Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless to pale yellow clear liquid (est) |
Assay: | 90.00 to 100.00 % sum of isomers
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 0.97400 to 0.98400 @ 25.00 °C.
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Pounds per Gallon - (est).: | 8.105 to 8.188
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Refractive Index: | 1.53000 to 1.53800 @ 20.00 °C.
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Boiling Point: | 82.00 to 87.00 °C. @ 0.70 mm Hg
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Boiling Point: | 265.00 to 266.00 °C. @ 760.00 mm Hg
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Acid Value: | 10.00 max. KOH/g
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Vapor Pressure: | 0.010000 mmHg @ 20.00 °C. |
Vapor Density: | 6.0 ( Air = 1 ) |
Flash Point: | 230.00 °F. TCC ( 110.00 °C. )
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logP (o/w): | 3.554 (est) |
Soluble in: |
| alcohol | | dipropylene glycol | | water, 93.9 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Organoleptic Properties:
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Odor Type: chocolate |
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Odor Strength: | medium |
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Substantivity: | > 48 hour(s) at 100.00 % |
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| sweet cocoa nutty rose powdery |
Odor Description: at 100.00 %. | sweet cocoa nutty rose powdery Luebke, William tgsc, (1991) |
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| sweet floral honey powdery cocoa rose |
Odor Description:
| sweet, floral, honey, powdery and cocoa-like with rosy nuance Mosciano, Gerard P&F 19, No. 3, 51, (1994) |
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Flavor Type: floral |
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| floral sweet waxy cocoa honey |
Taste Description: at 20.00 ppm. | Floral, sweet, waxy and cocoa-like with a honey nuance Mosciano, Gerard P&F 19, No. 3, 51, (1994) |
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Odor and/or flavor descriptions from others (if found). |
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Bedoukian Research |
4-METHYL-2-PHENYL-2-PENTENAL ≥90.0% (sum of isomers), Kosher |
Odor Description: | A distinctive cocoa mocha aroma with honey undertones, and a hint of peony Imparts sweet, rosy, powdery, honey, and cocoa notes to florals. |
Taste Description: | Dry, cocoa powder notes, rosy notes of honey Distinctly cocoa powder, rosy notes for honey. |
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R C Treatt & Co Ltd |
4-Methyl-2-phenyl-2-pentenal NI, Kosher |
Odor Description: | loral/honey/chocolate |
Taste Description: | green chocolate Used in chocolate flavours for bakery and soft confection at 15ppm; in frozen dairy and desserts at 10ppm; and in non-alcoholic beverages at 1ppm |
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Taytonn ASCC |
4-Methyl-2-phenyl-2-pentenal |
Odor Description: | Cocoa, Floral, Powder/ Powdery, Sweet |
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Cosmetic Information:
Suppliers:
Bedoukian Research |
4-METHYL-2-PHENYL-2-PENTENAL, NO ANTIOXIDANT
Odor: A distinctive cocoa mocha aroma with honey undertones, and a hint of peony Use: Imparts sweet, rosy, powdery, honey, and cocoa notes to florals. Flavor: Dry, cocoa powder notes, rosy notes of honey Distinctly cocoa powder, rosy notes for honey. |
Bedoukian Research |
4-METHYL-2-PHENYL-2-PENTENAL
≥90.0% (sum of isomers), Kosher Odor: A distinctive cocoa mocha aroma with honey undertones, and a hint of peony Use: Imparts sweet, rosy, powdery, honey, and cocoa notes to florals. Flavor: Dry, cocoa powder notes, rosy notes of honey Distinctly cocoa powder, rosy notes for honey. |
Beijing Lys Chemicals |
4-Methyl-2-phenyl-2-pentenal
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BOC Sciences |
For experimental / research use only. |
4-Methyl-2-phenyl-2-pentenal, mixture of cis and trans
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Charkit Chemical |
