Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Organoleptic Properties:
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Odor Type: sulfurous |
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| sulfurous coffee nutty |
Odor Description: at 0.10 % in dipropylene glycol. | sulfurous coffee nutty |
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Flavor Type: sulfurous |
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| coffee |
Taste Description:
| coffee |
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Odor and/or flavor descriptions from others (if found). |
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Cosmetic Information:
Suppliers:
Safety Information:
Preferred SDS: View |
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
Not determined
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for S-furfuryl thioformate usage levels up to: | | 0.0200 % in the fragrance concentrate.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 1.30 (μg/capita/day) |
Maximised Survey-derived Daily Intakes (MSDI-USA): | 0.02 (μg/capita/day) |
NOEL (No Observed Effect Level): | 0.83 (mg/kg bw per day) |
Structure Class: | III |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 4 |
Click here to view publication 4 |
| average usual ppm | average maximum ppm |
baked goods: | - | - |
beverages(nonalcoholic): | - | 1.00000 |
beverages(alcoholic): | - | - |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | - | - |
condiments / relishes: | - | - |
confectionery froastings: | - | - |
egg products: | - | - |
fats / oils: | - | - |
fish products: | - | - |
frozen dairy: | - | 1.00000 |
fruit ices: | - | 1.00000 |
gelatins / puddings: | - | - |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | - | 1.00000 |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | - |
meat products: | - | - |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | - | - |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
Safety References:
European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 13 (FGE.13); Furfuryl and furan derivatives with and without additional side-chain substituents and heteroatoms from chemical group 14 (Commission Regulation (EC) No 1565/2000 of 18 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 13Rev1: Furfuryl and furan derivatives with and without additional side-chain substituents and heteroatoms from chemical group 14 View page or View pdf |
Consideration of sulfur-substituted furan derivatives used as flavouring agents evaluated by JECFA (59th meeting) structurally related to a subgroup of substances within the group of “Furfuryl and furan derivatives with and without additional side-chain substituents and heteroatoms from chemical group 14” evaluated by EFSA in FGE.13Rev1 (2009) View page or View pdf |
Flavouring Group Evaluation 67 (FGE.67): Consideration of 40 furan-substituted aliphatic hydrocarbons, alcohols, aldehydes, ketones, carboxylic acids and related esters, sulfides, disulfides and ethers evaluated by JECFA at the 65th meeting (JECFA, 2006b) and re-evaluated at the 69th meeting (JECFA, 2009c) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 67, Revision 1 (FGE.67Rev.1): Consideration of 40 furan-substituted aliphatic hydrocarbons, alcohols, aldehydes, ketones, carboxylic acids and related esters, sulfides, disulfides and ethers evaluated by JECFA at the 65th meeting (JECFA, 2006b) and re-evaluated at the 69th meeting (JECFA, 2009c) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 65, Revision 1 (FGE.65Rev1): Consideration of sulfur-substituted furan derivatives used as flavouring agents evaluated by JECFA (59th meeting) structurally related to a subgroup of substances within the group of ‘Furfuryl and furan derivatives with and without additional side-chain substituents and heteroatoms from chemical group 14’ evaluated by EFSA in FGE.13Rev2 (2011) View page or View pdf |
EPI System: | View |
AIDS Citations: | Search |
Cancer Citations: | Search |
Toxicology Citations: | Search |
EPA Substance Registry Services (TSCA): | 59020-90-5 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 62144 |
National Institute of Allergy and Infectious Diseases: | Data |
