Category: fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | dark brown viscous liquid to solid (est) |
Assay: | 98.00 to 100.00 %
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 1.00330 to 1.01010 @ 25.00 °C.
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Pounds per Gallon - (est).: | 8.348 to 8.405
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Refractive Index: | 1.52590 to 1.53370 @ 20.00 °C.
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Boiling Point: | 413.00 to 414.00 °C. @ 760.00 mm Hg
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Flash Point: | > 200.00 °F. TCC ( > 93.33 °C. )
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logP (o/w): | 6.485 (est) |
Soluble in: |
| alcohol | | water, 0.3433 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Organoleptic Properties:
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Odor Type: citrus |
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Odor Strength: | medium , recommend smelling in a 50.00 % solution or less |
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Substantivity: | 260 hour(s) at 100.00 % |
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| fresh sweet lemon orangeflower fruity |
Odor Description: at 50.00 % in dipropylene glycol. | fresh sweet lemon orangeflower fruity |
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Odor and/or flavor descriptions from others (if found). |
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Cosmetic Information:
Suppliers:
Safety Information:
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
Not determined
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | fragrance agents |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
IFRA Critical Effect: | Sensitization |
IFRA fragrance material specification: | | The IFRA Scientific Committee examined the physicochemical properties of Schiff bases and concluded that, based on the available information, these materials should be considered under contributions from other sources. By default, the stoichiometric presence of the aldehydes of the Schiff bases is taken into account assuming 100% dissociation. An indicative list of Schiff bases incorporating aldehydes covered by an IFRA Standard of restriction is reported at page 2. These Schiff bases must be taken into account for determination of the maximum use level of the respective aldehydes. |
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only) |
citral | Max. Found: 53.30 % and Reason: Sensitization |
IFRA: | View Standard |
Recommendation for citral / methyl anthranilate schiff's base usage levels up to: | | 4.0000 % in the fragrance concentrate.
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Recommendation for citral / methyl anthranilate schiff's base flavor usage levels up to: |
| not for flavor use.
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Safety References:
References:
Other Information:
Potential Blenders and core components note
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For Odor |
No odor group found for these |
(E+Z)-4,8- | dimethyl-3,7-nonadien-2-one | FL/FR |
aldehydic |
(Z)-4- | dodecenal | FL/FR |
2- | methyl undecanal dimethyl acetal | FR |
balsamic |
| benzyl cinnamate | FL/FR |
| cinnamyl formate | FL/FR |
camphoreous |
| fenchol | FL/FR |
citrus |
| acetaldehyde citronellyl methyl acetal | FR |
| agathis australis oil | |
