Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless to pale yellow clear liquid (est) |
Assay: | 96.00 to 100.00 %
|
Food Chemicals Codex Listed: | Yes |
Specific Gravity: | 1.03000 to 1.03500 @ 25.00 °C.
|
Pounds per Gallon - (est).: | 8.571 to 8.612
|
Refractive Index: | 1.45700 to 1.46300 @ 20.00 °C.
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Boiling Point: | 196.00 to 197.00 °C. @ 760.00 mm Hg
|
Boiling Point: | 100.00 °C. @ 30.00 mm Hg
|
Acid Value: | 1.00 max. KOH/g
|
Vapor Pressure: | 0.324000 mmHg @ 25.00 °C. (est) |
Vapor Density: | 5.1 ( Air = 1 ) |
Flash Point: | 174.00 °F. TCC ( 78.89 °C. )
|
logP (o/w): | 1.352 (est) |
Shelf Life: | 24.00 month(s) or longer if stored properly. |
Storage: | store in cool, dry place in tightly sealed containers, protected from heat and light. |
Soluble in: |
| alcohol | | water, 4534 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Similar Items: note |
isoamyl 3-methyl thiopropionate |
methyl-3-methyl thiopropionate |
Organoleptic Properties:
|
Odor Type: sulfurous |
|
| sulfurous metallic pineapple fruity ripe pulpy tomato |
Odor Description: at 0.10 % in propylene glycol. | sulfury metallic pineapple fruity ripe pulpy tomato |
|
| sulfurous metallic pineapple fruity ripe pulpy tomato |
Odor Description:
| Sulfureous, metallic, pineapple, fruity ripe, pulpy and tomato Mosciano, Gerard P&F 19, No. 1, 27, (1994) |
|
|
Flavor Type: sulfurous |
|
| sulfurous onion garlic pineapple rummy vegetable |
Taste Description: at 30.00 ppm. | Sulfureous, onion garlic, pineapple, rumy, vegetative Mosciano, Gerard P&F 19, No. 1, 27, (1994) |
|
Odor and/or flavor descriptions from others (if found). |
|
R C Treatt & Co Ltd |
Ethyl-3-methylthio Propionate Halal, Kosher |
Odor Description: | fruity, cooked pineapple |
Taste Description: | fruity Used in bakery and soft confection at 2ppm, and desserts and beverages at 1ppm. |
|
Indukern F&F |
ETHYL 3-METHYLTHIOPROPIONATE |
Odor Description: | SULFUROUS, METALIC, FRUITY, PINEAPPLE |
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Cosmetic Information:
Suppliers:
Advanced Biotech |
ETHYL (3-METHYLTHIO) PROPIONATE
|
Ambles Nature et Chimie |
ETHYL 3-METHYLTHIO PROPIONATE
|
Anhui Haibei |
Ethyl 3-methylthio Propionate
Odor: Sulfury metallic pineapple fruity ripe pulpy tomato |
Axxence Aromatic |
ETHYL 3-(METHYLTHIO)-PROPIONATE Natural
Kosher |
Sustainability |
Beijing Lys Chemicals |
Ethyl 3-(methylthio)propionate
|
Berjé |
Ethyl-3-Methyl Thio Propionate
|
Media |
BOC Sciences |
For experimental / research use only. |
Ethyl 3-methylthiopropionate
|
Charkit Chemical |
ETHYL 3-METHYLTHIOPROPIONATE FEMA 3343
|
Charkit Chemical |
ETHYL 3-METHYLTHIOPROPIONATE NATURAL FEMA 3343
|
Citrus and Allied Essences |
Ethyl 3-Methyl Thiopropionate FCC
|
Market Report |
DeLong Chemicals America |
Ethyl 3-methylthiopropionate, Kosher
|
Endeavour Specialty Chemicals |
Ethyl 3-(methylthio)propionate 98% F&F
|
Speciality Chemical Product Groups |
Ernesto Ventós |
ETHYL 3-METHYLTHIOPROPIONATE
Odor: FRUITY,VEGETABLE,SWEET,ALLIACEOUS |
Excellentia International |
Ethyl-3-Methyl Thio Propionate Natural
|
FCI SAS |
ETHYL-3-METHYLTHIO PROPIONATE
Odor: Pineapple and tomato |
Frutarom |
ETHYL 3-METHYLTHIOPROPIONATE
KOSHER Flavor: Sulfurous, Metallic, Pineapple, Fruity, Ripe, Tomato |
CBD Offering |
IFF |
ETHYL 3-METHYLTHIOPROPIONATE
