Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless to pale yellow clear liquid (est) |
Assay: | 96.00 to 100.00 %
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 1.12800 to 1.13800 @ 25.00 °C.
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Pounds per Gallon - (est).: | 9.386 to 9.469
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Specific Gravity: | 1.12500 to 1.13300 @ 20.00 °C.
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Pounds per Gallon - est.: | 9.372 to 9.439
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Refractive Index: | 1.57900 to 1.58900 @ 20.00 °C.
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Melting Point: | 5.00 °C. @ 760.00 mm Hg
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Boiling Point: | 169.00 to 170.00 °C. @ 12.00 mm Hg
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Boiling Point: | 273.00 °C. @ 760.00 mm Hg
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Vapor Pressure: | 0.001000 mmHg @ 25.00 °C. (est) |
Vapor Density: | 6.0 ( Air = 1 ) |
Flash Point: | 235.00 °F. TCC ( 112.78 °C. )
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logP (o/w): | 2.878 (est) |
Soluble in: |
| alcohol | | water, very slightly | | water, 1087 mg/L @ 25 °C (est) |
Organoleptic Properties:
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Odor Type: herbal |
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Odor Strength: | high , recommend smelling in a 10.00 % solution or less |
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Substantivity: | 284 hour(s) at 100.00 % |
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| celery herbal cortex lovage maple fenugreek phenolic brothy vegetable brown |
Odor Description: at 10.00 % in dipropylene glycol. | celery herbal cortex lovage maple fenugreek phenolic brothy vegetable brown Luebke, William tgsc, (2021) |
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| celery sweet lovage maple herbal brown vegetable |
Odor Description:
| Celery, sweet, lovage and maple-Iike with herbal, brown, vegetative nuances Mosciano, Gerard P&F 21, No. 1, 33, (1996) |
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Flavor Type: green |
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| green celery cortex lovage phenolic herbal privet vegetable |
Taste Description:
| green celery cortex lovage phenolic herbal privet vegetable Luebke, William tgsc, (2021) |
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| green celery sweet lovage vegetable herbal |
Taste Description: at 25.00 ppm. | Green, celery, sweet and lovage with vegetative and herbal nuances Mosciano, Gerard P&F 21, No. 1, 33, (1996) |
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Odor and/or flavor descriptions from others (if found). |
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Sigma-Aldrich |
3-Propylidenephthalide, mixture of cis and trans isomers, ≥96%, FG |
Odor Description: | woody; floral; sweet; herbaceous; spicy |
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Cosmetic Information:
Suppliers:
BOC Sciences |
For experimental / research use only. |
3-Propylidenephthalide 95%
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Citrus and Allied Essences |
3-Propylidene Phthalide
Odor: powerful, very warm, spicy-herbaceous |
Market Report |
Ernesto Ventós |
APIONAX
Odor: CELERY, HERBACEOUS, SPICY, WARM |
Frutarom |
3-PROPYLIDENEPHTHALIDE
KOSHER Flavor: Celery, Herbaceous, Spicy, Warm |
CBD Offering |
IFF |
3-PROPYLIDENEPHTHALIDE
KOSHER Flavor: Celery, Herbaceous, Spicy, Warm |
Jiangyin Healthway |
3-Propylidenephthalide
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New functional food ingredients |
Lluch Essence |
CELERIAX
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Penta International |
PROPYLIDENE PHTHALIDE
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R C Treatt & Co Ltd |
3-Propylidene Phthalide
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Reincke & Fichtner |
3-Propylidenephthalide
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Sigma-Aldrich |
3-Propylidenephthalide, mixture of cis and trans isomers, ≥96%, FG
Odor: woody; floral; sweet; herbaceous; spicy |
Certified Food Grade Products |
Synerzine |
3-Propylidenephthalide
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Taytonn ASCC |
3-Propylidenephthalide
Odor: Spicy, Herbal/ Herbaceous, Celery, Warm |
TCI AMERICA |
For experimental / research use only. |
3-Propylidenephthalide >96.0%(GC)
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Tianjin Danjun International |
3-n-Propylidenephthalide
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Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | Xn - Harmful. |
R 22 - Harmful if swallowed. R 37/38 - Irritating to respiratory system and skin. S 02 - Keep out of the reach of children. S 20/21 - When using do not eat, drink or smoke. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 - Wear suitable gloves and eye/face protection.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Human Experience: |
0.5 % solution: no irritation or sensitization. |
Oral/Parenteral Toxicity: |
oral-rat LD50 1650 mg/kg (Moreno, 1975r)
oral-rat LD50 1650 mg/kg Food and Cosmetics Toxicology. Vol. 16, Pg. 865, 1978.