| aldehydic nitrile | FR |
beta- | bisabolol | FL/FR |
| cedrat peel oil | FL/FR |
| citral | FL/FR |
| citral diethyl acetal | FL/FR |
| citral dimethyl acetal | FL/FR |
| citral ethylene glycol acetal | FR |
| citral propylene glycol acetal | FL/FR |
| citronella oil ceylon | FL/FR |
| citronellyl nitrile | FR |
(Z)-4- | decenal | FL/FR |
(E+Z)-4,8- | dimethyl-3,7-nonadien-2-yl acetate | FL/FR |
homo | geranyl nitrile | FR |
2- | heptanol | FL/FR |
| heptyl phenyl acetate | |
| kauri-copal leaf oil | |
| lemon hexadiene | FL/FR |
| lemon oil c.p. california | FL/FR |
| lemon oil c.p. furocoumarin reduced | FL/FR |
| lemon oil italy | FL/FR |
| lemon oil terpeneless | FL/FR |
| lemongrass oil | FL/FR |
| lemongrass oil guatemala | FL/FR |
| lemongrass oil morocco | FL/FR |
| litsea cubeba fruit oil | FL/FR |
| litsea cubeba oil terpeneless | FL/FR |
| methyl heptenone | FL/FR |
(Z+E)-2- | methyl-2-(4-methyl-3-pentenyl) cyclopropane carbaldehyde | FL/FR |
| neroli ketone | FR |
| ocimenol | FL/FR |
| petitgrain combava oil | FR |
alpha- | terpinyl methyl ether | FL/FR |
| tetrahydrocitral | FL/FR |
| trimethyl cyclohexene | FR |
| verbena oil spain | FL/FR |
| verbena oil terpeneless | FL/FR |
clean |
| clean nitrile | FR |
coumarinic |
| tonka ketone | FR |
fatty |
| butyl undecylenate | FL/FR |
fermented |
| methyl decanoate | FL/FR |
floral |
| acetal 318 | FR |
| acetyl tetralin | FR |
iso | amyl angelate | FL/FR |
alpha- | amyl cinnamaldehyde | FL/FR |
alpha- | amyl cinnamaldehyde dimethyl acetal | FL/FR |
iso | amyl geranate | FR |
| benzyl acetate | FL/FR |
| benzyl acetoacetate | FL/FR |
| benzyl formate | FL/FR |
| champaca absolute | FR |
| citronellyl butyrate | FL/FR |
| citronellyl hexanoate | FL/FR |
| citronellyl propionate | FL/FR |
(E)- | citronellyl tiglate | FL/FR |
| cyclamen aldehyde / methyl anthranilate schiff's base | FR |
| decanal / methyl anthranilate schiff's base | FR |
| decyl formate | FR |
| dihydrojasmone | FL/FR |
| dimethyl benzyl carbinyl acetate | FL/FR |
| ethyl anthranilate | FL/FR |
| geraniol | FL/FR |
| honeysuckle absolute | FR |
| hydroxycitronellal / methyl anthranilate schiff's base | FR |
| leerall / methyl anthranilate schiff's base | FR |
| lemon oil distilled | FL/FR |
| lilyall / methyl anthranilate schiff's base | FR |
| linalyl anthranilate | FL/FR |
| menthadienyl formate | FR |
| methoxymelonal | FL/FR |
| methyl benzyl acetate (mixed ortho-,meta-,para-) | FL/FR |
alpha-iso | methyl ionone (90% min.) | FL/FR |
| methyl ionyl acetate | FL/FR |
alpha- | naphthyl methyl ketone | FL/FR |
beta- | naphthyl methyl ketone | FL/FR |
| neroli oil bigarde | FL/FR |
| neroli oil CO2 extract | FL/FR |
| nerolin fragarol | FL/FR |
| neryl isovalerate | FL/FR |
| nonanal / methyl anthranilate schiff's base | FR |
3- | nonanon-1-yl acetate | FL/FR |
| ocean propanal / methyl anthranilate schiff's base | FR |
| petitgrain bigarade oil | FL/FR |
| petitgrain lemon oil | FL/FR |
| phenethyl isobutyrate | FL/FR |
| phenethyl isovalerate | FL/FR |
| phenyl amyl alcohol | FL/FR |
1- | phenyl propyl butyrate | FL/FR |
2- | phenyl propyl isobutyrate | FL/FR |
4- | phenyl-3-buten-2-ol | FL/FR |
| propyl anthranilate | FL/FR |
iso | propyl benzoate | FL/FR |
| rose undecene | FR |
alpha- | terpinyl anthranilate | FL/FR |
| terpinyl formate | FL/FR |
| terpinyl valerate | FL/FR |
| tetrahydroionyl acetate | FR |
(E)-2,5,9- | trimethyl-4,9-decadien-1-al | FR |