METHYL-2-PHENYL-2-PENTENAL, 4- M2200 FEMA 3200
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Frutarom |
4-METHYL-2-PHENYL-2-PENTENAL
KOSHER Flavor: Floral, Sweet, Waxy, Honey, Cocoa |
CBD Offering |
IFF |
4-METHYL-2-PHENYL-2-PENTENAL
KOSHER Flavor: Floral, Sweet, Waxy, Honey, Cocoa |
Kingchem Laboratories |
4 METHYL 2 PHENYL 2 PENTENAL
Odor: Sour, unripe apple, floral, cocoa |
Lluch Essence |
4-METHYL-2-PHENYL-2-PENTENAL 98%
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M&U International |
4-Methyl-2-Phenyl-2-Pentenal
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Penta International |
4-METHYL-2-PHENYL-2-PENTENAL
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R C Treatt & Co Ltd |
4-Methyl-2-phenyl-2-pentenal
NI, Kosher Odor: loral/honey/chocolate Flavor: green chocolate Used in chocolate flavours for bakery and soft confection at 15ppm; in frozen dairy and desserts at 10ppm; and in non-alcoholic beverages at 1ppm |
Santa Cruz Biotechnology |
For experimental / research use only. |
4-Methyl-2-phenyl-2-pentenal, (E)+(Z)
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Sigma-Aldrich |
4-Methyl-2-phenyl-2-pentenal, mixture of cis and trans, ≥88%, stabilized
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Certified Food Grade Products |
Synerzine |
4-Methyl-2-phenyl-2-pentenal
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Taytonn ASCC |
4-Methyl-2-phenyl-2-pentenal
Odor: Cocoa, Floral, Powder/ Powdery, Sweet |
WholeChem |
4-Methyl-2-phenyl-2-pentenal
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Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | Xi - Irritant |
R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
Not determined
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for cocoa pentenal usage levels up to: | | 8.0000 % in the fragrance concentrate.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.34 (μg/capita/day) |
Maximised Survey-derived Daily Intakes (MSDI-USA): | 5.00 (μg/capita/day) |
Structure Class: | II |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 4 |
Click here to view publication 4 |
| average usual ppm | average maximum ppm |
baked goods: | - | 1.50000 |
beverages(nonalcoholic): | - | 1.50000 |
beverages(alcoholic): | - | - |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | - | 1.50000 |
condiments / relishes: | - | - |
confectionery froastings: | - | - |
egg products: | - | - |
fats / oils: | - | - |
fish products: | - | - |
frozen dairy: | - | 1.50000 |
fruit ices: | - | 1.50000 |
gelatins / puddings: | - | 1.50000 |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | - | 1.50000 |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | - |
meat products: | - | - |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | - | - |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
Safety References:
References:
Other Information:
Potential Blenders and core components note
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For Odor |
acidic |
| cyclohexyl acetic acid | FL/FR |
animal |
| methyl (E)-2-octenoate | FL/FR |
berry |
| raspberry ketone methyl ether | FL/FR |
cheesy |
iso | valeric acid | FL/FR |
chocolate |
2- | methoxypyrazine | FL/FR |
cocoa |
2- | methyl butyraldehyde | FL/FR |
fatty |
(E,Z,Z)-2,4,7- | tridecatrienal | FL/FR |
fermented |
| valeraldehyde | FL/FR |
| benzyl acetate | FL/FR |
| citronellyl phenyl acetate | FL/FR |
| decyl formate | FR |
3,6- | dimethyl-3-octyl acetate | FR |
| ethyl phenyl acetate | FL/FR |
| geranyl isobutyrate | FL/FR |
| geranyl phenyl acetate | FL/FR |
alpha- | hexyl cinnamaldehyde | FL/FR |
| hyacinth acetals | FL/FR |
| hydroxycitronellal | FL/FR |
| hydroxycitronellol | FL/FR |
beta- | naphthyl methyl ketone | FL/FR |
| phenethyl alcohol | FL/FR |
| phenethyl benzoate | FL/FR |
| phenethyl hexanoate | FL/FR |
3- | phenyl propyl formate | FL/FR |
4- | phenyl-3-buten-2-ol | FL/FR |
iso | propyl phenyl acetate | FL/FR |
| rhodinyl phenyl acetate | FL/FR |
| rose acetate | FR |
| rose butanoate | FL/FR |
| rose oil (rosa damascena) russia | FL/FR |
| rose oil (rosa damascena) turkey | FL/FR |
