Category: flavoring agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | yellow clear liquid (est) |
Assay: | 65.00 to 100.00 %
|
Food Chemicals Codex Listed: | No |
Specific Gravity: | 1.13500 to 1.17000 @ 25.00 °C.
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Pounds per Gallon - (est).: | 9.444 to 9.736
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Refractive Index: | 1.60000 to 1.62000 @ 20.00 °C.
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Boiling Point: | 112.00 to 120.00 °C. @ 16.00 mm Hg
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Boiling Point: | 95.00 to 97.00 °C. @ 5.00 mm Hg
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Vapor Pressure: | 0.105000 mmHg @ 25.00 °C. (est) |
Vapor Density: | 6.1 ( Air = 1 ) |
Flash Point: | 145.00 °F. TCC ( 62.78 °C. )
|
logP (o/w): | 3.367 (est) |
Soluble in: |
| ether | | water, 50.65 mg/L @ 25 °C (est) |
Insoluble in: |
| alcohol | | water |
Organoleptic Properties:
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Odor Type: sulfurous |
|
| garlic onion green onion metallic |
Odor Description: at 0.10 % in propylene glycol. | garlic green onion metallic |
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Flavor Type: sulfurous |
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| sulfurous onion green onion garlic metallic |
Taste Description:
| sulfurous green onion garlic metallic |
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Odor and/or flavor descriptions from others (if found). |
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R C Treatt & Co Ltd |
Diallyl Trisulphide NI, Kosher |
Odor Description: | sweet/herbaceous, onion |
Taste Description: | onion Used in onion/garlic flavours in meat and vegetable sauces and dressings at 1ppm. |
|
Taytonn ASCC |
Diallyl Trisulphide 35-40% |
Odor Description: | Alliaceous, Green, Onion |
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Cosmetic Information:
Suppliers:
Axsyn |
For experimental / research use only. |
Trisulfide,di-2-propen-1-yl
|
Beijing Lys Chemicals |
Diallyl trisulfide
|
BOC Sciences |
For experimental / research use only. |
Diallyl Trisulfide
|
Carbosynth |
For experimental / research use only. |
Diallyl Trisulfide
|
Charkit Chemical |
DIALLYL TRISULPHIDE D0250 FEMA 3265
|
DeLong Chemicals America |
Diallyl trisulfide, Kosher
|
Frutarom |
DIALLYL TRISULPHIDE 80
KOSHER Flavor: Garlic, Onion, Green, Metallic |
CBD Offering |
IFF |
DIALLYL TRISULPHIDE 80
KOSHER Flavor: Garlic, Onion, Green, Metallic |
Jiangyin Healthway |
Diallyl trisulphide
|
New functional food ingredients |
Lluch Essence |
DIALLYL TRISULFIDE
|
M&U International |
ALLYL TRISULFIDE, Kosher
|
Penta International |
DIALLYL TRISULFIDE
|
R C Treatt & Co Ltd |
Diallyl Trisulphide
NI, Kosher Odor: sweet/herbaceous, onion Flavor: onion Used in onion/garlic flavours in meat and vegetable sauces and dressings at 1ppm. |
Santa Cruz Biotechnology |
For experimental / research use only. |
Diallyl Trisulfide ≥98%
|
Sigma-Aldrich: Sigma |
For experimental / research use only. |
Diallyl Trisulfide ≥98% (HPLC)
|
Taytonn ASCC |
Diallyl Trisulphide 35-40%
Odor: Alliaceous, Green, Onion |
Tengzhou Jitian Aroma Chemiclal |
Diallyl Trisulfide
|
Tianjin Danjun International |
Diallyl trisulfide
|
United International |
Diallyl Trisulfide
|
WholeChem |
Diallyl trisulfide
|
Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | Xi - Irritant |
R 36/37/38 - Irritating to eyes, respiratory system, and skin. S 02 - Keep out of the reach of children. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
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|
Hazards identification |
|
Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
oral-mouse LD50 [sex: M,F] 100 - 400 mg/kg Not definitive test (Moran et al., 1980)
oral-mouse LD50 100 mg/kg Drug and Chemical Toxicology. Vol. 3, Pg. 249, 1980.
