Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless clear liquid (est) |
Assay: | 95.00 to 100.00 %
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 0.91400 to 0.92200 @ 25.00 °C.
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Pounds per Gallon - (est).: | 7.605 to 7.672
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Specific Gravity: | 0.91500 to 0.92300 @ 20.00 °C.
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Pounds per Gallon - est.: | 7.623 to 7.689
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Refractive Index: | 1.42700 to 1.43100 @ 20.00 °C.
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Boiling Point: | 151.00 to 152.00 °C. @ 752.00 mm Hg
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Boiling Point: | 148.00 to 149.00 °C. @ 760.00 mm Hg
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Vapor Pressure: | 3.987000 mmHg @ 25.00 °C. (est) |
Flash Point: | 121.00 °F. TCC ( 49.44 °C. )
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logP (o/w): | 1.650 |
Shelf Life: | 36.00 month(s) or longer if stored properly. |
Storage: | store in cool, dry place in tightly sealed containers, protected from heat and light. |
Soluble in: |
| alcohol | | water, 1289 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Stability: |
| alcoholic lotion | | antiperspirant | | deo stick | | fabric softener | | hard surface cleaner | | shampoo | | soap |
Organoleptic Properties:
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Odor Type: fruity |
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Odor Strength: | medium , recommend smelling in a 1.00 % solution or less |
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Substantivity: | < 1 hour(s) at 100.00 % |
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| sweet fresh banana fruity jasmin ripe heliotrope balsamic |
Odor Description: at 1.00 % in propylene glycol. | sweet fresh banana fruity jasmin ripe heliotrope balsam Luebke, William tgsc, (2006) |
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Flavor Type: fruity |
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| sweet banana fruity ripe floral green |
Taste Description: at 30.00 ppm in water. | sweet banana fruity ripe floral green Luebke, William tgsc, (2006) |
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Odor and/or flavor descriptions from others (if found). |
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Bedoukian Research |
PRENYL ACETATE ≥98.0%, Kosher |
Odor Description: | A fruity mango odor with apple, pear banana nuances Very useful for artificial Lavandin, Lavender and Bergamot Oils. |
Taste Description: | Fresh, ethereal, sweet Can add freshness to fruit flavors, especially cherry, apple, and raspberry. |
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Symrise |
Prenyl acetate |
Odor Description: | fruity, fresh |
Taste Description: | Fruity, Sweet, Juicy, Pear, Estery Useful in: fruity yellow, fruity tropical, fruity others, alcoholics. |
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IFF |
Prenyl Acetate |
Odor Description: | Fruity floral, not as pungent as amyl acetate but longer lasting. Fresh green nuances |
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Moellhausen |
PRENYL ACETATE |
Odor Description: | natural, fresh, fruity, green apple, banana and pear note, volatile, reminiscent of ylang top |
Taste Description: | natural green apple, banana |
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Pell Wall Perfumes |
Prenyl Acetate |
Odor Description: | Sweet, fresh-bergamot, fruity-banana, lavender, heliotrope Arctander tells us that “this material was made commercially available in 1966 at a time when Lavandin oil was scarce and expensive. Any material that could help improve an artificial Lavandin or Lavender was of immediate interest.
