Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Organoleptic Properties:
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Odor Type: floral |
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Odor Strength: | medium |
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Substantivity: | 68 hour(s) at 100.00 % |
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| rose green hyacinth watercress herbal |
Odor Description: at 100.00 %. | rose green hyacinth watercress herbal Luebke, William tgsc, (1987) |
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Flavor Type: green |
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| green cortex watercress banana unripe banana narcissus phenolic |
Taste Description:
| sweet green cortex watercress unripe banana narcissus phenolic Luebke, William tgsc, (1987) |
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Odor and/or flavor descriptions from others (if found). |
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Alfrebro |
PHENETHYL FORMATE NATURAL |
Odor Description: | Rose, Hyacinth, Chrysanthemum |
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Indukern F&F |
PHENYL ETHYL FORMATE |
Odor Description: | POWERFUL, HERBAL, GREEN, ROSE |
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Pell Wall Perfumes |
Phenylethyl Formate |
Odor Description: | Sweet, floral-rose, green-hyacinth, spicy-cinnamon Arctander expresses surprise at how rarely this material appears in fragrance formulas and suggests these uses: “The ester is an excellent modifier in Muguet, Orchid, Lilac, Rose, Narcisse, and, in larger amounts, in Hyacinth. It is interesting to note once more the enormous difference between the Formates and the Acetates while there is not nearly the same type-difference between the Acetates and the Propionates, etc. Generally formates are neglected in perfumery, perhaps partly because of above mentioned problem. But their warm, dry-foliage type floral odor lends very natural and attractive effects to a fragrance.”
The problem he alludes to is that a poor quality formate does not keep well: “One reason for its infrequent use may be that it does not keep well if it has not been prepared in the proper quality in the first place. If traces of water or formic acid were present from the beginning, the material will not only show pungent and unpleasant odor, but it will deteriorate rapidly and increase further in acidity. However, a properly made ester, kept dry and cool, will keep excellently on the perfumer’s shelf, and its odor remains warm, green-herbaceous and floral.” |
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Cosmetic Information:
Suppliers:
Alfrebro |
PHENETHYL FORMATE NATURAL
Odor: Rose, Hyacinth, Chrysanthemum |
Augustus Oils |
Phenyl Ethyl Formate
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Services |
Azelis UK |
Phenyl Ethyl Formate
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Bell Flavors & Fragrances |
Phenyl Ethyl Formate
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Berjé |
Phenyl Ethyl Formate
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Media |
BOC Sciences |
For experimental / research use only. |
Phenethyl Formate
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Citrus and Allied Essences |
Phenyl Ethyl Formate
Odor: reminicent of hyacinth and chrysanthemum. |
Market Report |
Elan Inc. |
PHENYL ETHYL FORMATE
Kosher |
Ernesto Ventós |
PHENYL ETHYL FORMATE
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Fleurchem |
phenyl ethyl formate natural
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Indukern F&F |
PHENYL ETHYL FORMATE
Odor: POWERFUL, HERBAL, GREEN, ROSE |
Keva |
PHENYL ETHYL FORMATE
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Lluch Essence |
PHENYL ETHYL FORMATE
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Moellhausen |
PHENYLETHYL FORMATE
Odor: green-herbaceous, floral-rosy |
Pell Wall Perfumes |
Phenylethyl Formate
Odor: Sweet, floral-rose, green-hyacinth, spicy-cinnamon Use: Arctander expresses surprise at how rarely this material appears in fragrance formulas and suggests these uses: “The ester is an excellent modifier in Muguet, Orchid, Lilac, Rose, Narcisse, and, in larger amounts, in Hyacinth. It is interesting to note once more the enormous difference between the Formates and the Acetates while there is not nearly the same type-difference between the Acetates and the Propionates, etc. Generally formates are neglected in perfumery, perhaps partly because of above mentioned problem. But their warm, dry-foliage type floral odor lends very natural and attractive effects to a fragrance.”