KOSHER Flavor: Sulfurous, Metallic, Pineapple, Fruity, Ripe, Tomato |
Indukern F&F |
ETHYL 3-METHYLTHIOPROPIONATE
Odor: SULFUROUS, METALIC, FRUITY, PINEAPPLE |
Jiangyin Healthway |
Ethyl 3-methylthio propionate
|
New functional food ingredients |
Jinan Enlighten Chemical Technology(Wutong Aroma ) |
Ethyl 3-methylthio propionate, Kosherk
|
K.L. Koh Enterprise |
ETHYL 3-METHYLTHIOPROPIONATE
|
Kingchem Laboratories |
ETHYL 3-METHYLTHIOPROPIONATE
Odor: Pineapple |
Lluch Essence |
ETHYL 3-METHYL THIOPROPIONATE NATURAL
|
Lluch Essence |
ETHYL 3-METHYL THIOPROPIONATE
Odor: GARLIC LIKE, SULPHUROUS |
M&U International |
ETHYL-3-METHYLTHIO PROPIONATE, Kosher
|
Moellhausen |
ETHYL 3-METHYLTHIOPROPIONATE
|
Natural Advantage |
Ethyl Methylthiopropionate Nat, 1% in Triacetin Nat USOC
Flavor: blueberry, caramellic, cheesy, fruity, grape, red, metallic, sulphurous |
Riverside Aromatics LTD.is the exclusive distributor for Europe in UK for any non-US based inquiries |
Natural Advantage |
Ethyl Methylthiopropionate Nat, 1% in Triacetin
Flavor: blueberry, caramellic, cheesy, fruity, grape, red, metallic, sulphurous |
Natural Advantage |
Ethyl Methylthiopropionate Nat, Neat
Flavor: blueberry, caramellic, cheesy, fruity, grape, red, metallic, sulphurous |
Penta International |
ETHYL-3-METHYLTHIOPROPIONATE NATURAL
|
Penta International |
ETHYL-3-METHYLTHIOPROPIONATE
|
R C Treatt & Co Ltd |
Ethyl-3-methylthio Propionate
Halal, Kosher Odor: fruity, cooked pineapple Flavor: fruity Used in bakery and soft confection at 2ppm, and desserts and beverages at 1ppm. |
Reincke & Fichtner |
Ethyl-3-methylthiopropionate
|
Riverside Aromatics |
ETHYL 3-METHYLTHIOPROPIONATE NATURAL
|
Robinson Brothers |
Ethyl 3-(methylthio)propionate F&F
|
https://www.robinsonbrothers.uk/chemistry-competences |
Santa Cruz Biotechnology |
For experimental / research use only. |
Ethyl 3-(methylthio)propionate
|
Sigma-Aldrich |
Ethyl 3-(methylthio)propionate, ≥99%, FCC, FG
Odor: citrus; pineapple |
Certified Food Grade Products |
Sunaux International |
Ethyl-3-methylthio Propionate
|
Synerzine |
ETHYL 3-(METHYLTHIO)PROPIONATE
|
Synerzine |
Ethyl Methyl Mercaptopropionate (natural)
|
Synerzine |
Ethyl Methyl Mercaptopropionate (synthetic)
|
Taytonn ASCC |
Ethyl 3-Methylthiopropionate
Odor: Fruity, Tropical |
TCI AMERICA |
For experimental / research use only. |
Ethyl 3-(Methylthio)propionate >98.0%(GC)
|
Tengzhou Jitian Aroma Chemiclal |
Ethyl-3-methylthio propionate
|
Tengzhou Xiang Yuan Aroma Chemicals |
Ethyl Methyl Thio-3-Propionate
|
Tianjin Danjun International |
Ethyl 3-(methylthio)propionate
|
United International |
Ethyl 3-methylthiopropionate
|
WholeChem |
Ethyl 3-methylthio propionate
|
Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | Xi - Irritant |
R 36/37/38 - Irritating to eyes, respiratory system, and skin. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
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Hazards identification |
|
Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
|
Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
gavage-rat LD50 [sex: M,F] > 5000 mg/kg (Panasevich et al., 1980)
|
Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
|
Safety in Use Information:
Category: | flavor and fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for ethyl methyl mercaptopropionate usage levels up to: | | 0.0500 % in the fragrance concentrate.
