane
Services
BOC Sciences
For experimental / research use only.
2H-Pyran,6-butyl-3,6-dihydro-2,4-dimethyl-
Givaudan
Gyrane
Odor: Geranium, Floral, Green
Use: Gyrane is a radiant green floral with spicy geranium aspects. It supports the fresh green top-notes of a fragrance, and works well with materials such as Ligustral, Neofolione and cis-3 hexenol derivatives.
Indukern F&F
GYRANE
Odor: GERANIUM, FLORAL, GREEN
Lluch Essence
GYRANE
Penta International
2-BUTYL-4,6-DIMETHYLDIHYDROPYRAN
Vigon International
Gyrane
Odor: Geranium, Floral, Green
Synonyms   Articles   Notes   Search   Top
Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50  > 5000 mg/kg
Food and Chemical Toxicology. Vol. 26, Pg. 289, 1988.

Dermal Toxicity:
skin-rabbit LD50 > 5000 mg/kg
Food and Chemical Toxicology. Vol. 26, Pg. 289, 1988.

Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for geranium dihydropyran usage levels up to:
  10.0000 % in the fragrance concentrate.
 
Recommendation for geranium dihydropyran flavor usage levels up to:
 not for flavor use.
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Safety References:
EPI System: View
AIDS Citations: Search
Cancer Citations: Search
Toxicology Citations: Search
EPA Substance Registry Services (TSCA): 24237-00-1
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 91147
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 2-butyl-4,6-dimethyl-5,6-dihydro-2H-pyran
Chemidplus: 0024237001
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References:
 2-butyl-4,6-dimethyl-5,6-dihydro-2H-pyran
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 24237-00-1
Pubchem (cid): 91147
Pubchem (sid): 135049539
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
ChemSpider: View
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Potential Blenders and core components note
 
For Odor
aldehydic
isobutyraldehydeFL/FR
6,7,8-decen-1-olFR
 dodecanal (aldehyde C-12 lauric)FL/FR
3-methyl-4-hexyl oxybutyraldehydeFR
alliaceous
 dibutyl sulfideFL/FR
anise
 fennel fragranceFR
balsamic
 benzophenoneFR
 bornyl formateFL/FR
isobornyl isobutyrateFL/FR
 cinnamyl formateFL/FR
caramellic
2-isobutyl-3-methyl pyrazineFL/FR
citrus
 bergamot oilFL/FR
 bergamot oil bergaptene reduced italyFL/FR
 bergamot oil turkeyFL/FR
 citral dimethyl acetalFL/FR
 citrus floral green fragranceFR
2,4-dimethyl-3-cyclohexene-1-methanyl acetateFR
 nonanal dimethyl acetalFL/FR
(E)-2-tetradecenalFL/FR
2-tetradecenalFL/FR
coconut
delta-heptalactoneFL/FR
earthy
1-nonen-3-olFL/FR
3-octen-2-oneFL/FR
1-octen-3-olFL/FR
fatty
2-decenalFL/FR
(Z)-3-octen-1-olFL/FR
floral
 acetaldehyde dibutyl acetalFL/FR
 aeolanthus graveolens oilFR
 aglaia odorata absoluteFR
 amyl benzoateFL/FR
 amyl salicylateFL/FR
 anisyl propanal / methyl anthranilate schiff's baseFR
 boronia concreteFL/FR