|
Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
|
Safety in Use Information:
Category: | flavoring agents |
IFRA Purity Specification: | < 0.1% free allyl alcohol |
Recommendation for diallyl trisulfide usage levels up to: | | not for fragrance use.
|
|
Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.05 (μg/capita/day) |
Maximised Survey-derived Daily Intakes (MSDI-USA): | 0.02 (μg/capita/day) |
Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 348 (μg/person/day) |
NOEL (No Observed Effect Level): | 4.6 (mg/kg bw per day) |
Threshold of Concern: | 540 (μg/person/day) |
Structure Class: | II |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 5 |
Click here to view publication 5 |
| average usual ppm | average maximum ppm |
baked goods: | - | 1.00000 |
beverages(nonalcoholic): | - | - |
beverages(alcoholic): | - | - |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | - | - |
condiments / relishes: | - | 1.00000 |
confectionery froastings: | - | - |
egg products: | - | - |
fats / oils: | - | - |
fish products: | - | - |
frozen dairy: | - | - |
fruit ices: | - | - |
gelatins / puddings: | - | - |
granulated sugar: | - | - |
gravies: | - | 1.00000 |
hard candy: | - | - |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | - |
meat products: | - | 1.00000 |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | - | - |
soups: | - | 1.00000 |
sugar substitutes: | - | - |
sweet sauces: | - | - |
|
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). |
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. |
| average usage mg/kg | maximum usage mg/kg |
Dairy products, excluding products of category 02.0 (01.0): | 0.60000 | 2.00000 |
Fats and oils, and fat emulsions (type water-in-oil) (02.0): | 0.04000 | 1.00000 |
Edible ices, including sherbet and sorbet (03.0): | 0.50000 | 2.00000 |
Processed fruit (04.1): | - | - |
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | 0.20000 | 1.50000 |
Confectionery (05.0): | 0.75000 | 2.00000 |
Chewing gum (05.0): | - | - |
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 0.62000 | 1.00000 |
Bakery wares (07.0): | 0.80000 | 2.00000 |
Meat and meat products, including poultry and game (08.0): | 0.73000 | 1.00000 |
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | 0.10000 | 1.00000 |
Eggs and egg products (10.0): | 0.08000 | 1.00000 |
Sweeteners, including honey (11.0): | - | - |
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 0.45000 | 1.00000 |
Foodstuffs intended for particular nutritional uses (13.0): | - | - |
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | 0.50000 | 1.00000 |
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 0.10000 | 2.00000 |
Ready-to-eat savouries (15.0): | 1.10000 | 5.00000 |
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | - | - |
Safety References:
European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 8 (FGE.08)[1]: Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical group 20 View page or View pdf |
Flavouring Group Evaluation 74 (FGE.74)[1]: Consideration of Simple Aliphatic Sulphides and Thiols evaluated by JECFA (61st meeting) Structurally related to Aliphatic and Alicyclic Mono-, Di-, Tri-, and Polysulphides with or without Additional Oxygenated Functional Groups from Chemical Group 20 evaluated by EFSA in FGE.08 (2008) View page or View pdf |
Flavouring Group Evaluation 8, Revision 1 (FGE.08Rev1): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Flavouring Group Evaluation 91 (FGE.91): Consideration of simple aliphatic and aromatic sulphides and thiols evaluated by JECFA (53rd and 68th meetings) structurally related to aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups evaluated by EFSA in FGE.08Rev1 (2009) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 74, Revision 1 (FGE.74Rev1): Consideration of Simple Aliphatic Sulphides and Thiols evaluated by the JECFA (53rd and 61st meeting) Structurally related to Aliphatic and Alicyclic Mono-, Di-, Tri-, and Polysulphides with or without Additional Oxygenated Functional Groups from Chemical Group 20 evaluated by EFSA in FGE.08Rev1 (2009) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 8, Revision 3 (FGE.08Rev3): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 74, Revision 2 (FGE.74Rev2): Consideration of Simple Aliphatic Sulphides and Thiols evaluated by the JECFA (53rd and 61st meeting) Structurally related to Aliphatic and Alicyclic Mono-, Di-, Tri-, and Polysulphides with or without Additional Oxygenated Functional Groups from Chemical Group 20 evaluated by EFSA in FGE.08Rev3 (2011) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 08, Revision 4 (FGE.08Rev4): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Statement on List of Representative Substances for Testing.
