Category: fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | bright yellow viscous liquid (est) |
Food Chemicals Codex Listed: | No |
Specific Gravity: | 1.06270 to 1.07070 @ 25.00 °C.
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Pounds per Gallon - (est).: | 8.843 to 8.909
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Refractive Index: | 1.52590 to 1.53540 @ 20.00 °C.
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Boiling Point: | 497.00 to 498.00 °C. @ 760.00 mm Hg
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Flash Point: | > 212.00 °F. TCC ( > 100.00 °C. )
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logP (o/w): | 4.050 |
Shelf Life: | 36.00 month(s) or longer if stored properly. |
Storage: | store in cool, dry place in tightly sealed containers, protected from heat and light. |
Soluble in: |
| alcohol | | oils | | water, 0.2014 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Stability: |
| alcoholic lotion | | deo stick | | fabric softener | | shampoo |
Organoleptic Properties:
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Odor Type: floral |
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Odor Strength: | medium , recommend smelling in a 50.00 % solution or less |
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Substantivity: | 400 hour(s) at 100.00 % |
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| fresh lily floral sweet orangeflower |
Odor Description: at 50.00 % in dipropylene glycol. | fresh lily floral sweet orangeblossom Luebke, William tgsc, (1990) |
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Odor and/or flavor descriptions from others (if found). |
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IFF |
Lyrame Super |
Odor Description: | Tenacious floral absolute odor with a very sweet, orange blossom profile. Increases the substantivity of a fragrance and provides fixation and floralcy as well |
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Robertet |
Schiff lyral |
Odor Description: | Floral, honey, orange flower |
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Cosmetic Information:
Suppliers:
Augustus Oils |
Lyral – Ma Schiff Base
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Services |
Azelis UK |
LYRAME SUPER
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BOC Sciences |
For experimental / research use only. |
Methyl Anthranilate / Lyral Schiff Base
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Charabot |
Schiff lyral
Odor: Floral, honey, orange flower |
Ernesto Ventós |
LYRAME SUPER IFF
Odor: FLORAL,FRUITY,MUGUET,ORANGE BLOSSOM |
Ernesto Ventós |
SCHIFF BASE, LYRAL
Odor: FLORAL,FRUITY,MUGUET,ORANGE BLOSSOM |
IFF |
Lyrame Super
Odor: Tenacious floral absolute odor with a very sweet, orange blossom profile. Increases the substantivity of a fragrance and provides fixation and floralcy as well |
Indukern F&F |
LYRAME SUPER
Odor: FLORAL, FRUITY, MUGUET, ORANGE BLOSSOM |
Lluch Essence |
SCHIFF BASE LYRAL/METHYL ANTHRANILATE
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M&U International |
Lyrame Super
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Penta International |
METHYL ANTHRANILATE/LYRAL
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Perfumery Laboratory |
LIRAM SUPER ™ 50% in the IFG IFF (LYRAME SUPER ™ IFF)
Odor: A fresh, sweet scent of lily of the valley and orange blossoms |
Robertet |
Schiff lyral
Odor: Floral, honey, orange flower |
Seasons and Harvest / Crop calendar |
Taytonn ASCC |
Lyrame Super
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Taytonn ASCC |
Lyrame
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Vigon International |
LYRAL BASE
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Vigon International |
Methyl Anthranilate / Lyral Schiff Base
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Safety Information:
European information : |
Most important hazard(s): | Xi - Irritant |
R 36/38 - Irritating to skin and eyes. R 43 - May cause sensitisation by skin contact. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
Not determined
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
IFRA Critical Effect: | Sensitization |
IFRA fragrance material specification: | | The IFRA Scientific Committee examined the physicochemical properties of Schiff bases and concluded that, based on the available information, these materials should be considered under contributions from other sources. By default, the stoichiometric presence of the aldehydes of the Schiff bases is taken into account assuming 100% dissociation. An indicative list of Schiff bases incorporating aldehydes covered by an IFRA Standard of restriction is reported at page 2. These Schiff bases must be taken into account for determination of the maximum use level of the respective aldehydes. |
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only) |
3,4-leerall | Max. Found: 61.3 % and Reason: Sensitization |
leerall | Max. Found: 61.3 % and Reason: Sensitization |
Recommendation for leerall / methyl anthranilate schiff's base usage levels up to: | | 5.0000 % in the fragrance concentrate.
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Recommendation for leerall / methyl anthranilate schiff's base flavor usage levels up to: |
| not for flavor use.
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Safety References:
References:
| methyl 2-[[4-(4-hydroxy-4-methylpentyl)-1-cyclohex-3-enyl]methylideneamino]benzoate |
NIST Chemistry WebBook: | Search Inchi |
Canada Domestic Sub. List: | 67634-12-2 |
Pubchem (cid): | 106740 |
Pubchem (sid): | 135062609 |
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| benzoic acid, 2-(((4-(4-hydroxy-4-methylpentyl)-3-cyclohexen-1-yl)methylene)amino)-, methyl ester | | benzoic acid, 2-(((4-(4-hydroxy-4-methylpentyl)-3-cyclohexenyl)methylene)amino)-, methyl ester | | benzoic acid, 2-((4-(4-hydroxy-4-methylpentyl)-3-cyclohexen-1-yl)methylene)amino-, methyl ester | 2-(((4-(4- | hydroxy-4-methylpentyl)-3-cyclohexen-1-yl)methylene)amino)benzoic acid, methyl ester | | leerall / methyl anthranilate schiff's base | | lyrame (IFF) | | lyrame super (IFF) | | lyrantion (Quest) | | lyrantion 50%DPG (Quest) | | methyl 2-(((4-(4-hydroxy-4-methyl pentyl)-3-cyclohexenyl)methylene)amino) benzoate | | methyl 2-(((4-(4-hydroxy-4-methylpentyl)-3-cyclohexenyl)methylene)amino)benzoate | | methyl 2-(((E)-1-(4-(4-hydroxy-4-methyl pentyl)-3-cyclohexenyl)methylidene)amino)-1-benzene | | methyl 2-[[4-(4-hydroxy-4-methylpentyl)-1-cyclohex-3-enyl]methylideneamino]benzoate | | methyl anthranilate / leerall schiff's base | | methyl anthranilate / lyral | | methyl anthranilate / lyral schiff base | | methyl anthranilate / lyral schiff base 50% in DEP | | methyl hydroxymethyl pentyl cyclohexenyl methylene aminobenzoate | | methyl N-((4-(4-hydroxy-4-methyl pentyl)-3-cyclohexen-1-yl)methylidene) anthranilate | | methyl N-((4-(4-hydroxy-4-methylpentyl)-3-cyclohexen-1-yl)methylidene)anthranilate | | schiff lyral | | schiff's base lyrama super |
Articles:
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