|
|
Maximised Survey-derived Daily Intakes (MSDI-EU): | 24.00 (μg/capita/day) |
Structure Class: | I |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 6 |
Click here to view publication 6 |
| average usual ppm | average maximum ppm |
baked goods: | - | 2.00000 |
beverages(nonalcoholic): | - | 1.00000 |
beverages(alcoholic): | - | - |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | - | - |
condiments / relishes: | - | - |
confectionery froastings: | - | - |
egg products: | - | - |
fats / oils: | - | - |
fish products: | - | - |
frozen dairy: | - | 1.00000 |
fruit ices: | - | 1.00000 |
gelatins / puddings: | - | 1.00000 |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | - | 2.00000 |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | 1.00000 |
meat products: | - | - |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | - | - |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
Safety References:
European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 8 (FGE.08)[1]: Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical group 20 View page or View pdf |
Flavouring Group Evaluation 8, Revision 1 (FGE.08Rev1): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 8, Revision 3 (FGE.08Rev3): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 08, Revision 4 (FGE.08Rev4): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
EPI System: | View |
AIDS Citations: | Search |
Cancer Citations: | Search |
Toxicology Citations: | Search |
EPA Substance Registry Services (TSCA): | 13327-56-5 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 61592 |
National Institute of Allergy and Infectious Diseases: | Data |
WGK Germany: | 3 |
| ethyl 3-methylsulfanylpropanoate |
Chemidplus: | 0013327565 |
References:
Other Information:
Potential Blenders and core components note
|
For Odor |
alliaceous |
| dibutyl sulfide | FL/FR |
1,3- | dithiane | |
| methyl furfuryl disulfide | FL/FR |
berry |
| raspberry ketone | FL/FR |
| heptanoic acid | FL/FR |
iso | valeric acid | FL/FR |
chemical |
| propyl propionate | FL/FR |
ethereal |
| propyl valerate | FL/FR |
fatty |
| allyl decanoate | FL/FR |
| allyl octanoate | FL/FR |
| methyl 2-hexenoate | FL/FR |
fermented |
| ethyl (E)-2-crotonate | FL/FR |
floral |
| geranyl valerate | FL/FR |
| phenethyl isovalerate | FL/FR |
fruity |
| allyl 3,5,5-trimethyl hexanoate | FL/FR |
| allyl cinnamate | FL/FR |
| allyl cyclohexyl acetate | FL/FR |
| allyl cyclohexyl butyrate | FL/FR |
| allyl heptanoate | FL/FR |
| allyl propionate | FL/FR |
iso | amyl isovalerate | FL/FR |
| amyl propionate | FL/FR |
iso | amyl propionate | FL/FR |
| amyl valerate | FL/FR |
iso | amyl valerate | FL/FR |
| ananas comosus extract | |
| apricot fragrance | FR |
| benzyl ethyl ether | FL/FR |
iso | butyl (E)-2-butenoate | |
iso | butyl butyrate | FL/FR |
iso | butyl hexanoate | FL/FR |
| butyl valerate | FL/FR |
| dihydroactinidolide | FL/FR |
| ethyl 3-(2-furyl) propanoate | FL/FR |
| ethyl 3-hexenoate | FL/FR |
| ethyl 3-methyl valerate | FL/FR |
| ethyl 5-hydroxyoctanoate | FL/FR |