| wallflower absolute | FR |
fruity |
| amyl heptanoate | FL/FR |
| benzaldehyde / methyl anthranilate schiff's base | FR |
| berry hexanoate | FR |
iso | butyl anthranilate | FL/FR |
iso | butyl furyl propionate | FL/FR |
| citronellyl isobutyrate | FL/FR |
| cyclohexyl anthranilate | FL/FR |
(E)-beta- | damascone | FL/FR |
(Z)-beta- | damascone | FL/FR |
beta- | damascone | FL/FR |
| ethyl isobutyrate | FL/FR |
| ethyl levulinate | FL/FR |
| heptanal cyclic ethylene acetal | FR |
| heptyl isobutyrate | FL/FR |
3- | mercaptohexyl acetate | FL/FR |
| methyl (Z)-3-hexenoate | FL/FR |
| methyl anthranilate | FL/FR |
| methyl dimethyl anthranilate | FL/FR |
| methyl isobutyrate | FL/FR |
(E)-7- | methyl-3-octen-2-one | FL/FR |
| rhubarb pyran | FR |
4-(para- | tolyl)-2-butanone | FL/FR |
| tropical ionone | FL/FR |
green |
iso | amyl 3-(2-furan) propionate | FL/FR |
| citrus carbaldehyde / methyl anthranilate schiff's base | FR |
iso | decanal | FL/FR |
(Z)-3- | hexen-1-yl isovalerate | FL/FR |
| hexoxyacetaldehyde dimethyl acetal | FR |
| nerol oxide | FL/FR |
herbal |
| canarium luzonicum gum | FL/FR |
| canarium luzonicum oil | FL/FR |
| chamomile isobutyrate | FR |
| chamomile propionate | FR |
| chamomile valerate | FR |
| clary propyl acetate | FR |
| methyl cyclogeranate (Firmenich) | FR |
| rue oil | FL/FR |
| rue oil cuba | FL/FR |
naphthyl |
beta- | naphthyl ethyl ether | FL/FR |
beta- | naphthyl methyl ether | FL/FR |
2- | naphthyl phenyl ketone | |
powdery |
alpha- | methyl ionone | FL/FR |
spicy |
para- | anisyl formate | FL/FR |
terpenic |
| elemi resinoid | FL/FR |
gamma- | terpinene | FL/FR |
woody |
2- | decalinyl acetate | FR |
(E+Z)-4,8- | dimethyl-3,7-nonadien-2-ol | FL/FR |
| labdanum ethanone | FR |
alpha- | terpinene | FL/FR |
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For Flavor |
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No flavor group found for these |
| agathis australis oil | |
iso | amyl angelate | FL/FR |
alpha- | amyl cinnamaldehyde dimethyl acetal | FL/FR |
| cedrat peel oil | FL/FR |
| citral propylene glycol acetal | FL/FR |
beta- | cubebene | FL |
iso | decanal | FL/FR |
| dihydronootkatone | FL |
S-(2,5- | dimethyl-3-furyl) ethane thioate | FL |
(E+Z)-4,8- | dimethyl-3,7-nonadien-2-ol | FL/FR |
(E+Z)-4,8- | dimethyl-3,7-nonadien-2-one | FL/FR |
(E+Z)-4,8- | dimethyl-3,7-nonadien-2-yl acetate | FL/FR |
(Z)-4- | dodecenal | FL/FR |
| heptyl phenyl acetate | |
| kauri-copal leaf oil | |
4- | mercapto-4-methyl-2-pentanol | FL |
| methyl benzyl acetate (mixed ortho-,meta-,para-) | FL/FR |
| methyl dimethyl anthranilate | FL/FR |
(Z+E)-2- | methyl-2-(4-methyl-3-pentenyl) cyclopropane carbaldehyde | FL/FR |
alpha- | naphthyl methyl ketone | FL/FR |
2- | naphthyl phenyl ketone | |
| ocimenol | FL/FR |
| phenyl amyl alcohol | FL/FR |
1- | phenyl propyl butyrate | FL/FR |
2- | phenyl propyl isobutyrate | FL/FR |
| propyl anthranilate | FL/FR |
iso | propyl benzoate | FL/FR |
alpha- | terpinyl anthranilate | FL/FR |
| tetrahydrocitral | FL/FR |
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iso | amyl 3-(2-furan) propionate | FL/FR |
| benzyl acetoacetate | FL/FR |
iso | butyl furyl propionate | FL/FR |
beta- | damascone | FL/FR |
berry |
| heptyl isobutyrate | FL/FR |
burnt |
| ethyl 2-furoate | FL |
camphoreous |
| fenchol | FL/FR |
citrus |
beta- | bisabolol | FL/FR |
| citral | FL/FR |
