Category: food contact acrylic and modified acrylic plastics
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless liquid (est) |
Assay: | 97.00 to 100.00 %
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Food Chemicals Codex Listed: | Yes |
Specific Gravity: | 0.91600 to 0.91900 @ 25.00 °C.
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Pounds per Gallon - (est).: | 7.622 to 7.647
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Refractive Index: | 1.40300 to 1.40700 @ 20.00 °C.
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Melting Point: | -75.00 to -71.00 °C. @ 760.00 mm Hg
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Boiling Point: | 99.00 to 100.00 °C. @ 760.00 mm Hg
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Acid Value: | 5.00 max. KOH/g
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Vapor Pressure: | 38.181999 mmHg @ 25.00 °C. (est) |
Vapor Density: | 3.5 ( Air = 1 ) |
Flash Point: | 60.00 °F. TCC ( 15.56 °C. )
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logP (o/w): | 1.320 |
Soluble in: |
| alcohol | | water, 8717 mg/L @ 25 °C (est) | | water, 1.50E+04 mg/L @ 25 °C (exp) |
Insoluble in: |
| water |
Organoleptic Properties:
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Odor Type: plastic |
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Odor Strength: | high , recommend smelling in a 0.10 % solution or less |
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Substantivity: | 4 hour(s) at 100.00 % |
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| plastic acrylate fruity |
Odor Description: at 1.00 % in dipropylene glycol. | harsh plastic acrylate fruity Luebke, William tgsc, (1988) |
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Odor and/or flavor descriptions from others (if found). |
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Cosmetic Information:
Suppliers:
Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | Xn - Harmful. |
R 11 - Highly flammable. R 20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 - Irritating to eyes, respiratory system, and skin. R 43 - May cause sensitisation by skin contact. S 09 - Keep container in a well-ventilated place. S 16 - Keep away from sources of ignition - No Smoking. S 33 - Take precautionary measures against static discharge. S 36/37 - Wear suitable protective clothing and gloves.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Human Experience: |
4 % solution: no irritation or sensitization. |
Oral/Parenteral Toxicity: |
oral-rat LD50 800 mg/kg Bromatologia i Chemia Toksykologiczna. Vol. 12, Pg. 405, 1979.
intraperitoneal-rat LD50 450 mg/kg Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 36, Pg. 58, 1975.
oral-rabbit LD50 370 mg/kg GASTROINTESTINAL: ALTERATION IN GASTRIC SECRETION National Technical Information Service. Vol. OTS0521003
oral-mouse LD50 1799 mg/kg Toxicology Letters. Vol. 11, Pg. 125, 1982.
intraperitoneal-mouse LD50 599 mg/kg Journal of Dental Research. Vol. 51, Pg. 526, 1972.
oral-cat LD > 800 uL/kg GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
GASTROINTESTINAL: NAUSEA OR VOMITING National Technical Information Service. Vol. OTS0521003
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Dermal Toxicity: |
skin-rabbit LD50 500 ul/kg LIVER: OTHER CHANGES
SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE"
LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA National Technical Information Service. Vol. OTS0520180
skin-mouse LD50 2997 mg/kg National Technical Information Service. Vol. OTS0520999
skin-rat LDLo 1800 mg/kg Polish Journal of Pharmacology and Pharmacy. Vol. 32, Pg. 223, 1980.
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Inhalation Toxicity: |
inhalation-rat LC50 1414 ppm/4H GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION National Technical Information Service. Vol. OTS0520180
inhalation-mouse LC50 16200 mg/m3 Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 23(9), Pg. 55, 1979.
inhalation-guinea pig LCLo 1204 ppm/7H LUNGS, THORAX, OR RESPIRATION: COUGH
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 317, 1949.
inhalation-human TCLo 50 ppm LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION
SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 75, 1969.
inhalation-rabbit TCLo 1204 ppm/7H GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
BEHAVIORAL: ATAXIA
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 317, 1949.