alpha-butyl cinnamaldehydeFL/FR
 cassie absolute replacerFL/FR
laevo-citronellolFL/FR
 citronellyl acetateFL/FR
 citronellyl butyrateFL/FR
 citronellyl propionateFL/FR
(E)-citronellyl tiglateFL/FR
 coriander seed oil CO2 extractFL/FR
 cumin carbinolFR
isocyclodimethyl octanolFR
 cyclohexyl ethyl acetateFL/FR
 cyclohexyl propanolFR
2-decalinolFR
 dictamnus hispanicus oilFR
 dihydrocarvyl acetateFL/FR
(±)-2,3-dihydrofarnesolFL/FR
 dihydroisojasmonate methyl esterFR
 dihydrorose oxideFR
 dimethyl benzyl carbinolFL/FR
 dimethyl benzyl carbinyl butyrateFL/FR
6,8-dimethyl-2-nonanolFR
 ethyl 2-benzyl butyrateFL/FR
 ethyl phenoxyacetateFR
 farnesolFL/FR
 farnesyl acetateFL/FR
 floral butanalFR
 floral pyranFR
 floral undecenoneFR
 gardenia absoluteFR
 gardenia acetalFR
 gardenia concreteFR
 gardenia fragranceFR
 gardenia specialtyFR
 gardenia taitensis flower absoluteFR
 geranium essenceFL/FR
 geranium leaf oil indiaFL/FR
 geranium nitrileFR
 geranium oilFL/FR
 geranium oil africaFL/FR
 geranium oil bourbonFL/FR
 geranium oil bourbon replacerFR
 geranium oil chinaFL/FR
 geranium oil egyptFL/FR
 geranium oil egypt fractionsFR
 geranium oil moroccoFL/FR
 geranium oil replacerFR
 geranium oil rwandaFL/FR
 geranium oil terpenelessFL/FR
 geranium petiole oil indiaFL/FR
 geranium pyranFR
 geranium rose oilFL/FR
 geranium rose-scented oil cubaFR
 geranium specialtyFR
 geranyl acetoneFL/FR
 geranyl anthranilateFR
 geranyl formateFL/FR
 geranyl hexanoateFL/FR
 geranyl phenyl acetateFL/FR
 geranyl tiglateFL/FR
(Z)-4-hepten-2-yl salicylateFR
(Z)-3-hexen-1-yl salicylateFL/FR
alpha-hexyl cinnamaldehydeFL/FR
 hexyl lactateFL/FR
 hyacinth absolute replacerFR
 hyacinth oilFR
 hydrangea fragranceFR
 hydroxycitronellal diethyl acetalFL/FR
 hydroxycitronellal propylene glycol acetalFL/FR
 jasmin cyclopentanolFR
 jonquil absoluteFR
 jonquil absolute replacerFR
 jonquil fragranceFR
 lilac absoluteFR
calla lily fragranceFR
 lily fragranceFR
 lily propanolFR
 linalool oxideFL/FR
 linalyl phenyl acetateFL/FR
 lotus fragranceFR
 magnolia indeneFR
(2-methoxy-1-methyl propyl) benzeneFR
(3-methoxy-2-methyl propyl) benzeneFR
1-(2-methyl allyl oxy)-2-methyl butaneFR
 methyl citronellateFL/FR
4-methyl-4-phenyl-2-pentanolFR
 mimosa absoluteFL/FR
 mimosa absolute franceFL/FR
 mimosa absolute indiaFL/FR
 mimosa absolute replacerFR
 mimosa fragranceFR
 mimosa specialtyFR
 muguet butanolFR
 musk acetateFR
 narcissus absolute replacerFR
 narcissus fragranceFR
 narcissus specialtyFR
 nerolFL/FR
 neroli oil CO2 extractFL/FR
 nerolidolFL/FR
(E)-nerolidolFL/FR
 neryl formateFL/FR
 ocean propanalFL/FR
 ocean propanal / methyl anthranilate schiff's baseFR
 octyl acetateFL/FR
 orange leaf absoluteFL/FR
bitter orangeflower absolute tunisiaFL/FR
 palmarosa oilFL/FR
 palmarosa oil replacerFR