| ethyl butyrate | FL/FR |
| ethyl cyclohexane propionate | FL/FR |
| ethyl heptanoate | FL/FR |
| ethyl hexanoate | FL/FR |
| ethyl-2-cyclopentenyl acetate | FR |
| fruity carboxylate | FR |
| methyl hexanoate | FL/FR |
| methyl isovalerate | FL/FR |
| passiflora lauriflora fruit extract | CS |
| pineapple hydroxyhexanoate | FL/FR |
| prenyl acetate | FL/FR |
iso | propyl butyrate | FL/FR |
| propyl heptanoate | FL/FR |
iso | propyl hexanoate | FL/FR |
iso | propyl isobutyrate | FL/FR |
| propyl isobutyrate | FL/FR |
| prune specialty | FL/FR |
green |
| cognac heptanone | FL/FR |
| galbanum oxyacetate | FR |
(E)-2- | hexen-1-yl butyrate | FL/FR |
3- | hexenyl 2-methyl butyrate | FL/FR |
| hexyl isobutyrate | FL/FR |
| pineapple heptadienone 10% | FR |
| spirogalbanone (Givaudan) | FR |
herbal |
| herbal undecanone | FR |
nutty |
2- | methyl-3-ethoxypyrazine | FL/FR |
spicy |
| ethyl vinyl ketone | FL/FR |
1,3- | dithiolane | |
| ethyl 2-mercaptopropionate | FL/FR |
2- | methyl 5-(methyl thio) furan | FL/FR |
3-( | methyl thio) hexanol | FL/FR |
4- | methyl-1,3-dithiane | |
| passiflora acetate | FL/FR |
tropical |
| passiflora edulis fruit extract | FL/FR |
| passiflora edulis fruit water | FL/FR |
| pina colada fragrance | FR |
| tropical 3-thiobutyrate | FL/FR |
waxy |
| ethyl octanoate | FL/FR |
|
For Flavor |
|
No flavor group found for these |
| allyl 3,5,5-trimethyl hexanoate | FL/FR |
| allyl cinnamate | FL/FR |
| allyl cyclohexyl butyrate | FL/FR |
| allyl cyclohexyl valerate | FL |
| amyl propionate | FL/FR |
| amyl valerate | FL/FR |
| ananas comosus extract | |
| benzyl ethyl ether | FL/FR |
9- | decen-2-one | FL |
| ethyl 3-methyl valerate | FL/FR |
| ethyl 5-hydroxyoctanoate | FL/FR |
| ethyl cyclohexane propionate | FL/FR |
| ethyl cyclohexyl carboxylate | FL |
| geranyl valerate | FL/FR |
| methyl 2-hexenoate | FL/FR |
2- | methyl-3-ethoxypyrazine | FL/FR |
iso | propyl hexanoate | FL/FR |
iso | propyl isobutyrate | FL/FR |
| propyl valerate | FL/FR |
| prune specialty | FL/FR |
alliaceous |
| allyl disulfide | FL |
| allyl propionate | FL/FR |
| allyl thiopropionate | FL |
| chive flavor | FL |
| cyclopentyl mercaptan | FL |
| diethyl disulfide | FL |
3- | mercapto-2-pentanone | FL |
2- | methyl thioacetaldehyde | FL |
3- | tetrahydrothiophenone | FL |
| truffle sulfide | FL |
berry |
| raspberry ketone | FL/FR |
buttery |
| butter onion garlic flavor | FL |
cheesy |
iso | valeric acid | FL/FR |
citrus |
| cognac heptanone | FL/FR |
coffee |
| methyl furfuryl disulfide | FL/FR |
fatty |
| allyl octanoate | FL/FR |
fermented |
| methyl thio isovalerate | FL |
fruity |
| allyl cyclohexyl acetate | FL/FR |
| allyl decanoate | FL/FR |
| allyl heptanoate | FL/FR |
iso | amyl propionate | FL/FR |
iso | amyl valerate | FL/FR |
iso | butyl butyrate | FL/FR |
iso | butyl hexanoate | FL/FR |
| butyl valerate | FL/FR |
| dihydroactinidolide | FL/FR |
| ethyl 3-(2-furyl) propanoate | FL/FR |
| ethyl 3-hexenoate | FL/FR |
| ethyl butyrate | FL/FR |
| ethyl heptanoate | FL/FR |
| ethyl hexanoate | FL/FR |
