Category: flavoring agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Organoleptic Properties:
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Odor Type: alliaceous |
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| sharp alliaceous onion sulfurous garlic horseradish minty coffee |
Odor Description: at 0.10 % in propylene glycol. | sharp alliaceous onion sulfurous garlic horseradish mint coffee |
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| sharp sulfurous onion garlic horseradish minty coffee |
Odor Description:
| Sharp, sulfuraceous, onion, garlic, horseradish, mint and coffee Mosciano, Gerard P&F 14, No. 6, 47, (1989) |
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Flavor Type: alliaceous |
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| leek horseradish cabbage green tomato coffee |
Taste Description: at 15.00 ppm. | Leek, horseradish, cabbage, green, tomato and coffee Mosciano, Gerard P&F 14, No. 6, 47, (1989) |
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Odor and/or flavor descriptions from others (if found). |
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Cosmetic Information:
Suppliers:
Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | T - Toxic. |
R 22 - Harmful if swallowed. R 23 - Toxic by inhalation. S 02 - Keep out of the reach of children. S 23 - Do not breath vapour. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection. S 45 - In case of accident or if you feel unwell seek medical advice immediately.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
oral-rat LD50 493 mg/kg LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
BEHAVIORAL: COMA American Industrial Hygiene Association Journal. Vol. 19, Pg. 171, 1958.
intraperitoneal-rat LD50 373 mg/kg BEHAVIORAL: COMA
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION American Industrial Hygiene Association Journal. Vol. 19, Pg. 171, 1958.
intraperitoneal-mouse LD50 100 mg/kg National Technical Information Service. Vol. AD277-689
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
inhalation-mouse LC50 178 ppm/4H BEHAVIORAL: ATAXIA
BEHAVIORAL: MUSCLE WEAKNESS
LUNGS, THORAX, OR RESPIRATION: CYANOSIS American Industrial Hygiene Association Journal. Vol. 19, Pg. 171, 1958.
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Safety in Use Information:
Category: | flavoring agents |
Recommendation for benzyl mercaptan usage levels up to: | | not for fragrance use.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 1.20 (μg/capita/day) |
Structure Class: | II |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 3 |
Click here to view publication 3 |
| average usual ppm | average maximum ppm |
baked goods: | 0.50000 | 0.75000 |
beverages(nonalcoholic): | 0.15000 | 0.25000 |
beverages(alcoholic): | - | - |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | - | - |
condiments / relishes: | - | - |
confectionery froastings: | - | - |
egg products: | - | - |
fats / oils: | - | - |
fish products: | - | - |
frozen dairy: | 0.15000 | 0.50000 |
fruit ices: | 0.15000 | 0.50000 |
gelatins / puddings: | - | - |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | 0.50000 | 0.75000 |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | - |
meat products: | - | - |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | - | - |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
Safety References:
European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 8 (FGE.08)[1]: Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical group 20 View page or View pdf |
Flavouring Group Evaluation 74 (FGE.74)[1]: Consideration of Simple Aliphatic Sulphides and Thiols evaluated by JECFA (61st meeting) Structurally related to Aliphatic and Alicyclic Mono-, Di-, Tri-, and Polysulphides with or without Additional Oxygenated Functional Groups from Chemical Group 20 evaluated by EFSA in FGE.08 (2008) View page or View pdf |
