Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Organoleptic Properties:
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Odor Type: fermented |
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| pungent chemical sweet alliaceous caramellic rummy |
Odor Description: at 10.00 % in dipropylene glycol. | pungent chemical diffusive sweet alliaceous caramel rum |
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| pungent chemical sweet alliaceous caramellic rummy |
Odor Description:
| Pungent, chemical and diffusive, with sweet alliaceous and caramellic rum-like nuances Mosciano, Gerard P&F 15, No. 2, 69, (1990) |
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Flavor Type: musty |
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| musty onion garlic caramellic brown |
Taste Description: at 10.00 ppm. | Musty, onion and garlic, caramellic and brown notes Mosciano, Gerard P&F 15, No. 2, 69, (1990) |
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Odor and/or flavor descriptions from others (if found). |
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Taytonn ASCC |
Ethyl Trans-2-Butenoate |
Odor Description: | Sweet, Caramellic/ Caramel, Rum |
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Indukern F&F |
ETHYL CROTONATE |
Odor Description: | ETHEREAL, POWERFUL, FRUITY |
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Cosmetic Information:
Suppliers:
Advanced Biotech |
ETHYL CROTONATE NATURAL
96% min. Odor: Ethereal, rum |
Alfrebro |
ETHYL-trans-2-BUTENOATE NATURAL (ETHYL CROTONATE)
Odor: Rum, Ethereal |
Alfrebro |
ETHYL-trans-2-BUTENOATE
Odor: Ethereal, Rum |
Augustus Oils |
Ethyl Crotonate
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Services |
BOC Sciences |
For experimental / research use only. |
Ethyl crotonate
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Charkit Chemical |
ETHYL TRANS-2-BUTENOATE FEMA 3486
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Frutarom |
ETHYL TRANS-2-BUTENOATE
KOSHER Flavor: Pungent, Sweet, Alliaceous, Caramellic, Rummy |
CBD Offering |
IFF |
ETHYL TRANS-2-BUTENOATE
KOSHER Flavor: Pungent, Sweet, Alliaceous, Caramellic, Rummy |
Indukern F&F |
ETHYL CROTONATE
Odor: ETHEREAL, POWERFUL, FRUITY |
Jiangyin Healthway |
Ethyl Crotonate Natural98%
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New functional food ingredients |
Jiangyin Healthway |
Ethyl Crotonate
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Kingchem Laboratories |
ETHYL CROTONATE (T2 BUTENOATE)
Odor: Sweet, ethereal |
Penta International |
ETHYL CROTONATE NATURAL
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Penta International |
ETHYL CROTONATE
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Reincke & Fichtner |
Ethyl trans-2-butenoate
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Sigma-Aldrich |
Ethyl trans-2-butenoate, ≥96%, FG
Odor: ethereal; wine-like |
Certified Food Grade Products |
Sigma-Aldrich |
Ethyl trans-2-butenoate, natural, ≥97%, FG
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SRS Aromatics |
ETHYL CROTONATE
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Synerzine |
Ethyl trans-butenoate
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Taytonn ASCC |
Ethyl Trans-2-Butenoate
Odor: Sweet, Caramellic/ Caramel, Rum |
TCI AMERICA |
For experimental / research use only. |
Ethyl Crotonate >98.0%(GC)
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Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | Xi - Irritant |
R 11 - Highly flammable. R 36/37/38 - Irritating to eyes, respiratory system, and skin. S 02 - Keep out of the reach of children. S 16 - Keep away from sources of ignition - No Smoking. S 20/21 - When using do not eat, drink or smoke. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Human Experience: |
4 % solution: no irritation or sensitization. |
Oral/Parenteral Toxicity: |
oral-rat LD50 3000 mg/kg Journal of Industrial Hygiene and Toxicology. Vol. 26, Pg. 269, 1944.
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Dermal Toxicity: |
skin-guinea pig LD50 > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 19, Pg. 115, 1981.
