Category: fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | yellow liquid to solid (est) |
Assay: | 98.00 to 100.00 %
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 1.03590 to 1.04210 @ 25.00 °C.
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Pounds per Gallon - (est).: | 8.620 to 8.671
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Refractive Index: | 1.53560 to 1.54290 @ 20.00 °C.
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Boiling Point: | 471.82 °C. @ 760.00 mm Hg (est)
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Vapor Pressure: | 0.001300 mmHg @ 20.00 °C. |
Flash Point: | > 212.00 °F. TCC ( > 100.00 °C. )
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logP (o/w): | 7.660 (est) |
Soluble in: |
| alcohol | | water, 0.02806 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Stability: |
| beauty care | | fine fragrance | | household | | laundry care |
Organoleptic Properties:
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Odor Type: floral |
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Odor Strength: | medium , recommend smelling in a 50.00 % solution or less |
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Substantivity: | 400 hour(s) at 100.00 % |
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| fresh green orangeflower lily citrus muguet |
Odor Description: at 50.00 % in dipropylene glycol. | fresh green orangeflower lily citrus hydroxycitronellal Luebke, William tgsc, (1986) |
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Odor and/or flavor descriptions from others (if found). |
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Bedoukian Research |
SCHIFF'S BASE LILIAL-METHYL ANTHRANILATE ≥90.0% (sum of isomers), Kosher |
Odor Description: | neroli, orange blossom A very high quality product with subtle floral notes to enhance delicate fragrances. |
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Givaudan |
Verdantiol |
Odor Description: | Linden-Orange Flower Verdantiol offers an intense floral note to delicate flower type creations, such as neroli, orange blossom, narcissus and frangipani. Excellent fixative value on all supports. |
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Moellhausen |
VERDANTIOL |
Odor Description: | fresh floral, sweet aromatic, citrusy; notes of muguet and neroli |
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Robertet |
Schiff lilial |
Odor Description: | Floral, orange flower, lily of the valley |
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Cosmetic Information:
Suppliers:
Apple Flavor & Fragrance |
Lilial/MA schiffbase
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Augustus Oils |
Lilial – Ma Schiff Base
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Services |
BOC Sciences |
For experimental / research use only. |
Benzoic acid,2-[[3-[4-(1,1-dimethylethyl)phenyl]-2-methylpropylidene]amino]-, methyl ester
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Charabot |
Schiff lilial
Odor: Floral, orange flower, lily of the valley |
CJ Latta & Associates |
SCHIFF BASE HIGH PURITY
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Ernesto Ventós |
SCHIFF BASE EXTRA, LILIAL
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Ernesto Ventós |
SCHIFF BASE, LILIAL
Odor: FLORAL, DRY |
Fleurchem |
lilial / methyl anthranilate schiff's base
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Givaudan |
Verdantiol
Odor: Linden-Orange Flower Use: Verdantiol offers an intense floral note to delicate flower type creations, such as neroli, orange blossom, narcissus and frangipani. Excellent fixative value on all supports. |
Grau Aromatics |
LILANATE 3275 P (LILIALMETHYLANTHRANILATE)
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IFF |
Lilianth
Odor: Fresh green orangeflower, lily, citrus, hydroxycitronellal like note |
Indukern F&F |
SCHIFF BASE LILIAL
Odor: FLORAL, DRY |
Inoue Perfumery |
LILYANTINE
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Keva |
VERANIOL L.S
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Lluch Essence |
SCHIFF BASE LILIAL/METHYL ANTHRANILATE
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Moellhausen |
VERDANTIOL
Odor: fresh floral, sweet aromatic, citrusy; notes of muguet and neroli |
Penta International |
METHYL ANTHRANILATE/LILIAL
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PerfumersWorld |
Verdantiol
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Robertet |
Schiff lilial
Odor: Floral, orange flower, lily of the valley |
Seasons and Harvest / Crop calendar |
SRS Aromatics |
LILANATE 3275 P
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U. K. Aromatics and Chemicals |
LILIANTINE
Odor: Fresh, green, neroli, Orange flower, lily Citrusy |
Vigon International |
Methyl Anthranilate / Lilial Schiff Base
Odor: Linden-Orange Flower |
Safety Information:
European information : |
Most important hazard(s): | Xi - Irritant |
R 38 - Irritating to skin. R 43 - May cause sensitisation by skin contact. S 02 - Keep out of the reach of children. S 24 - Avoid contact with skin. S 37 - Wear suitable gloves.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Human Experience: |
12% in petrolatum produced no irritation or sensitization in humans. |
Oral/Parenteral Toxicity: |
oral-rat LD50 3000 mg/kg Food and Chemical Toxicology. Vol. 20, Pg. 729, 1982.
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Dermal Toxicity: |
skin-rabbit LD50 > 5000 mg/kg Food and Chemical Toxicology. Vol. 20, Pg. 729, 1982.
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
IFRA Critical Effect: | Sensitization |
IFRA fragrance material specification: | | The IFRA Scientific Committee examined the physicochemical properties of Schiff bases and concluded that, based on the available information, these materials should be considered under contributions from other sources. By default, the stoichiometric presence of the aldehydes of the Schiff bases is taken into account assuming 100% dissociation. An indicative list of Schiff bases incorporating aldehydes covered by an IFRA Standard of restriction is reported at page 2. These Schiff bases must be taken into account for determination of the maximum use level of the respective aldehydes. |
Recommendation for lilyall / methyl anthranilate schiff's base usage levels up to: | | 5.0000 % in the fragrance concentrate.
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Recommendation for lilyall / methyl anthranilate schiff's base flavor usage levels up to: |
| not for flavor use.
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Safety References:
References:
| methyl 2-[[3-(4-tert-butylphenyl)-2-methylpropylidene]amino]benzoate |
NIST Chemistry WebBook: | Search Inchi |
Canada Domestic Sub. List: | 91-51-0 |
Pubchem (cid): | 64807 |
Pubchem (sid): | 135021438 |
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| anthranilic acid, N-(3-(p-tert-butylphenyl)-2-methylpropylidene)-, methyl ester | | benzoic acid, 2-((3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropylidene)amino)-, methyl ester | p-tert- | butyl-alpha-methyl hydrocinnamal / methyl anthranilate schiff base | para-tert- | butyl-alpha-methyl hydrocinnamal / methyl anthranilate schiff base | | lilanate 3275 P (Grau) | | lilial/ma schiffbase | | lilianth (IFF) | | liliavert (A.C.S. International) | | lilyall / methyl anthranilate schiff's base | | lilyantine | | maranthra | | methyl 2-((3-(4-(1,1-dimethyl ethyl)phenyl)-2-methyl propylidene)amino) benzoate | | methyl 2-((3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropylidene)amino)benzoate | | methyl 2-[[3-(4-tert-butylphenyl)-2-methylpropylidene]amino]benzoate | | methyl anthranilate / lilial | | methyl anthranilate / lilyall schiff's base | | methyl-N-(p-tert-butyl-a-methylhydrocinnamylidene) anthranilate | | methyl-N-(p-tert-butyl-alpha-methylhydrocinnamylidene) anthranilate | | methyl-N-(para-tert-butyl-alpha-methyl hydrocinnamylidene) anthranilate | | schiff base lilial | | schiff's base lilial-methyl anthranilate | | schiff's base lilianthral | | verdantiol (Givaudan) |
Articles:
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