Category: flavoring agents and cosmetic fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless clear liquid (exp) |
Assay: | 95.00 to 100.00 %
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 0.82200 to 0.83100 @ 25.00 °C.
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Pounds per Gallon - (est).: | 6.840 to 6.915
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Refractive Index: | 1.37800 to 1.38600 @ 20.00 °C.
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Melting Point: | -100.00 °C. @ 760.00 mm Hg
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Boiling Point: | 102.00 to 104.00 °C. @ 760.00 mm Hg
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Boiling Point: | 32.00 to 33.00 °C. @ 50.00 mm Hg
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Acid Value: | 1.00 max. KOH/g
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Vapor Pressure: | 27.600000 mmHg @ 25.00 °C. |
Vapor Density: | 4.1 ( Air = 1 ) |
Flash Point: | -5.00 °F. TCC ( -20.56 °C. )
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logP (o/w): | 0.840 |
Shelf Life: | 12.00 month(s) or longer if stored properly. |
Storage: | store in cool, dry place in tightly sealed containers, protected from heat and light. |
Soluble in: |
| alcohol | | aliphatic alcohols | | ethyl ether | | water, 1.954e+004 mg/L @ 25 °C (est) | | water, 4.40E+04 mg/L @ 25 °C (exp) |
Organoleptic Properties:
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Odor Type: ethereal |
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Odor Strength: | high , recommend smelling in a 1.00 % solution or less |
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Substantivity: | < 1 hour(s) at 100.00 % |
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| ethereal green nutty earthy sweet vegetable |
Odor Description: at 1.00 % in propylene glycol. | ether green nut earthy sweet vegetable Luebke, William tgsc, (2017) |
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Flavor Type: nutty |
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| nutty earthy vegetable |
Taste Description:
| nutty earthy vegetable Luebke, William tgsc, (2017) |
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Odor and/or flavor descriptions from others (if found). |
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Lluch Essence |
ACETALDEHYDE DIETHYL ACETAL |
Odor Description: | ETHEREAL, EARTHY, GREEN |
Taste Description: | nutty |
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Cosmetic Information:
Suppliers:
Advanced Biotech |
ACETAL 30-35% IN ETOH NATURAL
Odor: Alcoholic, Whisky, nutty |
Advanced Biotech |
ACETAL NATURAL
98% min. Odor: Whisky, nutty |
Alfrebro |
ACETAL NATURAL 30 - 35% IN ETHANOL
Odor: Strong, fruity |
Augustus Oils |
Acetal
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Services |
Axxence Aromatic |
ACETAL 98%, Natural
Kosher |
Sustainability |
Beijing Lys Chemicals |
Acetal
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Charkit Chemical |
ACETAL FEMA 2002
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CJ Latta & Associates |
ACETALS
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Ernesto Ventós |
ACETAL (ACETALDEHYDE DIETHYL ACETAL)
Odor: EARTHY,ETHEREAL,GREEN,NUTTY,SWEET |
Excellentia International |
Acetal Natural
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Fleurchem |
acetal natural
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Frutarom |
ACETAL (1,1-DIETHOXYETHANE)
KOSHER Flavor: Green, Nutty, Earthy, Sweet, Vegetable |
CBD Offering |
IFF |
ACETAL (1,1-DIETHOXYETHANE)
KOSHER Flavor: Green, Nutty, Earthy, Sweet, Vegetable |
Indukern F&F |
ACETAL
Odor: ETHEREAL, FRUITY |
Inoue Perfumery |
ACETALDEHYDE DIETHYL ACETAL
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Jiangyin Healthway |
Acetal Natural99%
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New functional food ingredients |
Keva |
1,1-DIETHOXYETHANE
Odor: Fruity, green |
Lluch Essence |
1,1-DIETHOXYETHANE ® PFW
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Lluch Essence |
ACETAL NATURAL 98%
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Lluch Essence |
ACETALDEHYDE DIETHYL ACETAL
Odor: ETHEREAL, EARTHY, GREEN |
M&U International |
Acetal, Kosher
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M&U International |
Nat. Acetal
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Natural Advantage |