| citral diethyl acetal | FL/FR |
| citral dimethyl acetal | FL/FR |
| citronella oil ceylon | FL/FR |
(Z)-4- | decenal | FL/FR |
| lemon hexadiene | FL/FR |
| lemon oil c.p. california | FL/FR |
| lemon oil c.p. furocoumarin reduced | FL/FR |
| lemon oil distilled | FL/FR |
| lemon oil italy | FL/FR |
| lemon oil terpeneless | FL/FR |
| lemongrass oil | FL/FR |
| lemongrass oil guatemala | FL/FR |
| lemongrass oil morocco | FL/FR |
| litsea cubeba fruit oil | FL/FR |
| petitgrain bigarade oil | FL/FR |
| petitgrain lemon oil | FL/FR |
| verbena oil france | FL |
| verbena oil spain | FL/FR |
| verbena oil terpeneless | FL/FR |
ethereal |
| ethyl isobutyrate | FL/FR |
| methyl isobutyrate | FL/FR |
fatty |
| methyl decanoate | FL/FR |
(E)-7- | methyl-3-octen-2-one | FL/FR |
floral |
| citronellyl hexanoate | FL/FR |
| citronellyl propionate | FL/FR |
| dihydrojasmone | FL/FR |
| dimethyl benzyl carbinyl acetate | FL/FR |
| geraniol | FL/FR |
| linalyl anthranilate | FL/FR |
alpha-iso | methyl ionone (90% min.) | FL/FR |
beta- | naphthyl methyl ketone | FL/FR |
| neroli oil bigarde | FL/FR |
| neroli oil CO2 extract | FL/FR |
| tropical ionone | FL/FR |
fruity |
| amyl heptanoate | FL/FR |
| benzyl acetate | FL/FR |
| benzyl formate | FL/FR |
iso | butyl anthranilate | FL/FR |
| citronellyl butyrate | FL/FR |
| citronellyl isobutyrate | FL/FR |
| cyclohexyl anthranilate | FL/FR |
(E)-beta- | damascone | FL/FR |
(Z)-beta- | damascone | FL/FR |
| ethyl anthranilate | FL/FR |
| ethyl levulinate | FL/FR |
2- | heptanol | FL/FR |
2- | hexyl-4-acetoxytetrahydrofuran | FL |
| methoxymelonal | FL/FR |
| methyl (Z)-3-hexenoate | FL/FR |
| methyl 4-phenyl butyrate | FL |
| methyl anthranilate | FL/FR |
alpha- | methyl ionone | FL/FR |
| nerolin fragarol | FL/FR |
| neryl isovalerate | FL/FR |
3- | nonanon-1-yl acetate | FL/FR |
| phenethyl isovalerate | FL/FR |
2- | phenyl-4-pentenal | FL |
| terpinyl formate | FL/FR |
| terpinyl valerate | FL/FR |
4-(para- | tolyl)-2-butanone | FL/FR |
green |
| canarium luzonicum gum | FL/FR |
| canarium luzonicum oil | FL/FR |
(E)- | citronellyl tiglate | FL/FR |
| elemi resinoid | FL/FR |
(Z)-3- | hexen-1-yl isovalerate | FL/FR |
| methyl heptenone | FL/FR |
| nerol oxide | FL/FR |
herbal |
| rue oil | FL/FR |
| rue oil cuba | FL/FR |
honey |
| phenethyl isobutyrate | FL/FR |
lemon |
| litsea cubeba oil terpeneless | FL/FR |
naphthyl |
beta- | naphthyl methyl ether | FL/FR |
powdery |
beta- | naphthyl ethyl ether | FL/FR |
spicy |
para- | anisyl formate | FL/FR |
| benzyl cinnamate | FL/FR |
| cinnamyl formate | FL/FR |
terpenic |
gamma- | terpinene | FL/FR |
alpha- | terpinene | FL/FR |
tropical |
alpha- | amyl cinnamaldehyde | FL/FR |
3- | mercaptohexyl acetate | FL/FR |
waxy |
| butyl undecylenate | FL/FR |
4- | phenyl-3-buten-2-ol | FL/FR |
woody |
| methyl ionyl acetate | FL/FR |
alpha- | terpinyl methyl ether | FL/FR |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| benzoic acid, 2-((3,7-dimethyl-2,6-octadienylidene)amino)-, methyl ester | N-(3,7- | dimethyl-2,6-octadienylidene) anthranilic acid methyl ester | | methyl 2-((3,7-dimethyl-2,6-octadienylidene)amino) benzoate | | methyl 2-((3,7-dimethyl-2,6-octadienylidene)amino)benzoate | | methyl 2-[[(2E)-3,7-dimethylocta-2,6-dienylidene]amino]benzoate | | methyl anthranilate / citral schiff's base |
Articles:
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