Flavouring Group Evaluation 8, Revision 1 (FGE.08Rev1): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Flavouring Group Evaluation 91 (FGE.91): Consideration of simple aliphatic and aromatic sulphides and thiols evaluated by JECFA (53rd and 68th meetings) structurally related to aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups evaluated by EFSA in FGE.08Rev1 (2009) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 8, Revision 3 (FGE.08Rev3): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 08, Revision 4 (FGE.08Rev4): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Safety and efficacy of eight compounds belonging to different chemical groups when used as flavourings for cats and dogs View page or View pdf |
EPI System: | View |
Chemical Carcinogenesis Research Information System: | Search |
AIDS Citations: | Search |
Cancer Citations: | Search |
Toxicology Citations: | Search |
EPA Substance Registry Services (TSCA): | 100-53-8 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 7509 |
National Institute of Allergy and Infectious Diseases: | Data |
WGK Germany: | 3 |
| phenylmethanethiol |
Chemidplus: | 0000100538 |
RTECS: | XT8650000 for cas# 100-53-8 |
References:
Other Information:
Potential Blenders and core components note
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For Odor |
alliaceous |
| dimethyl trisulfide | FL/FR |
| dipropyl disulfide | FL/FR |
| ferula assa-foetida gum oil | FL/FR |
| garlic oil china | FL/FR |
| methyl furfuryl disulfide | FL/FR |
| propyl mercaptan | FL/FR |
S-( | methyl thio) butyrate | FL/FR |
citrus |
| grapefruit mercaptan | FL/FR |
coffee |
| coffee difuran | FL/FR |
creamy |
2,3- | butane diol | FR |
ethereal |
2- | methyl-1-butanol | FL/FR |
floral |
| petitgrain lemon oil | FL/FR |
fruity |
| furfuryl acetate | FL/FR |
green |
2-iso | butyl thiazole | FL/FR |
| geranium thiazole | FL/FR |
| green dioxolane | FR |
1- | hepten-3-ol | FL/FR |
(Z)-4- | hexen-1-ol | FL/FR |
(E)-4- | hexen-1-ol | |
(Z)-3- | hexen-1-yl tiglate | FL/FR |
3- | hexenal | FL/FR |
1- | penten-3-ol | FL/FR |
(E)-2- | pentenal | FL/FR |
malty |
S- | methyl methioninium chloride | |
meaty |
| meaty dithiane | FL/FR |
soapy |
| benzyl laurate | FL/FR |
spicy |
| ethyl vinyl ketone | FL/FR |
| cassis pentanone | FL/FR |
| dimethyl disulfide | FL/FR |
| dimethyl sulfide | FL/FR |
| ethyl methyl mercaptopropionate | FL/FR |
| ferula assa-foetida absolute | FL/FR |
| methyl 3-(methyl thio) propionate | FL/FR |
2- | methyl 5-(methyl thio) furan | FL/FR |
| methyl mercaptan | FL/FR |
3-( | methyl thio) hexanol | FL/FR |
2-( | methyl thio) phenol | FL/FR |
| onion oil | FL/FR |
2- | phenethyl isothiocyanate | FL/FR |
S- | tropical 2-thiobutyrate | FL/FR |
4- | tropical oxathiane | FL/FR |
vegetable |
| methional | FL/FR |
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For Flavor |
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No flavor group found for these |
| allyl methyl disulfide | FL |
| allyl methyl trisulfide | FL |
| allyl propyl disulfide | FL |
| allyl propyl sulfide | FL |
| allyl propyl trisulfide | FL |
iso | amyl mercaptan | FL |
| diethyl trisulfide | FL |
| diisopropyl sulfide | FL |
| diisopropyl trisulfide | FL |
| dimethyl tetrasulfide | FL |
(Z+E)-2,5- | dimethyl-3-tetrahydrofuran thiol | FL |
(Z+E)-2,5- | dimethyl-3-thioacetoxytetrahydrofuran | FL |
| dipropyl sulfide | FL |
| ethyl isothiocyanate | FL |
| ethyl methyl trisulfide | FL |
| ethyl propyl disulfide | FL |
| ethyl propyl trisulfide | FL |
| heptyl mercaptan | FL |
4- | mercapto-3-methyl-2-butanol | FL |
| mercaptoacetaldehyde | FL |
| methyl butyl sulfide | FL |
4-( | methyl thio) butanol | FL |
2-( | methyl thio) methyl-2-butenal | FL |
4- | methyl thiobutyl isothiocyanate | FL |
6- | methyl thiohexyl isothiocyanate | FL |
5- | methyl thiopentyl isothiocyanate | FL |
2- | methyl-5-methoxythiazole | FL |
4- | pentenyl isothiocyanate | FL |
2- | phenethyl isothiocyanate | FL/FR |
| propenyl propyl disulfide | FL |
iso | propyl disulfide | FL |
| tetrahydrothiophene | FL |
| thiophene | FL |