Acetal Nat, 35% in OH
Flavor: alcoholic, ethereal, fruity, green, nutty, sweet |
Riverside Aromatics LTD.is the exclusive distributor for Europe in UK for any non-US based inquiries |
Natural Advantage |
Acetal-98 Nat
Flavor: alcoholic, ethereal, fruity, green, nutty, sweet |
PCW France |
1,1-Diethoxyethane
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Steps to a fragranced product |
Penta International |
ACETALDEHYDE DIETHYL ACETAL NATURAL
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Penta International |
ACETALDEHYDE DIETHYL ACETAL
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Pfaltz & Bauer |
For experimental / research use only. |
Acetaldehyde diethyl acetal
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Reincke & Fichtner |
Acetal
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Riverside Aromatics |
ACETAL, NATURAL
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Riverside Aromatics |
ACETAL, NATURAL
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Robertet |
ACETAL
Pure & Nat |
Seasons and Harvest / Crop calendar |
Seqens |
ACETALDEHYDE DIETHYLACETAL
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Sigma-Aldrich |
Acetal, ≥98%, FG
Odor: honey; green; floral; tart |
Certified Food Grade Products |
Sigma-Aldrich |
Acetal, natural, FG, ≥97%
Odor: honey; green; floral; tart |
Silverline Chemicals |
Diethyl Acetal
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SRS Aromatics |
1,1-DIETHOXYETHANE
Odor: Ether, Green, Nut, Earthy, Sweet, Vegetable |
Taytonn ASCC |
Acetal
Odor: Earthy, Ethereal, Green, Nutty, Sweet |
TCI AMERICA |
For experimental / research use only. |
Acetal >98.0%(GC)
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Ungerer & Company |
Acetal Natural
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Vigon International |
Acetaldehyde Diethyl Acetal Natural
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Vigon International |
Acetaldehyde Diethyl Acetal
Odor: Fruity,Alcoholic,Green,Nutty,Whiskey |
WEN International |
ACETAL Natural
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WholeChem |
Acetal
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Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | Xi - Irritant |
R 11 - Highly flammable. R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 09 - Keep container in a well-ventilated place. S 16 - Keep away from sources of ignition - No Smoking. S 33 - Take precautionary measures against static discharge. S 37/39 - Wear suitable gloves and eye/face protection.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
Skin irritation (Category 2), H315 Eye irritation (Category 2A), H319
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GHS Label elements, including precautionary statements |
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Pictogram | |
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Signal word | Danger |
Hazard statement(s) |
H225 - Highly Flammable liquid and vapour H315 - Causes skin irritation H319 - Causes serious eye irritation
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Precautionary statement(s) |
P210 - Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/…/equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P264 - Wash skin thouroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313 - IF SKIN irritation occurs: Get medical advice/attention. P337 + P313 - IF eye irritation persists: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P403 + P235 - Store in a well-ventilated place. Keep cool. P501 - Dispose of contents/ container to an approved waste disposal plant.
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Oral/Parenteral Toxicity: |
oral-rat LD50 4600 mg/kg Medizin und Ernaehrung. Vol. 8, Pg. 244, 1967.
intraperitoneal-rat LD50 900 mg/kg "Industrial Hygiene and Toxicology," 2nd ed., Patty, F.A., ed., New York, John Wiley & Sons, Inc., 1958-63Vol. 2, Pg. 1982, 1963.
oral-rabbit LD50 3545 mg/kg Proceedings of the Society for Experimental Biology and Medicine. Vol. 29, Pg. 730, 1932.
oral-mouse LD50 3500 mg/kg Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 42(3), Pg. 12, 1977.
intraperitoneal-mouse LD50 500 mg/kg National Technical Information Service. Vol. AD277-689
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
inhalation-rat LCLo 4000 ppm/4H Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 343, 1949.