The current Statement lays down a list of substances in sub-groups with representative substances for which additional data are required prior to their evaluation through the Procedure (Regulation (EC) No 1565/2000). View page or View pdf |
Scientific Opinion on the safety and efficacy of aliphatic and aromatic mono- and di-thiols and mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups (chemical group 20) when used as flavourings for all animal species View page or View pdf |
EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 74, Revision 4 (FGE.74Rev4): Consideration of aliphatic sulphides and thiols evaluated by JECFA (53rd and 61st meeting) structurally related to aliphatic and alicyclic mono-, di-, tri- and polysulphides with or without additional oxygenated functional groups from chemical group 20 evaluated by EFSA in FGE.08Rev5 View page or View pdf |
EPI System: | View |
Chemical Carcinogenesis Research Information System: | Search |
AIDS Citations: | Search |
Cancer Citations: | Search |
Toxicology Citations: | Search |
EPA Substance Registry Services (TSCA): | 2050-87-5 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 16315 |
National Institute of Allergy and Infectious Diseases: | Data |
WGK Germany: | 3 |
| 3-prop-2-enylsulfanyldisulfanylprop-1-ene |
Chemidplus: | 0002050875 |
RTECS: | BC6168000 for cas# 2050-87-5 |
References:
Other Information:
Potential Blenders and core components note
|
For Odor |
No odor group found for these |
green | onion oleoresin | FL/FR |
| allium sativum oil egypt | FL/FR |
| dibutyl sulfide | FL/FR |
| dimethyl trisulfide | FL/FR |
| dipropyl disulfide | FL/FR |
| ferula assa-foetida gum oil | FL/FR |
| garlic oil | FL/FR |
| garlic oil china | FL/FR |
| garlic oil mexico | FL/FR |
| methyl furfuryl disulfide | FL/FR |
| propyl mercaptan | FL/FR |
coffee |
| coffee difuran | FL/FR |
ethereal |
2- | methyl-1-butanol | FL/FR |
fermented |
| ethyl (E)-2-crotonate | FL/FR |
| ferula assa-foetida gum | FL/FR |
meaty |
| meaty dithiane | FL/FR |
spicy |
| ethyl vinyl ketone | FL/FR |
sulfurous |
2- | acetyl thiophene | FL/FR |
| cassis pentanone | FL/FR |
| dimethyl disulfide | FL/FR |
| dimethyl sulfide | FL/FR |
| ethyl 2-mercaptopropionate | FL/FR |
| ethyl methyl mercaptopropionate | FL/FR |
| ferula assa-foetida absolute | FL/FR |
| ferula assa-foetida gum extract | FL/FR |
| furfuryl thioacetate | FL/FR |
| lychee mercaptan acetate | FL/FR |
| mango thiol | FL/FR |
| methyl 3-(methyl thio) propionate | FL/FR |
2- | methyl 5-(methyl thio) furan | FL/FR |
O- | methyl S-1-methoxyhexan-3-yl carbonothioate | FL/FR |
3-( | methyl thio) hexanol | FL/FR |
2-( | methyl thio) phenol | FL/FR |
| onion oil | FL/FR |
| onion oil CO2 extract | FL/FR |
| onion oil dutch | FL/FR |
| onion oil egypt | FL/FR |
| onion oil mexico | FL/FR |
2- | phenethyl isothiocyanate | FL/FR |
4- | tropical oxathiane | FL/FR |
tropical |
cis- | galbanum oxathiane | FL/FR |
trans- | galbanum oxathiane | FL/FR |
vegetable |
1- | furfuryl pyrrole | FL/FR |
| methional | FL/FR |