| furfuryl isovalerate | FL |
| methionyl butyrate | FL |
| methyl hexanoate | FL/FR |
| methyl isovalerate | FL/FR |
( | methyl thio) methyl hexanoate | FL |
| phenethyl isovalerate | FL/FR |
| pineapple hydroxyhexanoate | FL/FR |
| prenyl acetate | FL/FR |
iso | propyl butyrate | FL/FR |
| propyl isobutyrate | FL/FR |
green |
iso | amyl isovalerate | FL/FR |
| dibutyl sulfide | FL/FR |
(E)-2- | hexen-1-yl butyrate | FL/FR |
3- | hexenyl 2-methyl butyrate | FL/FR |
| hexyl isobutyrate | FL/FR |
meaty |
(R,S)-2- | mercapto-3-butanol | FL |
bis(2- | methyl-3-furyl) disulfide | FL |
ortho- | thiocresol | FL |
metallic |
3-( | methyl thio) hexanol | FL/FR |
musty |
| ethyl (E)-2-crotonate | FL/FR |
2- | methyl 5-(methyl thio) furan | FL/FR |
onion |
1,3- | dithiane | |
| ethyl 2-mercaptopropionate | FL/FR |
| methionol | FL |
| methyl propyl disulfide | FL |
| methyl propyl trisulfide | FL |
| onion flavor | FL |
| propyl thioacetate | FL |
seafood |
1,4- | dithiane | FL |
spicy |
| ethyl vinyl ketone | FL/FR |
sulfurous |
| allyl sulfide | FL |
| butyl mercaptan | FL |
1,3- | dithiolane | |
S- | ethyl thioacetate | FL |
| furfuryl thiopropionate | FL |
3- | mercapto-2-methyl pentanal | FL |
3- | mercapto-2-methyl-1-butanol | FL |
4- | methyl-1,3-dithiane | |
caramelized | onion oleoresin | FL |
| tropical 3-thiobutyrate | FL/FR |
tropical |
| passiflora acetate | FL/FR |
| passiflora edulis fruit extract | FL/FR |
| passiflora edulis fruit water | FL/FR |
| propyl propionate | FL/FR |
waxy |
iso | butyl (E)-2-butenoate | |
| ethyl octanoate | FL/FR |
| heptanoic acid | FL/FR |
| propyl heptanoate | FL/FR |
|
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| ethyl (3-methylthio) propionate | | ethyl (3-methylthio) propionate natural | | ethyl 3-(methyl thio) propanoate | | ethyl 3-(methyl thio) propionate | | ethyl 3-(methylmercapto)propionate | | ethyl 3-(methylsulfanyl)propanoate | | ethyl 3-(methylthio propionate | | ethyl 3-(methylthio)-propionate | | ethyl 3-(methylthio)propanoate | | ethyl 3-(methylthio)propionate | | ethyl 3-methyl mercaptopropionate | | ethyl 3-methyl thiopropionate | | ethyl 3-methyl thiopropionate FCC | | ethyl 3-methylsulfanylpropanoate | | ethyl 3-methylthio propionate | | ethyl 3-methylthiopropionate | | ethyl beta-methyl thiopropionate | | ethyl methylthioproprionate natural | | ethyl-3-(methyl thio) propionate | | ethyl-3-(methylthio)-propionate natural | | ethyl-3-methyl thio propionate | | ethyl-3-methyl thiopropionate | | ethyl-3-methylthio propionate | | ethyl-3-methylthiopropionate | | ethyl-3-metylthiopropionate, natural | 3-( | methyl thio) propionic acid ethyl ester | 3- | methyl thiopropionic acid ethyl ester | 3-( | methylthio)propanoic acid ethyl ester | (3- | methylthio)propionic acid ethyl ester | 3-( | methylthio)propionic acid ethyl ester | 3-( | methylthio)propionic acid ethylester | | pineapple thiopropionate | | propanoic acid, 3-(methylthio)-, ethyl ester | | propionic acid, 3-methylthio-, ethyl ester |
Articles:
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