However, this material has found uses far beyond Lavandin, Lavender and Bergamot … If increased use result in volume production, one may justly assume that this material can be produced at a much more attractive price and thus come into entirely new fields of perfumery application.” |
Taste Description: | sweet banana fruity ripe floral green |
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Cosmetic Information:
Suppliers:
Associate Allied Chemicals |
Prenyl Acetate
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About |
Augustus Oils |
Prenyl Acetate
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Services |
Azelis UK |
PRENYL ACETATE
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BASF |
Prenyl Acetate
Odor: Fruity, pear, green, aspects of banana Flavor: Sweet, fruity, floral, pear |
Bedoukian Research |
PRENYL ACETATE
≥98.0%, Kosher Odor: A fruity mango odor with apple, pear banana nuances Use: Very useful for artificial Lavandin, Lavender and Bergamot Oils. Flavor: Fresh, ethereal, sweet Can add freshness to fruit flavors, especially cherry, apple, and raspberry. |
Berjé |
Prenyl Acetate
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Media |
BOC Sciences |
For experimental / research use only. |
PRENYL ACETATE 98.0%
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Charkit Chemical |
PRENYL ACETATE FEMA 4202
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Citrus and Allied Essences |
Prenyl Acetate
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Market Report |
Creatingperfume.com |
PRENYL ACETATE (IFF)
Odor: fruity mango odor with apple, pear banana nuances |
Diffusions Aromatiques |
ACETATE PRENYLE
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Ernesto Ventós |
PRENYL ACETATE IFF
Odor: FRUITY,GREEN APPLE,BANANA |
Ernesto Ventós |
PRENYL ACETATE
Odor: FRUITY,GREEN APPLE,BANANA |
Fine Fragrances Pvt Ltd |
Prenyl Acetate
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Global Essence |
Prenyl Acetate
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Grau Aromatics |
VERTENOL-ACETATE (PRENYL-ACETATE)
NI, Kosher |
IFF |
Prenyl Acetate
Odor: Fruity floral, not as pungent as amyl acetate but longer lasting. Fresh green nuances |
Indukern F&F |
PRENYL ACETATE
Odor: FRUITY, GREEN, PEAR, APPLE |
Inoue Perfumery |
PRENYL ACETATE
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Lluch Essence |
PRENYL ACETATE
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M&U International |
Prenyl Acetate (IFF# : 166416)
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Miltitz Aromatics |
PRENYL ACETATE
min. 97 % Odor: Fresh-fruity, penetrating green, reminiscent of pear, banana, pineapple and exotic fruits Use: PRENYL ACETATE brings a topnote of expressive freshness and liveliness to lavender, fruit and particularly to citrus compositions. If applied in neutral pH-range, this ester will enhance its naturalness and acceptance. Flavor: Strong, fruity, sweet pear-banana like |
Moellhausen |
PRENYL ACETATE
Odor: natural, fresh, fruity, green apple, banana and pear note, volatile, reminiscent of ylang top Flavor: natural green apple, banana |
O'Laughlin Industries |
PRENYL ACETATE
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OQEMA |
Prenyl Acetate
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Pell Wall Perfumes |
Prenyl Acetate
Odor: Sweet, fresh-bergamot, fruity-banana, lavender, heliotrope Use: Arctander tells us that “this material was made commercially available in 1966 at a time when Lavandin oil was scarce and expensive. Any material that could help improve an artificial Lavandin or Lavender was of immediate interest.
However, this material has found uses far beyond Lavandin, Lavender and Bergamot … If increased use result in volume production, one may justly assume that this material can be produced at a much more attractive price and thus come into entirely new fields of perfumery application.” |
Penta International |
PRENYL ACETATE
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R C Treatt & Co Ltd |
Prenyl Acetate
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Reincke & Fichtner |
Prenyl Acetate
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Sensient Flavor and Fragrances |
Prenyl Acetate
Odor: Fruity, green, pear |
Sigma-Aldrich |
Prenyl acetate, ≥98%, FG
Odor: apple; lavender; green |
Certified Food Grade Products |
SRS Aromatics |
PRENYL ACETATE (FG)
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SRS Aromatics |
PRENYL ACETATE
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Symrise |
Prenyl acetate
Odor: fruity, fresh Flavor: Fruity, Sweet, Juicy, Pear, Estery Useful in: fruity yellow, fruity tropical, fruity others, alcoholics. |
Tadimety Aromatics |
Acet Prenyl
Odor: Fruity,Pear, Green |
Taytonn ASCC |
Prenyl Acetate
Odor: Fresh, Fruity, Green |
TCI AMERICA |
For experimental / research use only. |
3-Methyl-2-butenyl Acetate >98.0%(GC)
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The John D. Walsh Company |
Prenyl Acetate
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The Lermond Company |
PRENYL ACETATE
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The Perfumers Apprentice |
Prenyl Acetate (I)
Odor: Fruity, floral, pear. Fresh, green nuances |
Vigon International |
Prenyl Acetate (Methyl-3 2-Butenyl Acetate)
Odor: Fruity, fresh |
ZEON Chemicals |
Prenyl Acetate
Odor: Fresh, fruity, sweet, |
Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | Xi - Irritant |
R 10 - Flammable. R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 16 - Keep away from sources of ignition - No Smoking. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 - Wear suitable gloves and eye/face protection.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
oral-rat LD50 2900 mg/kg GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE
GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS National Technical Information Service. Vol. OTS0571762
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Dermal Toxicity: |
skin-rabbit LD50 > 5000 mg/kg Food and Chemical Toxicology. Vol. 20, Pg. 817, 1982.