 papaya isobutyrateFL/FR
 pelargonium graveolens extractFL/FR
 pelargonium graveolens flower waterFR
 pelargonium graveolens flower/leaf/stem waterFR
 peony acetonitrileFR
 phenethyl pivalateFL/FR
 phenyl acetaldehyde dicitronellyl acetalFR
 phenyl acetaldehyde digeranyl acetalFR
 phenyl acetaldehyde diisobutyl acetalFL/FR
2-phenyl propionaldehyde ethylene glycol acetalFR
2-phenyl propyl acetateFL/FR
 rhodinolFL/FR
 rhodinyl acetateFL/FR
 rhodinyl butyrateFL/FR
 rhodinyl formateFL/FR
 rhodinyl isobutyrateFL/FR
 rhodinyl phenyl acetateFL/FR
 rhodinyl propionateFL/FR
 rose absolute pentanolFR
 rose butanoateFL/FR
 rose geranium fragranceFR
(Z)-rose oxideFL/FR
laevo-rose oxideFL/FR
 rose pyranFR
(R)-styralyl alcoholFL/FR
 styralyl formateFL/FR
 sweet pea absoluteFR
 terpinyl isobutyrateFL/FR
5-tricyclodecenyl acetateFR
(S,E)-3,7,11-trimethyldodeca-6,10-dienalFR
 verdyl acetateFR
 violet methyl carbonateFR
 violet specialtyFR
 ylang ylang flower oil IIIFL/FR
fresh
3-(3-propen-2-yl phenyl) butanalFR
fruity
 amyl formateFL/FR
 benzyl methyl etherFL/FR
 butyl propionateFL/FR
 citronellyl isobutyrateFL/FR
 cyclohexyl crotonateFR
 dimethyl succinateFL/FR
 ethyl methyl-para-tolyl glycidateFL/FR
 neryl propionateFL/FR
 peach pivalateFR
2-pentyl furanFL/FR
 tropical iononeFL/FR
fungal
 jasmin nonaneFR
green
isoamyl 3-(2-furan) propionateFL/FR
isobutyl benzyl carbinolFL/FR
2-isobutyl thiazoleFL/FR
 chrysanthemum oxideFL/FR
 cortex pyridineFL/FR
 cumin acetaldehydeFL/FR
 decanal propylene glycol acetalFL/FR
alpha,alpha-dimethyl benzyl alcoholFL/FR
3,7-dimethyl-6-octenoic acidFL/FR
 diphenyl methaneFL/FR
 diphenyl oxideFL/FR
 earthy acetalFL/FR
 ferula galbaniflua gum extractFL/FR
 flower hexeneFR
 galbanum resinoid replacerFR
 geranium absoluteFL/FR
 geranium fragranceFR
 geranium stem oil indiaFL/FR
 geranium thiazoleFL/FR
 green cyclopropionateFR
(Z)-3-hepten-1-olFL/FR
(Z)-3-hexen-1-yl acetoacetateFL/FR
(Z)-3-hexen-1-yl angelateFR
(Z)-3-hexen-1-yl tiglateFL/FR
 hexyl (Z)-tiglateFL/FR
 hyacinth absoluteFL/FR
 ivy dioxolaneFR
 ivy fragranceFR
(2-methoxy-1-methyl butyl) benzeneFR
[(4E,4Z)-5-methoxy-3-methyl-4-penten-1-yl] benzeneFR
 methyl cyclocitrone (IFF)FR
para-methyl hydratropaldehydeFL/FR
 methyl octine carbonateFL/FR
4-methyl-4-phenyl pentanoneFR
 octanal dimethyl acetalFL/FR
 octyl oxyacetaldehydeFR
 pelargonium graveolens stem leaf extractFR
 phenyl acetaldehyde solutionFL/FR
 rose furan epoxideFL/FR
 terpinyl propionateFL/FR
2,4,8-trimethyl-5-oxatricyclo(6.2.1.0*2,6*)undecaneFR
herbal
 chrysanthemum fragranceFR
 chrysanthemum ketoneFR
 clary sage absoluteFL/FR
 coriander oleoresinFL/FR
 dihexyl (E)-fumarateFR
 geranium concreteFL/FR
 geranium cyclohexaneFR
6-hydroxydihydrotheaspirane (mixture of isomers)FL/FR
 linalyl acetateFL/FR
 marigold absolute (tagetes patula)FR