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Safety in Use Information:
Category: | food contact acrylic and modified acrylic plastics |
IFRA Critical Effect: | Dermal sensitization |
IFRA: | View Standard |
Recommendation for ethyl acrylate usage levels up to: | | PROHIBITED: Should not be used as a fragrance ingredient.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 1.30 (μg/capita/day) |
Maximised Survey-derived Daily Intakes (MSDI-USA): | 0.70 (μg/capita/day) |
Threshold of Concern: | 1800 (μg/person/day) |
Structure Class: | I |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 3 |
Click here to view publication 3 |
| average usual ppm | average maximum ppm |
baked goods: | - | 1.10000 |
beverages(nonalcoholic): | 0.13000 | 0.26000 |
beverages(alcoholic): | - | - |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | 0.10000 | 0.10000 |
condiments / relishes: | - | - |
confectionery froastings: | - | - |
egg products: | - | - |
fats / oils: | - | - |
fish products: | - | - |
frozen dairy: | 0.06000 | 1.00000 |
fruit ices: | 0.06000 | 1.00000 |
gelatins / puddings: | - | - |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | - | 1.10000 |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | - |
meat products: | - | - |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | - | - |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
Safety References:
European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Scientific Opinion on Flavouring Group Evaluation 71: Consideration of aliphatic, linear, alpha,beta-unsaturated carboxylic acids and related esters View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 95 (FGE.95): Consideration of aliphatic, linear or branched-chain saturated and unsaturated alcohols, aldehydes, acids and related esters evaluated by JECFA (69th meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05Rev1 (2008) View page or View pdf |
Scientific Opinion on the safety of neutral methacrylate copolymer for the proposed uses as a food additive View page or View pdf |
Scientific Opinion on the safety and efficacy of straight-chain primary aliphatic alcohols/aldehydes/acids, acetals and esters with esters containing saturated alcohols and acetals containing saturated aldehydes (chemical group 1) when used as flavourings for all animal species View page or View pdf |
Scientific Opinion on the safety assessment of the substances (butadiene, ethyl acrylate, methyl methacrylate, styrene) copolymer either not crosslinked or crosslinked with divinylbenzene or 1,3-butanediol dimethacrylate, in nanoform, for use in food contact materials View page or View pdf |
Safety of ethyl acrylate to be used as flavouring View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 71 Revision 1 (FGE.71Rev1): consideration of aliphatic, linear, a,ß-unsaturated alcohols, aldehydes, carboxylic acids, and related esters evaluated by JECFA (63rd and 69th meeting) structurally related to flavouring substances evaluated in FGE.05Rev3 View page or View pdf |
EPI System: | View |
NIOSH International Chemical Safety Cards: | search |
NIOSH Pocket Guide: | search |
Chemical Carcinogenesis Research Information System: | Search |
AIDS Citations: | Search |
Cancer Citations: | Search |
Toxicology Citations: | Search |
Carcinogenic Potency Database: | Search |
EPA GENetic TOXicology: | Search |
EPA Substance Registry Services (TSCA): | 140-88-5 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 8821 |
National Institute of Allergy and Infectious Diseases: | Data |
SCCNFP: | opinion |
WISER: | UN 1917 |
WGK Germany: | 2 |
| ethyl prop-2-enoate |
Chemidplus: | 0000140885 |
EPA/NOAA CAMEO: | hazardous materials |
RTECS: | 140-88-5 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| acrylic acid ethyl ester | | acrylic acid, ethyl ester | | ethoxycarbonyl ethylene | | ethyl 2-propenoate | | ethyl acrylate 1% in ethyl propionate natural | | ethyl acrylate 1% in PG natural | | ethyl acrylate natural | | ethyl acrylic ester | | ethyl ester of acrylic acid | | ethyl prop-2-enoate | | ethyl propenoate | 2- | propenoic acid ethyl ester | 2- | propenoic acid, ethyl ester |
Articles:
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