yeasty |
2- | octen-4-one | FL/FR |
|
For Flavor |
|
No flavor group found for these |
| allyl methyl disulfide | FL |
| allyl methyl trisulfide | FL |
| allyl propyl disulfide | FL |
| allyl propyl sulfide | FL |
| allyl propyl trisulfide | FL |
iso | amyl mercaptan | FL |
| butyl isothiocyanate | FL |
| diallyl hexasulfide | FL |
| diethyl trisulfide | FL |
| diisoamyl disulfide | FL |
(Z+E)-2,5- | dimethyl-3-tetrahydrofuran thiol | FL |
(Z+E)-2,5- | dimethyl-3-thioacetoxytetrahydrofuran | FL |
| dipropyl sulfide | FL |
| ethyl 2-(methyl thio) acetate | FL |
| ethyl 3-(methyl thio)-(E)-2-propenoate | FL |
| ethyl methyl trisulfide | FL |
| ethyl propyl disulfide | FL |
| ethyl propyl trisulfide | FL |
trans- | galbanum oxathiane | FL/FR |
2- | heptane thiol | FL |
3- | mercapto-3-methyl butyl formate | FL |
4- | mercapto-3-methyl-2-butanol | FL |
3- | mercaptohexanal | FL |
bis(1- | mercaptopropyl) sulfide | FL |
| methyl butyl sulfide | FL |
4- | methyl-2-(methyl thiomethyl)-2-hexenal | FL |
2- | methyl-5-methoxythiazole | FL |
2- | phenethyl isothiocyanate | FL/FR |
| prenyl mercaptan | FL |
iso | propyl disulfide | FL |
|
(±)-3,5- | diethyl-1,2,4-trithiolane | FL |
alliaceous |
| allium porrum extract | FL |
| allium sativum oil egypt | FL/FR |
| allyl disulfide | FL |
| allyl mercaptan | FL |
| allyl thiopropionate | FL |
| benzyl mercaptan | FL |
1,3- | butane dithiol | FL |
| chive extract | FL |
| cyclopentyl mercaptan | FL |
| dicyclohexyl disulfide | FL |
| diethyl disulfide | FL |
| dimethyl trisulfide | FL/FR |
| dipropyl disulfide | FL/FR |
| dipropyl trisulfide | FL |
| ferula assa-foetida gum oil | FL/FR |
| garlic oil | FL/FR |
| garlic oil china | FL/FR |
| garlic oil extenders | FL |
| garlic oil mexico | FL/FR |
smoked | garlic oleoresin | FL |
fried | garlic oleoresin | FL |
| leek oil | FL |
3- | mercapto-2-pentanone | FL |
| methyl 3-mercaptobutanoate | FL |
2- | methyl thioacetaldehyde | FL |
| onion oil extenders | FL |
| propyl mercaptan | FL/FR |
| shallot oil | FL |
3- | tetrahydrothiophenone | FL |
| truffle sulfide | FL |
coffee |
| coffee difuran | FL/FR |
| methyl furfuryl disulfide | FL/FR |
| methyl furfuryl thiol | FL |
corn chip |
2- | acetyl-2-thiazoline | FL |
eggy |
iso | propyl mercaptan | FL |
ethereal |
2- | methyl-1-butanol | FL/FR |
fatty |
| dimethyl sulfoxide | FL |
fruity |
4- | tropical oxathiane | FL/FR |
garlic |
| allium sativum bulb tincture | FL |
| allyl methyl sulfide | FL |
| ferula assa-foetida gum | FL/FR |
| garlic distillates | FL |
| garlic flavor | FL |
sauteed | garlic flavor | FL |
black | garlic flavor | FL |
| garlic oil CO2 extract | FL |
| garlic oleoresin | FL |
2- | pentenyl-4-propyl-1,3-oxathiane (mixture of isomers) | FL |
green |
| cassis pentanone | FL/FR |
| dibutyl sulfide | FL/FR |
cis- | galbanum oxathiane | FL/FR |
juicy |
| lychee mercaptan acetate | FL/FR |
meaty |
| meaty dithiane | FL/FR |
3- | mercapto-2-butanone | FL |
(R,S)-2- | mercapto-3-butanol | FL |
2-( | methyl thio) phenol | FL/FR |