2-methyl butyl salicylateFL/FR
(1S,5R)-myrtenyl acetateFL/FR
 phenyl acetaldehyde diisoamyl acetalFR
 rain forest specialtyFR
medicinal
 kunzea ericoides leaf oilFR
mentholic
laevo-menthyl acetateFL/FR
minty
isopropyl tiglateFL/FR
spicy
alpha-caryophyllene alcoholFL/FR
beta-caryophyllene alcoholFL/FR
 cinnamyl propionateFL/FR
isocyclogeraniol (IFF)FR
 ginger oleoresinFL/FR
 spicy carbonateFR
sulfurous
 lychee mercaptan acetateFL/FR
tea
 camellia oleifera leaf extractFL/FR
terpenic
 angelica seed oilFL/FR
vegetable
 methionalFL/FR
waxy
3-decanoneFL/FR
woody
 convolvulus scoparius wood oilFR
 
For Flavor
 
No flavor group found for these
 acetaldehyde dibutyl acetalFL/FR
 amyl benzoateFL/FR
 bornyl formateFL/FR
 boronia concreteFL/FR
beta-caryophyllene alcoholFL/FR
alpha-caryophyllene alcoholFL/FR
 cassie absolute replacerFL/FR
 decanal propylene glycol acetalFL/FR
3-decanoneFL/FR
(±)-2,3-dihydrofarnesolFL/FR
alpha,alpha-dimethyl benzyl alcoholFL/FR
 earthy acetalFL/FR
 ethyl 2-benzyl butyrateFL/FR
 geranyl phenyl acetateFL/FR
(Z)-3-hepten-1-olFL/FR
(Z)-3-hexen-1-yl acetoacetateFL/FR
 hexyl (Z)-tiglateFL/FR
 hyacinth absoluteFL/FR
 hydroxycitronellal propylene glycol acetalFL/FR
 linalyl phenyl acetateFL/FR
2-methyl butyl salicylateFL/FR
 phenyl acetaldehyde solutionFL/FR
2-phenyl propyl acetateFL/FR
 rose furan epoxideFL/FR
(R)-styralyl alcoholFL/FR
 styralyl formateFL/FR
 terpinyl isobutyrateFL/FR
2-tetradecenalFL/FR
isoamyl 3-(2-furan) propionateFL/FR
alpha-butyl cinnamaldehydeFL/FR
aldehydic
isobutyraldehydeFL/FR
amber
 angelica seed oilFL/FR
isobutyl benzyl carbinolFL/FR
aromatic
 amyl salicylateFL/FR
balsamic
isobornyl isobutyrateFL/FR
 phenethyl pivalateFL/FR
6-hydroxydihydrotheaspirane (mixture of isomers)FL/FR
citrus
 bergamot oilFL/FR
 bergamot oil bergaptene reduced italyFL/FR
 bergamot oil turkeyFL/FR
 citral dimethyl acetalFL/FR
 nerolFL/FR
creamy
3-octen-2-oneFL/FR
earthy
1-nonen-3-olFL/FR
fatty
2-decenalFL/FR
(Z)-3-octen-1-olFL/FR
floral
 cinnamyl propionateFL/FR
laevo-citronellolFL/FR
 citronellyl acetateFL/FR
 citronellyl propionateFL/FR
 dihydrocarvyl acetateFL/FR
 dimethyl benzyl carbinyl butyrateFL/FR
3,7-dimethyl-6-octenoic acidFL/FR
 farnesolFL/FR
 farnesyl acetateFL/FR
 geranium essenceFL/FR
 geranium leaf oil indiaFL/FR
 geranium oilFL/FR
 geranium oil africaFL/FR
 geranium oil bourbonFL/FR
 geranium oil chinaFL/FR
 geranium oil egyptFL/FR
 geranium oil moroccoFL/FR
 geranium oil rwandaFL/FR
 geranium oil terpenelessFL/FR
 geranium petiole oil indiaFL/FR
 geranium rose oilFL/FR
 geranyl acetoneFL/FR
 geranyl tiglateFL/FR
 linalyl acetateFL/FR
 methyl citronellateFL/FR
 neroli oil CO2 extractFL/FR
 ocean propanalFL/FR
 orange leaf absoluteFL/FR
bitter orangeflower absolute tunisiaFL/FR
 pelargonium graveolens extractFL/FR