| sambucus nigra flower oil CO2 extract | FR |
fresh |
| decyl vinyl ether | FR |
fruity |
| cherry oxyacetate | FL/FR |
| ethyl methyl-para-tolyl glycidate | FL/FR |
| strawberry glycidate 1 (aldehyde C-16 (so-called)) | FL/FR |
| strawberry glycidate 2 | FL/FR |
| tropical ionone | FL/FR |
green |
(Z)-3- | hexen-1-yl phenyl acetate | FL/FR |
| hexyl phenyl acetate | FL/FR |
4- | methyl-4-phenyl pentanone | FR |
| phenyl acetaldehyde ethylene glycol acetal | FR |
| rosa damascena leaf absolute | FR |
herbal |
| clary sage absolute | FL/FR |
american | elder flower absolute | FR |
| perillaldehyde | FL/FR |
honey |
| methyl phenyl acetate | FL/FR |
| phenyl acetic acid | FL/FR |
| propyl phenyl acetate | FL/FR |
musty |
| cocoa butenal | FL/FR |
2- | methyl pyrazine | FL/FR |
2,3,5- | trimethyl pyrazine | FL/FR |
roasted |
| trigonella foenum-graecum seed oil CO2 extract | FL/FR |
spicy |
| cinnamyl acetate | FL/FR |
iso | eugenyl phenyl acetate | FL/FR |
sweet |
| beeswax absolute replacer | FR |
waxy |
| ethyl myristate | FL/FR |
| ethyl octanoate | FL/FR |
1- | undecanol | FL/FR |
woody |
| santalyl butyrate | FL/FR |
| santalyl phenyl acetate | FL/FR |
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For Flavor |
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No flavor group found for these |
1- | acetyl cyclohexyl acetate | FL |
2(4)-iso | butyl-4(2),6-dimethyl dihydro-4H-1,3,5-dithiazine | FL |
4,5- | dimethyl-2-ethyl thiazole | FL |
2- | methoxypyrazine | FL/FR |
3- | phenyl propyl formate | FL/FR |
| santalyl butyrate | FL/FR |
| santalyl phenyl acetate | FL/FR |
aldehydic |
1- | undecanol | FL/FR |
aromatic |
| hyacinth acetals | FL/FR |
berry |
| raspberry ketone methyl ether | FL/FR |
bitter |
(E,Z,Z)-2,4,7- | tridecatrienal | FL/FR |
cheesy |
iso | valeric acid | FL/FR |
cocoa |
| cocoa distillates | FL |
floral |
| citronellyl phenyl acetate | FL/FR |
| geranyl isobutyrate | FL/FR |
| geranyl phenyl acetate | FL/FR |
| methyl phenyl acetate | FL/FR |
beta- | naphthyl methyl ketone | FL/FR |
| phenethyl alcohol | FL/FR |
| phenethyl benzoate | FL/FR |
| phenyl acetic acid | FL/FR |
| rose oil (rosa damascena) russia | FL/FR |
| rose oil (rosa damascena) turkey | FL/FR |
| tropical ionone | FL/FR |
fruity |
| benzyl acetate | FL/FR |
| cherry oxyacetate | FL/FR |
| ethyl methyl-para-tolyl glycidate | FL/FR |
| hexyl phenyl acetate | FL/FR |
| methyl (E)-2-octenoate | FL/FR |
| rose butanoate | FL/FR |
| strawberry glycidate 1 (aldehyde C-16 (so-called)) | FL/FR |
| strawberry glycidate 2 | FL/FR |
fusel |
2- | methyl butyraldehyde | FL/FR |
green |
| cocoa butenal | FL/FR |
(Z)-3- | hexen-1-yl phenyl acetate | FL/FR |
herbal |
| clary sage absolute | FL/FR |
honey |
| ethyl phenyl acetate | FL/FR |
iso | propyl phenyl acetate | FL/FR |
| propyl phenyl acetate | FL/FR |
musty |
2,3,5- | trimethyl pyrazine | FL/FR |
nutty |
2,4- | dimethyl-5-vinyl thiazole | FL |
2- | methyl pyrazine | FL/FR |
powdery |
| hydroxycitronellol | FL/FR |
roasted |
| trigonella foenum-graecum seed oil CO2 extract | FL/FR |
spicy |
| cinnamyl acetate | FL/FR |
iso | eugenyl phenyl acetate | FL/FR |
| perillaldehyde | FL/FR |
sweet |
| cyclohexyl acetic acid | FL/FR |
waxy |
| ethyl myristate | FL/FR |
| ethyl octanoate | FL/FR |
alpha- | hexyl cinnamaldehyde | FL/FR |
| hydroxycitronellal | FL/FR |
| phenethyl hexanoate | FL/FR |
4- | phenyl-3-buten-2-ol | FL/FR |
| rhodinyl phenyl acetate | FL/FR |
winey |
| valeraldehyde | FL/FR |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| benzeneacetaldehyde, a-(2-methylpropylidene)- | alpha-iso | butylidene benzene acetaldehyde | alpha-iso | butylidenebenzeneacetaldehyde | | cocoa pentenal | | eglantal | 4 | methyl 2 phenyl 2 pentenal | alpha-(2- | methyl propylidene) benzene acetaldehyde | 4- | methyl-2-phenyl pent-2-enal | 4- | methyl-2-phenyl-2-penten-1-al | 4- | methyl-2-phenyl-2-pentenal | 4- | methyl-2-phenyl-4-pentenal | 4- | methyl-2-phenylpent-2-enal | alpha-(2- | methylpropylidene)benzeneacetaldehyde | 2- | pentenal, 4-methyl-2-phenyl- |
Articles:
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