bis(2- | methyl-3-furyl) disulfide | FL |
2- | methyl-3-tetrahydrofuran thiol | FL |
ortho- | thiocresol | FL |
metallic |
3-( | methyl thio) hexanol | FL/FR |
mushroom |
| methional diethyl acetal | FL |
musty |
| ethyl (E)-2-crotonate | FL/FR |
2- | methyl 5-(methyl thio) furan | FL/FR |
onion |
2- | acetyl thiophene | FL/FR |
| ethyl 2-mercaptopropionate | FL/FR |
| furfuryl isopropyl sulfide | FL |
| methionol | FL |
| methyl propyl disulfide | FL |
| methyl propyl trisulfide | FL |
2- | methyl-1,3-dithiolane | FL |
red | onion flavor | FL |
yellow | onion flavor | FL |
maui | onion flavor | FL |
vidalia | onion flavor | FL |
white | onion flavor | FL |
green | onion flavor | FL |
| onion flavor | FL |
| onion juice concentrate | FL |
| propyl thioacetate | FL |
| scallion flavor | FL |
| shallot oleoresin | FL |
roasted |
| ethyl 3-(furfuryl thio) propionate | FL |
| furfuryl thioacetate | FL/FR |
O- | methyl S-1-methoxyhexan-3-yl carbonothioate | FL/FR |
savory |
2,4,6- | triethyl tetrahydro-1,3,5-dithiazine | FL |
seafood |
1,4- | dithiane | FL |
spicy |
| ethyl vinyl ketone | FL/FR |
sulfurous |
| allium sativum bulb extract | FL |
| allyl sulfide | FL |
| butyl mercaptan | FL |
| diallyl polysulfides | FL |
| diallyl tetrasulfide | FL |
| dimethyl disulfide | FL/FR |
| dimethyl sulfide | FL/FR |
| ethyl methyl mercaptopropionate | FL/FR |
S- | ethyl thioacetate | FL |
| ferula assa-foetida absolute | FL/FR |
| ferula assa-foetida fluid extract | FL |
| ferula assa-foetida gum extract | FL/FR |
| ferula assa-foetida oleoresin | FL |
| furfuryl methyl sulfide | FL |
| furfuryl thiopropionate | FL |
| mango thiol | FL/FR |
3- | mercapto-2-methyl pentanal | FL |
3- | mercapto-2-methyl-1-butanol | FL |
| methyl 2-(methyl thio) butyrate | FL |
| methyl 2-methyl-3-furyl disulfide | FL |
| methyl 4-(methyl thio) butyrate | FL |
| methyl benzyl disulfide | FL |
1-( | methyl thio)-2-butanone | FL |
| methyl thiomethyl butyrate | FL |
2- | methyl thiophene | FL |
3- | methyl-2-butane thiol | FL |
| onion oil | FL/FR |
| onion oil CO2 extract | FL/FR |
| onion oil dutch | FL/FR |
| onion oil egypt | FL/FR |
| onion oil mexico | FL/FR |
| onion oleoresin | FL |
sauteed sweet | onion oleoresin | FL |
green | onion oleoresin | FL/FR |
caramelized | onion oleoresin | FL |
2,4,6- | trithiaheptane 10% in triacetin | FL |
tomato |
| methional | FL/FR |
vegetable |
alpha- | benzylidene methional | FL |
1- | furfuryl pyrrole | FL/FR |
| methyl 3-(methyl thio) propionate | FL/FR |
2- | octen-4-one | FL/FR |
| potato butyraldehyde | FL |
|
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| allitridin | | allitridum | | allyl trisulfide | | dasuansu | | di-2-propenyl trisulfide | | diallyl trisulphide | | diallyltrisulfane | | diallyltrisulfide | | diprop-2-en-1-yltrisulfane | | prop-2-enyl prop-2-enylthio disulfide | 3- | prop-2-enylsulfanyldisulfanylprop-1-ene | | trisulfane, 1,3-di-2-propen-1-yl- | | trisulfide, di-2-propenyl | | trisulfide, diallyl |
Articles:
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