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Safety in Use Information:
Category: | flavoring agents and cosmetic fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for acetal usage levels up to: | | 0.1000 % in the fragrance concentrate.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 200.00 (μg/capita/day) |
Maximised Survey-derived Daily Intakes (MSDI-USA): | 640.00 (μg/capita/day) |
Threshold of Concern: | 1800 (μg/person/day) |
Structure Class: | I |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 3. Update in publication number(s): 29 |
Click here to view publication 3 |
| average usual ppm | average maximum ppm |
baked goods: | 65.00000 | 120.00000 |
beverages(nonalcoholic): | 5.00000 | 11.00000 |
beverages(alcoholic): | 109.00000 | 154.00000 |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | 155.00000 | 155.00000 |
condiments / relishes: | - | - |
confectionery froastings: | - | - |
egg products: | - | - |
fats / oils: | 2.00000 | 3.00000 |
fish products: | - | - |
frozen dairy: | 36.00000 | 73.00000 |
fruit ices: | - | - |
gelatins / puddings: | 36.00000 | 67.00000 |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | 4.00000 | 39.00000 |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | - |
meat products: | - | - |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | 33.00000 | 56.00000 |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
Safety References:
European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 3 (FGE.03); Acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated aldehydes, and a orthoester of formic acid, from chemical groups 1 and 2 (Commission Regulation (EC) No 1565/2000 of 18 July 2000) View page or View pdf |
Flavouring Group Evaluation 3, Revision 1 (FGE.03Rev1): Acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated or unsaturated aldehydes, an ester of a hemiacetal and an orthoester of formic acid, from chemical groups 1, 2 & 4 Commission Regulation (EC) No 1565/2000 of 18 July 2000) [1] - Scientific Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)on a request from the Commission View page or View pdf |
Flavouring Group Evaluation 61 (FGE.61): Consideration of aliphatic acyclic acetals evaluated by JECFA (57th meeting) structurally related to acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated aldehydes, and an orthoester of formic acid evaluated by EFSA in FGE.03 (2004) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) View page or View pdf |
Flavouring Group Evaluation 61, Revision 1 (FGE.61Rev1): Consideration of aliphatic acetals evaluated by JECFA (57th meeting) structurally related to acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated aldehydes and one orthoester of formic acid evaluated View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 3, Revision 2 (FGE.03Rev2): Acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated or unsaturated aldehydes, an ester of a hemiacetal and an orthoester of formic acid, from chemical groups 1, 2 and 4 View page or View pdf |
Scientific Opinion on the safety and efficacy of straight-chain primary aliphatic alcohols/aldehydes/acids, acetals and esters with esters containing saturated alcohols and acetals containing saturated aldehydes (chemical group 1) when used as flavourings for all animal species View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 61 Revision 2 (FGE.61Rev2): consideration of aliphatic acetals evaluated by JECFA (57th, 63rd and 68th meetings) structurally related to acetals evaluated by EFSA in FGE.03Rev2 View page or View pdf |
EPI System: | View |
NIOSH International Chemical Safety Cards: | search |
AIDS Citations: | Search |
Cancer Citations: | Search |
Toxicology Citations: | Search |
EPA Substance Registry Services (TSCA): | 105-57-7 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 7765 |
National Institute of Allergy and Infectious Diseases: | Data |
WISER: | UN 1088 |
WGK Germany: | 2 |
| 1,1-diethoxyethane |
Chemidplus: | 0000105577 |
EPA/NOAA CAMEO: | hazardous materials |
RTECS: | 105-57-7 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| acetal | | acetal (1,1-diethoxyethane) | | acetal (acetaldehyde diethyl acetal) | | acetal (natural) | | acetal 30-35% in ETOH natural | | acetal natural | | acetaldehyde diethyl acetal | | acetaldehyde diethylacetal | | acetaldehyde ethyl acetal | 1,1- | diethoxy-ethane | 1,1- | diethoxyethane | | diethyl acetal | | diethylacetal | | ethane, 1,1-diethoxy- | | ethylidine diethyl ether |
Articles:
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