WGK Germany: | 3 |
| S-(furan-2-ylmethyl) methanethioate |
Chemidplus: | 0059020905 |
References:
Other Information:
Potential Blenders and core components note
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For Odor |
No odor group found for these |
| chicory root | |
3,6- | dimethyl pyrazine-2-thiol | |
2,5- | dimethyl-3-furfurylthio-pyrazine | |
2,5- | dimethyl-3,6-diethyl pyrazine | |
2,6- | dimethyl-gamma-thiopyrone | |
2,6- | dimethyl-thio-gamma-pyrone | |
2- | hydroxymethyl-6-methyl-pyridine | |
4- | hydroxymethyl-pyridine | |
2- | methyl-3-pentyl pyrazine | |
2- | pentenyl furan | |
2-(1- | propenyl) pyridine | |
2-( | thienyl-2)-ethanethiol | |
2,3,5- | trimethyl phenol | FR |
| methyl furfuryl disulfide | FL/FR |
balsamic |
2- | acetyl furan | FL/FR |
burnt |
2- | ethyl-3,5(or 6)-dimethyl pyrazine | FL/FR |
| coffee dione | FL/FR |
| cyclotene | FL/FR |
| fenugreek absolute | FL/FR |
| fenugreek oleoresin | FL/FR |
iso | propenyl pyrazine | FL/FR |
chocolate |
| cocoa hexenal | FL/FR |
2,6- | dimethyl pyrazine | FL/FR |
2,4,5- | trimethyl thiazole | FL/FR |
cocoa |
2- | methyl butyraldehyde | FL/FR |
coffee |
| cichorium intybus root extract | FL/FR |
| cichorium intybus root solid extract | FL/FR |
| coffea arabica seed extract | FL/FR |
roasted | coffea arabica seed extract | FL/FR |
| coffea arabica seed oil | FL/FR |
| coffee absolute | FL/FR |
arabica | coffee bean butter | FL/FR |
roasted arabica | coffee bean essence | FL/FR |
roasted | coffee bean extract | FL/FR |
roasted arabica | coffee bean oil | FL/FR |
roasted arabica | coffee bean oil CO2 extract | FL/FR |
| coffee bean oil extract | FL/FR |
| coffee difuran | FL/FR |
| coffee resinoid | FL/FR |
| furfuryl mercaptan | FL/FR |
1- | hydroxy-2-butanone | FL/FR |
2- | methyl-3-,5 or 6-(furfuryl thio) pyrazine | FL/FR |
| nutty pyrazine | FL/FR |
| tropical thiazole | FL/FR |
herbal |
| thymyl methyl ether | FL/FR |
medicinal |
2,6- | xylenol | FL/FR |
| menthofuran | FL/FR |
nutty |
3,5- | cocoa pyrazine | FL/FR |
2,3- | dimethyl pyrazine | FL/FR |
4,5- | dimethyl-2-ethyl-3-thiazoline | FL/FR |
2- | ethyl-4-methyl thiazole | FL/FR |
| filbert heptenone | FL/FR |
2,6- | lutidine | FL/FR |
5- | methyl quinoxaline | FL/FR |
2- | methyl thio-3,5 or 6-methyl pyrazine | FL/FR |
2,3,5,6- | tetramethyl pyrazine | FL/FR |
2,3,5- | trimethyl pyrazine | FL/FR |
popcorn |
2- | acetyl pyrazine | FL/FR |
sulfurous |
| benzothiazole | FL/FR |
| furfuryl thioacetate | FL/FR |
2- | methyl 5-(methyl thio) furan | FL/FR |
O- | methyl S-1-methoxyhexan-3-yl carbonothioate | FL/FR |
vegetable |
1- | furfuryl pyrrole | FL/FR |
| tetrahydrofurfuryl alcohol | FL/FR |
woody |
| juniper berry oleoresin | FL/FR |
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For Flavor |
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No flavor group found for these |
2,5- | dimethyl-3-thiofuroyl furan | FL |
2- | ethyl-3,5(or 6)-dimethyl pyrazine | FL/FR |
2- | methyl-3-,5 or 6-(furfuryl thio) pyrazine | FL/FR |
absinthe |
| absinthe flavor | FL |
alliaceous |
| benzyl mercaptan | FL |
| dicyclohexyl disulfide | FL |
| tropical thiazole | FL/FR |
bitter |
2- | hydroxymethyl-6-methyl-pyridine | |
brown |
| fenugreek oleoresin | FL/FR |
1- | hydroxy-2-butanone | FL/FR |
burnt |
| furfuryl alcohol | FL |
1-(2- | furfuryl thio) propanone | FL |
2- | methyl quinoxaline | FL |
iso | propenyl pyrazine | FL/FR |
2-( | thienyl-2)-ethanethiol | |
2,6- | xylenol | FL/FR |
caramellic |
| caramel furanone | FL |
| cyclotene | FL/FR |
| fenugreek absolute | FL/FR |
| fenugreek distillates | FL |
chocolate |
| mocha cream flavor | FL |
cocoa |
| cocoa hexenal | FL/FR |
2- | methyl furan | FL |
coffee |
| cappuccino flavor | FL |
| chicory flavor | FL |
| chicory root | |
| chicory root distillates | FL |
| chicory root essence | FL |
roasted | chicory root oil | FL |
| chicory tincture | FL |
| cichorium intybus root extract | FL/FR |
| cichorium intybus root solid extract | FL/FR |
| coffea arabica seed extract | FL/FR |
roasted | coffea arabica seed extract | FL/FR |
| coffea arabica seed oil | FL/FR |
| coffea canephora seed extract | FL |
| coffee absolute | FL/FR |
arabica | coffee bean butter | FL/FR |