 rhodinolFL/FR
 rhodinyl acetateFL/FR
 rhodinyl butyrateFL/FR
 rhodinyl isobutyrateFL/FR
laevo-rose oxideFL/FR
 tropical iononeFL/FR
 ylang ylang flower oil IIIFL/FR
fruity
 amyl formateFL/FR
 benzyl methyl etherFL/FR
 butyl propionateFL/FR
 citronellyl butyrateFL/FR
 citronellyl isobutyrateFL/FR
 dimethyl succinateFL/FR
 ethyl methyl-para-tolyl glycidateFL/FR
 geranyl hexanoateFL/FR
 hexyl lactateFL/FR
 neryl formateFL/FR
 rhodinyl formateFL/FR
 rhodinyl propionateFL/FR
 rose butanoateFL/FR
grassy
 palmarosa oilFL/FR
green
2-isobutyl thiazoleFL/FR
2-isobutyl-3-methyl pyrazineFL/FR
 chrysanthemum oxideFL/FR
(E)-citronellyl tiglateFL/FR
 cortex pyridineFL/FR
 cumin acetaldehydeFL/FR
 cyclohexyl ethyl acetateFL/FR
 dibutyl sulfideFL/FR
 diphenyl methaneFL/FR
 diphenyl oxideFL/FR
 ferula galbaniflua gum extractFL/FR
 geranium absoluteFL/FR
 geranium stem oil indiaFL/FR
 geranium thiazoleFL/FR
 geranyl formateFL/FR
(Z)-3-hexen-1-yl salicylateFL/FR
(Z)-3-hexen-1-yl tiglateFL/FR
 linalool oxideFL/FR
para-methyl hydratropaldehydeFL/FR
 methyl octine carbonateFL/FR
 nerolidolFL/FR
(E)-nerolidolFL/FR
 neryl propionateFL/FR
 nonanal dimethyl acetalFL/FR
 octanal dimethyl acetalFL/FR
 papaya isobutyrateFL/FR
2-pentyl furanFL/FR
 phenyl acetaldehyde diisobutyl acetalFL/FR
isopropyl tiglateFL/FR
(Z)-rose oxideFL/FR
 terpinyl propionateFL/FR
herbal
 clary sage absoluteFL/FR
 coriander oleoresinFL/FR
 coriander seed oil CO2 extractFL/FR
 geranium concreteFL/FR
juicy
 lychee mercaptan acetateFL/FR
lactonic
delta-heptalactoneFL/FR
medicinal
 dimethyl benzyl carbinolFL/FR
melon
 hydroxycitronellal diethyl acetalFL/FR
minty
laevo-menthyl acetateFL/FR
mushroom
1-octen-3-olFL/FR
soapy
 dodecanal (aldehyde C-12 lauric)FL/FR
spicy
 cinnamyl formateFL/FR
 ginger oleoresinFL/FR
tea
 camellia oleifera leaf extractFL/FR
tomato
 methionalFL/FR
waxy
alpha-hexyl cinnamaldehydeFL/FR
 mimosa absoluteFL/FR
 mimosa absolute franceFL/FR
 mimosa absolute indiaFL/FR
 octyl acetateFL/FR
 rhodinyl phenyl acetateFL/FR
(E)-2-tetradecenalFL/FR
woody
(1S,5R)-myrtenyl acetateFL/FR
 
Synonyms   Articles   Notes   Search   Top
Potential Uses:
 animalFR
 floralFR
 geraniumFR
 roseFR
Synonyms   Articles   Notes   Search   Top
Occurrence (nature, food, other): note
 not found in nature
Synonyms   Articles   Notes   Search   Top
Synonyms:
 butyl dihydrodimethyl pyran
6-butyl-2,4-dimethyl dihydropyrane
6-butyl-2,4-dimethyl-3,6-dihydro-2H-pyran
6-butyl-2,4-dimethyldihydropyrane
6-butyl-3,6-dihydro-2,4-dimethyl-2H-pyran
2-butyl-4,6-dimethyl dihydropyrane
2-butyl-4,6-dimethyl-5,6-dihydro-2H-pyran
2-butyl-4,6-dimethyldihydropyran
 geranium dihydropyran
 gyrane (Givaudan)
2H-pyran, 3,6-dihydro-6-butyl-2,4-dimethyl-
2H-pyran, 6-butyl-3,6-dihydro-2,4-dimethyl-
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