The problem he alludes to is that a poor quality formate does not keep well: “One reason for its infrequent use may be that it does not keep well if it has not been prepared in the proper quality in the first place. If traces of water or formic acid were present from the beginning, the material will not only show pungent and unpleasant odor, but it will deteriorate rapidly and increase further in acidity. However, a properly made ester, kept dry and cool, will keep excellently on the perfumer’s shelf, and its odor remains warm, green-herbaceous and floral.” |
Penta International |
PHENYLETHYL FORMATE NATURAL
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Penta International |
PHENYLETHYL FORMATE
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PerfumersWorld |
Phenyl ethyl formate
Odor: green-floral-rose hyacinth formic-dry-green vegetable |
R C Treatt & Co Ltd |
Phenyl Ethyl Formate
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Reincke & Fichtner |
Phenethyl Formate
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Santa Cruz Biotechnology |
For experimental / research use only. |
2-Phenylethyl Formate
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Sigma-Aldrich |
Phenethyl formate, ≥96%, FG
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Certified Food Grade Products |
Silverline Chemicals |
Phenyl Ethyl Formate
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SRS Aromatics |
PHENYL ETHYL FORMATE
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Synerzine |
Phenethyl Formate
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Taytonn ASCC |
Phenyl Ethyl Formate
Odor: Cinnamic/ Cinnamon , Floral, Green, Herbal/ Herbaceous, Hyacinth, Watercress |
TCI AMERICA |
For experimental / research use only. |
2-Phenylethyl Formate
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U. K. Aromatics and Chemicals |
PHENYL ETHYL FORMATE
Odor: rose green hyacinth watercress herbal Flavor: Banana, Blueberry, Apple |
Ungerer & Company |
Phenyl Ethyl Formate
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Vigon International |
Phenyl Ethyl Formate
Odor: Rose green hyacinth watercress herbal |
Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | Xi - Irritant |
R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 - Wear suitable gloves and eye/face protection.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Human Experience: |
6 % solution: no irritation or sensitization. |
Oral/Parenteral Toxicity: |
gavage-rat LD50 [sex: M,F] 3220 mg/kg (Levenstein, 1972c)
oral-rat LD50 3220 mg/kg Food and Cosmetics Toxicology. Vol. 12, Pg. 959, 1974.
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Dermal Toxicity: |
skin-rabbit LD50 > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 12, Pg. 959, 1974.
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for phenethyl formate usage levels up to: | | 5.0000 % in the fragrance concentrate.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 2.10 (μg/capita/day) |
Maximised Survey-derived Daily Intakes (MSDI-USA): | 30.00 (μg/capita/day) |
Structure Class: | I |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 3 |
Click here to view publication 3 |
| average usual ppm | average maximum ppm |
baked goods: | - | 15.00000 |
beverages(nonalcoholic): | - | 1.30000 |
beverages(alcoholic): | - | - |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | - | - |
condiments / relishes: | - | - |
confectionery froastings: | - | - |
egg products: | - | - |
fats / oils: | - | - |
fish products: | - | - |
frozen dairy: | - | 11.00000 |
fruit ices: | - | 11.00000 |
gelatins / puddings: | - | - |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | - | 13.00000 |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | - |
meat products: | - | - |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | - | - |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
Safety References:
Flavor & Extract Manufacturers Association (FEMA) reference(s): |
The FEMA GRAS assessment of phenethyl alcohol, aldehydes, acids, and related acetals and esters used as flavor ingredients. View pdf |
European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to: Flavouring Group Evaluation 14 (FGE.14): Phenethyl alcohol, aldehyde, esters, and related phenylacetic acid esters from chemical group 15 (Commission Regulation (EC) No 1565/2000 of 18 July 2000) View page or View pdf |
Flavouring Group Evaluation 53 (FGE.53): Consideration of phenethyl alcohol, aldehyde, acid and related acetals and esters evaluated by JECFA (59th meeting) structurally related to phenethyl alcohol, aldehyde, esters and related phenylacetic acid esters evaluated by EFSA in FGE.14 (2005) and one phenoxyethyl ester evaluated in FGE.23 (2006) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) View page or View pdf |
Flavouring Group Evaluation 14, Revision 1 (FGE.14Rev1): Phenethyl alcohol, aldehyde, acetals, carboxylic acid and related esters from chemical group 15 and 22 [1] - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food View page or View pdf |
Flavouring Group Evaluation 53, Revision 1 (FGE.53Rev1): Consideration of phenethyl alcohol, aldehyde, acid and related acetals and esters evaluated by JECFA (59th meeting) FGE.23Rev1 (2008) View page or View pdf |
EPI System: | View |
AIDS Citations: | Search |
Cancer Citations: | Search |
Toxicology Citations: | Search |
EPA Substance Registry Services (TSCA): | 104-62-1 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 7711 |
National Institute of Allergy and Infectious Diseases: | Data |
WGK Germany: | 2 |
| 2-phenylethyl formate |
Chemidplus: | 0000104621 |
RTECS: | LQ9400000 for cas# 104-62-1 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| benzene ethanol formate | | benzeneethanol, formate | | benzyl carbinyl formate | | benzyl carbinyl methanoate | | benzylcarbinyl formate | | benzylcarbinyl methanoate | | formic acid 2-phenethyl ester | | formic acid 2-phenyl ethyl ester | | formic acid 2-phenylethyl ester | | formic acid, 2-phenylethyl ester | | formic acid, phenethyl ester | | phenethyl alcohol formate | | phenethyl alcohol, formate | 2- | phenethyl formate | 2- | phenethyl methanoate | | phenyl ethyl alcohol formate | | phenyl ethyl formate | 2- | phenyl ethyl formate | beta- | phenyl ethyl formate | | phenyl ethyl formate natural | 2- | phenyl ethyl methanoate | | phenylethyl formate | 2- | phenylethyl formate | | phenylethyl formate natural | 2- | phenylethyl methanoate |
Articles:
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