roasted | coffee bean concentrate | FL |
roasted | coffee bean essence | FL |
roasted robusta | coffee bean essence | FL |
roasted arabica | coffee bean essence | FL/FR |
dried roasted | coffee bean extract | FL |
roasted robusta | coffee bean extract | FL |
roasted | coffee bean extract | FL/FR |
roasted arabica | coffee bean oil CO2 extract | FL/FR |
| coffee bean oil extract | FL/FR |
| coffee creme brulee flavor | FL |
| coffee difuran | FL/FR |
| coffee dione | FL/FR |
espresso | coffee distillates | FL |
| coffee distillates | FL |
| coffee enhancers | FL |
espresso | coffee essence | FL |
espresso | coffee extract | FL |
| coffee flavor | FL |
dark roast | coffee flavor | FL |
espresso | coffee flavor | FL |
irish | coffee flavor | FL |
| coffee liqueur flavor | FL |
| coffee pyrazine | FL |
| coffee resinoid | FL/FR |
| coffee royale flavor | FL |
| difurfuryl ether | FL |
| diisoamyl thiomalate | FL |
3,6- | dimethyl pyrazine-2-thiol | |
2,4- | dimethyl thiazole | FL |
2,5- | dimethyl-3-furfurylthio-pyrazine | |
2,5- | dimethyl-3,6-diethyl pyrazine | |
2- | ethyl-4-methyl thiazole | FL/FR |
| furfuryl mercaptan | FL/FR |
| methyl furfuryl disulfide | FL/FR |
| methyl furfuryl mercaptopropionate | FL |
2- | methyl-5-vinyl pyrazine | FL |
2-iso | propyl pyrazine | FL |
2- | thiophene thiol | FL |
dairy |
| creme brulle coffee flavor | FL |
earthy |
| difurfuryl sulfide | FL |
fruity |
| furfuryl propionate | FL |
fusel |
2- | methyl butyraldehyde | FL/FR |
green |
3,4- | dimethoxystyrene | FL |
2,6- | dimethyl-gamma-thiopyrone | |
2- | methyl-5-isopropyl pyrazine | FL |
2-(1- | propenyl) pyridine | |
hazelnut |
4- | hydroxymethyl-pyridine | |
malty |
| malt flavor | FL |
meaty |
| benzothiazole | FL/FR |
2,6- | dimethyl pyrazine | FL/FR |
3- | mercapto-2-butanone | FL |
2- | methyl 3-(methyl thio) furan | FL |
mustard |
| furfuryl methyl ether | FL |
musty |
2- | ethoxythiazole | FL |
| menthofuran | FL/FR |
2- | methyl 5-(methyl thio) furan | FL/FR |
| thymyl methyl ether | FL/FR |
2,3,5- | trimethyl pyrazine | FL/FR |
nutty |
2- | acetyl furan | FL/FR |
3,5- | cocoa pyrazine | FL/FR |
3,5(6)- | cocoa pyrazine | FL |
2,3- | dimethyl pyrazine | FL/FR |
4,5- | dimethyl-2-ethyl-3-thiazoline | FL/FR |
| filbert heptenone | FL/FR |
| hazelnut flavor | FL |
| hazelnut paste | FL |
2,6- | lutidine | FL/FR |
5- | methyl quinoxaline | FL/FR |
2- | methyl thio-3,5 or 6-methyl pyrazine | FL/FR |
2- | methyl-3-pentyl pyrazine | |
| nutty pyrazine | FL/FR |
| nutty thiazole | FL |
| tetrahydrofurfuryl alcohol | FL/FR |
2,3,5,6- | tetramethyl pyrazine | FL/FR |
2,4,5- | trimethyl thiazole | FL/FR |
onion |
| furfuryl isopropyl sulfide | FL |
phenolic |
2- | pentenyl furan | |
roasted |
2- | acetyl pyrazine | FL/FR |
roasted arabica | coffee bean oil | FL/FR |
2,6- | dimethyl-thio-gamma-pyrone | |
| ethyl 3-(furfuryl thio) propionate | FL |
| furfuryl thioacetate | FL/FR |
O- | methyl S-1-methoxyhexan-3-yl carbonothioate | FL/FR |
smoky |
dextro- | xylose | FL |
spicy |
| cinnamon hazelnut cappuccino flavor | FL |
sulfurous |
| butyl mercaptan | FL |
| ethyl methyl sulfide | FL |
S- | ethyl thioacetate | FL |
| furfuryl thiopropionate | FL |
3- | methyl-2-butane thiol | FL |
2- | thienyl mercaptan | FL |
vegetable |
1- | furfuryl pyrrole | FL/FR |
woody |
| juniper berry oleoresin | FL/FR |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
2- | furan methane thiol formate | S-( | furan-2-ylmethyl) methanethioate | 2- | furanmethanethiol formate | 2-2- | furanmethanethiol formate | 2- | furanmethanethiolformate | 3-(2- | furanyl methyl) methane thioate | S-(2- | furanyl methyl) methane thioate | 3-(2- | furanylmethyl) methanethioate | | furfuryl thioformate | | furfuryl thioformate (2-furanmethanethiol formate) | | furfuryl thiol formate | | furfurylthioformate | | furfurylthiol butyrate | | furfurylthiol formate | 2- | furyl methyl sulfanyl formaldehyde | | methane thioic acid 3-(2-furanyl methyl) ester | | methane thioic acid S-(2-furanyl methyl) ester | | methanethioic acid, 3-(2-furanylmethyl) ester | | methanethioic acid, S-(2-furanylmethyl) ester |
Articles:
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