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for ethyl (E)-2-crotonate usage levels up to: | | 4.0000 % in the fragrance concentrate.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 12.00 (μg/capita/day) |
Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 9500 (μg/person/day) |
Threshold of Concern: | 1800 (μg/person/day) |
Structure Class: | I |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 10 |
Click here to view publication 10 |
| average usual ppm | average maximum ppm |
baked goods: | - | 20.70000 |
beverages(nonalcoholic): | - | 3.00000 |
beverages(alcoholic): | - | 4.00000 |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | - | - |
condiments / relishes: | - | - |
confectionery froastings: | - | 16.10000 |
egg products: | - | - |
fats / oils: | - | - |
fish products: | - | - |
frozen dairy: | - | 8.40000 |
fruit ices: | - | 8.40000 |
gelatins / puddings: | - | 5.71000 |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | - | - |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | - |
meat products: | - | - |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | - | - |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
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Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). |
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. |
| average usage mg/kg | maximum usage mg/kg |
Dairy products, excluding products of category 02.0 (01.0): | 6.00000 | 8.00000 |
Fats and oils, and fat emulsions (type water-in-oil) (02.0): | - | 1.00000 |
Edible ices, including sherbet and sorbet (03.0): | 3.00000 | 8.00000 |
Processed fruit (04.1): | - | - |
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | - | - |
Confectionery (05.0): | 60.00000 | 100.00000 |
Chewing gum (05.0): | - | - |
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 1.20000 | 7.00000 |
Bakery wares (07.0): | 2.40000 | 6.00000 |
Meat and meat products, including poultry and game (08.0): | 1.00000 | 2.00000 |
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | 1.00000 | 5.00000 |
Eggs and egg products (10.0): | - | - |
Sweeteners, including honey (11.0): | - | - |
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 1.00000 | 2.00000 |
Foodstuffs intended for particular nutritional uses (13.0): | - | - |
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | 20.00000 | 50.00000 |
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 30.00000 | 100.00000 |
Ready-to-eat savouries (15.0): | 1.00000 | 10.00000 |
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | - | - |
Safety References:
Flavor & Extract Manufacturers Association (FEMA) reference(s): |
The FEMA GRAS assessment of alpha,beta-unsaturated aldehydes and related substances used as flavor ingredients. View pdf |
European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 5, Revision 1 (FGE.05Rev1):Esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids from chemical groups 1, 2, and 5 (Commission Regulation (EC) No 1565/2000 of 18 July 2000) [1] - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 71: Consideration of aliphatic, linear, alpha,beta-unsaturated carboxylic acids and related esters View page or View pdf |
Flavouring Group Evaluation 72 (FGE.72): Consideration of aliphatic, branched-chain saturated and unsaturated alcohols, aldehydes, acids, and related esters evaluated by the JECFA (61st meeting) structurally related to branched- and straight-chain unsaturated carboxylic acids. Esters of these and straight-chain aliphatic saturated alcohols evaluated by EFSA in FGE.05Rev2 (2010) View page or View pdf |
Flavouring Group Evaluation 5, Revision 2 (FGE.05Rev2): Branched- and straight-chain unsaturated carboxylic acids and esters of these with aliphatic saturated alcohols from chemical groups 1, 2, 3 and 5 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 95 (FGE.95): Consideration of aliphatic, linear or branched-chain saturated and unsaturated alcohols, aldehydes, acids and related esters evaluated by JECFA (69th meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05Rev1 (2008) View page or View pdf |
Scientific Opinion on the safety and efficacy of straight-chain primary aliphatic alcohols/aldehydes/acids, acetals and esters with esters containing saturated alcohols and acetals containing saturated aldehydes (chemical group 1) when used as flavourings for all animal species View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 5, Revision 3 (FGE.05Rev3): Branched- and straight-chain unsaturated aldehydes, dienals, unsaturated and saturated carboxylic acids and related esters with saturated and unsaturated aliphatic alcohols and a phenylacetic acid related ester from chemical groups 1, 2, 3, 5 and 15 View page or View pdf |
EPI System: | View |
AIDS Citations: | Search |
Cancer Citations: | Search |
Toxicology Citations: | Search |
EPA Substance Registry Services (TSCA): | 623-70-1 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 429065 |
National Institute of Allergy and Infectious Diseases: | Data |
WISER: | UN 1862 |
WGK Germany: | 2 |
| ethyl (E)-but-2-enoate |
Chemidplus: | 0000623701 |
RTECS: | GQ3500000 for cas# 623-70-1 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
(E)- | but-2-enoic acid ethyl ester | trans- | but-2-enoic acid ethyl ester | (2E)-2- | butenoic acid ethyl ester | (E)-2- | butenoic acid ethyl ester | trans-2- | butenoic acid ethyl ester | 2- | butenoic acid, ethyl ester, (2E)- | 2- | butenoic acid, ethyl ester, (E)- | (E)- | crotonic acid ethyl ester | (E)-alpha- | crotonic acid ethyl ester | | crotonic acid, ethyl ester, (E)- | | ethyl (2E)-2-butenoate | | ethyl (2E)-but-2-enoate | | ethyl (E)-2-butenoate | | ethyl (E)-but-2-enoate | (E)- | ethyl 2-butenoate | | ethyl 2-butenoate, (E)- | | ethyl alpha-crotonate | (E)- | ethyl but-2-enoate | | ethyl crotonate FCC | | ethyl crotonate natural | | ethyl trans-2-butenoate | | ethyl trans-crotonate | | ethyl-(2E)-but-2-enoat | | ethyl-trans-2-butenoate |
Articles:
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