2,3,5- | trithiahexane | FL |
S- | tropical 2-thiobutyrate | FL/FR |
alliaceous |
| allyl disulfide | FL |
| allyl mercaptan | FL |
| allyl thiopropionate | FL |
1,3- | butane dithiol | FL |
| cyclopentyl mercaptan | FL |
| dicyclohexyl disulfide | FL |
| diethyl disulfide | FL |
| dimethyl trisulfide | FL/FR |
| dipropyl disulfide | FL/FR |
| dipropyl trisulfide | FL |
| ferula assa-foetida gum oil | FL/FR |
| garlic oil china | FL/FR |
3- | mercapto-2-methyl pentanol | FL |
3- | mercapto-2-pentanone | FL |
| methyl 3-mercaptobutanoate | FL |
2- | methyl thioacetaldehyde | FL |
| propyl mercaptan | FL/FR |
3- | tetrahydrothiophenone | FL |
| truffle sulfide | FL |
burnt |
| methyl phenyl disulfide | FL |
cabbage |
| methyl 2-thiofuroate | FL |
citrus |
| grapefruit mercaptan | FL/FR |
| petitgrain lemon oil | FL/FR |
coffee |
| coffee difuran | FL/FR |
| methyl furfuryl disulfide | FL/FR |
corn chip |
2- | acetyl-2-thiazoline | FL |
eggy |
iso | propyl mercaptan | FL |
estery |
| furfuryl acetate | FL/FR |
ethereal |
| benzyl laurate | FL/FR |
2- | methyl-1-butanol | FL/FR |
fatty |
| dimethyl sulfoxide | FL |
fermented |
| methyl thio isovalerate | FL |
fruity |
| methionyl butyrate | FL |
4- | tropical oxathiane | FL/FR |
garlic |
| allyl methyl sulfide | FL |
| garlic oleoresin | FL |
green |
2-iso | butyl thiazole | FL/FR |
| cassis pentanone | FL/FR |
2- | furyl acetone | FL |
| geranium thiazole | FL/FR |
1- | hepten-3-ol | FL/FR |
(Z)-4- | hexen-1-ol | FL/FR |
(E)-4- | hexen-1-ol | |
(Z)-3- | hexen-1-yl tiglate | FL/FR |
3- | hexenal | FL/FR |
1- | penten-3-ol | FL/FR |
(E)-2- | pentenal | FL/FR |
meaty |
| meaty dithiane | FL/FR |
3- | mercapto-2-butanone | FL |
(R,S)-2- | mercapto-3-butanol | FL |
2-( | methyl thio) phenol | FL/FR |
bis(2- | methyl-3-furyl) disulfide | FL |
| phenyl mercaptan | FL |
| pyrazinyl ethane thiol | FL |
ortho- | thiocresol | FL |
metallic |
2,5- | dihydroxy-1,4-dithiane | FL |
3-( | methyl thio) hexanol | FL/FR |
musty |
2- | methyl 5-(methyl thio) furan | FL/FR |
S-( | methyl thio) butyrate | FL/FR |
onion |
| methionol | FL |
| methyl propyl disulfide | FL |
| methyl propyl trisulfide | FL |
| propyl thioacetate | FL |
roasted |
| ethyl 3-(furfuryl thio) propionate | FL |
| hexyl mercaptan | FL |
seafood |
1,4- | dithiane | FL |
spicy |
| benzyl isothiocyanate | FL |
| ethyl vinyl ketone | FL/FR |
sulfurous |
| allyl sulfide | FL |
| butyl mercaptan | FL |
| diallyl polysulfides | FL |
| diallyl tetrasulfide | FL |
| diallyl trisulfide | FL |
| dimethyl disulfide | FL/FR |
| dimethyl sulfide | FL/FR |
| ethyl methyl mercaptopropionate | FL/FR |
| ethyl methyl sulfide | FL |
S- | ethyl thioacetate | FL |
| ferula assa-foetida absolute | FL/FR |
| furfuryl methyl sulfide | FL |
| furfuryl thiopropionate | FL |
3- | mercapto-2-methyl pentanal | FL |
| methyl 2-(methyl thio) butyrate | FL |
| methyl 2-methyl-3-furyl disulfide | FL |
| methyl 4-(methyl thio) butyrate | FL |
| methyl benzyl disulfide | FL |
| methyl mercaptan | FL/FR |
S- | methyl methioninium chloride | |
1-( | methyl thio)-2-butanone | FL |
| methyl thiomethyl butyrate | FL |
| onion oil | FL/FR |
| onion oleoresin | FL |
| potato butanone | FL |
tomato |
| methional | FL/FR |
vegetable |
| methyl 3-(methyl thio) propionate | FL/FR |
| radish isothiocyanate | FL |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| benzene methane thiol | | benzenemethanethiol | | benzhydrosulfide | | benzyl hydrosulfide | | benzyl mercaptan natural | | benzyl thiol | | benzylhydrosulphide | | benzylmercaptan | | benzylthiol | alpha- | cresyl mercaptan | a- | mercaptoluene | | mercaptomethylbenzene | | mercaptotoluene | alpha- | mercaptotoluene | | phenyl methane thiol | | phenyl methyl mercaptan | | phenylmethanethiol | | thiobenzyl alcohol | a- | toluene thiol | alpha- | toluene thiol | | toluene-a-thiol | a- | toluenethiol | a- | tolyl mercaptan | alpha- | tolyl mercaptan |
Articles:
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