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for prenyl acetate usage levels up to: | | 10.0000 % in the fragrance concentrate.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 22.00 (μg/capita/day) |
Maximised Survey-derived Daily Intakes (MSDI-USA): | 160.00 (μg/capita/day) |
Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 2300 (μg/person/day) |
Threshold of Concern: | 1800 (μg/person/day) |
Structure Class: | I |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 22 |
Click here to view publication 22 |
| average usual ppm | average maximum ppm |
baked goods: | 10.00000 | 100.00000 |
beverages(nonalcoholic): | 0.30000 | 3.00000 |
beverages(alcoholic): | 1.50000 | 15.00000 |
breakfast cereal: | 0.30000 | 1.50000 |
cheese: | - | - |
chewing gum: | 15.00000 | 100.00000 |
condiments / relishes: | - | - |
confectionery froastings: | 1.50000 | 10.00000 |
egg products: | 1.50000 | 10.00000 |
fats / oils: | 1.50000 | 10.00000 |
fish products: | - | - |
frozen dairy: | 6.00000 | 60.00000 |
fruit ices: | 3.00000 | 30.00000 |
gelatins / puddings: | 3.00000 | 30.00000 |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | 5.00000 | 50.00000 |
imitation dairy: | - | - |
instant coffee / tea: | 0.60000 | 6.00000 |
jams / jellies: | 3.00000 | 30.00000 |
meat products: | - | - |
milk products: | 0.60000 | 6.00000 |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | 1.50000 | 15.00000 |
snack foods: | - | - |
soft candy: | 3.00000 | 30.00000 |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
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Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). |
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. |
| average usage mg/kg | maximum usage mg/kg |
Dairy products, excluding products of category 02.0 (01.0): | 7.00000 | 35.00000 |
Fats and oils, and fat emulsions (type water-in-oil) (02.0): | 5.00000 | 25.00000 |
Edible ices, including sherbet and sorbet (03.0): | 10.00000 | 50.00000 |
Processed fruit (04.1): | 7.00000 | 35.00000 |
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | - | - |
Confectionery (05.0): | 10.00000 | 50.00000 |
Chewing gum (05.0): | - | - |
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 5.00000 | 25.00000 |
Bakery wares (07.0): | 10.00000 | 50.00000 |
Meat and meat products, including poultry and game (08.0): | 2.00000 | 10.00000 |
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | 2.00000 | 10.00000 |
Eggs and egg products (10.0): | - | - |
Sweeteners, including honey (11.0): | - | - |
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 5.00000 | 25.00000 |
Foodstuffs intended for particular nutritional uses (13.0): | 10.00000 | 50.00000 |
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | - | - |
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 10.00000 | 50.00000 |
Ready-to-eat savouries (15.0): | 20.00000 | 100.00000 |
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | 5.00000 | 25.00000 |
Safety References:
European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 202: 3-Alkylated aliphatic acyclic alpha,beta-unsaturated aldehydes and precursors with or without additional double bonds from chemical subgroup 1.1.3 of FGE.19[1] View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 95 (FGE.95): Consideration of aliphatic, linear or branched-chain saturated and unsaturated alcohols, aldehydes, acids and related esters evaluated by JECFA (69th meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05Rev1 (2008) View page or View pdf |
Safety and efficacy of a,ß-unsaturated straight-chain and branched-chain aliphatic primary alcohols, aldehydes, acids and esters belonging to chemical group 3 when used as flavourings for all animal species View page or View pdf |
EPI System: | View |
AIDS Citations: | Search |
Cancer Citations: | Search |
Toxicology Citations: | Search |
EPA Substance Registry Services (TSCA): | 1191-16-8 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 14489 |
National Institute of Allergy and Infectious Diseases: | Data |
WISER: | UN 1993 |
WGK Germany: | 2 |
| 3-methylbut-2-enyl acetate |
Chemidplus: | 0001191168 |
RTECS: | EM9473700 for cas# 1191-16-8 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| acetic acid 3-methyl-2-butenyl ester | | acetic acid 3-methylbut-2-enyl ester | 2- | buten-1-ol, 3-methyl-, acetate | 3,3- | dimethyl allyl acetate | 3,3- | dimethylallyl acetate | 3- | methyl-2-buten-1-ol acetate | 3- | methyl-2-buten-1-ol, acetate | 3- | methyl-2-buten-1-yl acetate | 3- | methyl-2-butenyl acetate | 3- | methylbut-2-en-1-yl acetate | 3- | methylbut-2-ene-1-ol acetate | 3- | methylbut-2-enyl acetate | 3- | methylbut-2-enyl ethanoate | iso | pent-2-enyl acetate | | prenylacetate | | vertenol acetate (Grau) | | vertenol-acetate (Grau) |
Articles:
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