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Dermal Toxicity: |
skin-rabbit LD50 > 2500 mg/kg Food and Cosmetics Toxicology. Vol. 16, Pg. 865, 1978.
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
IFRA Critical Effect: | Dermal sensitization |
IFRA: | View Standard |
View IFRA Standards Library for complete information. |
Please review Amendment 49 IFRA documentation for complete information. |
IFRA RESTRICTION LIMITS IN THE FINISHED PRODUCT (%): |
Category 1: Products applied to the lips |
0.071 % |
Category 2: Products applied to the axillae |
0.021 % |
Category 3: Products applied to the face/body using fingertips |
0.42 % |
Category 4: Products related to fine fragrance |
0.40 % |
| Category 5: Products applied to the face and body using the hands (palms), primarily leave-on |
Category 5A: Body lotion products applied to the body using the hands (palms), primarily leave-on |
0.10 % |
Category 5B: Face moisturizer products applied to the face using the hands (palms), primarily leave-on |
0.10 % |
Category 5C: Hand cream products applied to the hands using the hands (palms), primarily leave-on |
0.10 % |
Category 5D: Baby Creams, baby Oils and baby talc |
0.10 % |
Category 6: Products with oral and lip exposure |
0.23 % |
| Category 7: Products applied to the hair with some hand contact |
Category 7A: Rinse-off products applied to the hair with some hand contact |
0.81 % |
Category 7B: Leave-on products applied to the hair with some hand contact |
0.81 % |
Category 8: Products with significant anogenital exposure |
0.041 % |
Category 9: Products with body and hand exposure, primarily rinse off |
0.77 % |
| Category 10: Household care products with mostly hand contact |
Category 10A: Household care excluding aerosol products (excluding aerosol/spray products) |
2.80 % |
Category 10B: Household aerosol/spray products |
2.80 % |
| Category 11: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate |
Category 11A: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure |
1.50 % |
Category 11B: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure |
1.50 % |
Category 12: Products not intended for direct skin contact, minimal or insignificant transfer to skin |
No Restriction |
| Notes: |
IFRA FLAVOR REQUIREMENTS: |
Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards. |
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 17.00 (μg/capita/day) |
Maximised Survey-derived Daily Intakes (MSDI-USA): | 52.00 (μg/capita/day) |
Structure Class: | III |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 3 |
Click here to view publication 3 |
| average usual ppm | average maximum ppm |
baked goods: | - | 5.00000 |
beverages(nonalcoholic): | - | - |
beverages(alcoholic): | - | - |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | - | - |
condiments / relishes: | - | - |
confectionery froastings: | - | - |
egg products: | - | - |
fats / oils: | - | - |
fish products: | - | - |
frozen dairy: | - | 5.00000 |
fruit ices: | - | 5.00000 |
gelatins / puddings: | - | - |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | - | 5.00000 |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | - |
meat products: | - | - |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | - | - |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
Safety References:
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| apionax | | celeriax (IFF) | 4,5- | dihydro-3-(1-propylidene)-phthalide | | propylidene phthalide | iso | propylidene phthalide | 3- | propylidene-1-benzo[c]furanone | 3- | propylidene-1(3H)-isobenzofuranone | 3- | propylidene-2-benzofuran-1-one | 3- | propylidene-2-benzofuran-1(3H)-one | 3- | propylidenephthalide | N- | propylidenephthalide |
Articles:
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