Category: fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | pale yellow clear liquid (est) |
Assay: | 90.00 to 100.00 % sum of isomers
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 0.96000 to 0.96900 @ 25.00 °C.
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Pounds per Gallon - (est).: | 7.988 to 8.063
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Specific Gravity: | 0.96100 to 0.97000 @ 20.00 °C.
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Pounds per Gallon - est.: | 8.006 to 8.081
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Refractive Index: | 1.46200 to 1.46700 @ 20.00 °C.
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Boiling Point: | 225.75 °C. @ 760.00 mm Hg (est)
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Vapor Pressure: | 0.085000 mmHg @ 25.00 °C. (est) |
Flash Point: | 185.00 °F. TCC ( 85.00 °C. )
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logP (o/w): | 3.480 |
Shelf Life: | 36.00 month(s) or longer if stored properly. |
Storage: | store in cool, dry place in tightly sealed containers, protected from heat and light. |
Soluble in: |
| alcohol | | water, 25.89 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Stability: |
| alcoholic lotion | | antiperspirant | | deo stick | | detergent | | fabric softener | | hard surface cleaner | | shampoo | | soap |
Organoleptic Properties:
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Odor Type: citrus |
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Odor Strength: | medium |
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Substantivity: | 24 hour(s) at 100.00 % |
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| citrus floral green grapefruit gardenia petal |
Odor Description: at 100.00 %. | citrus floral green grapefruit gardenia petal Luebke, William tgsc, (1988) |
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Odor and/or flavor descriptions from others (if found). |
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IFF |
Citrolate™ |
Odor Description: | Citrus, grapefruit note also reminiscent of the dry notes of bitter orange oil and melon. Useful in colognes as a freshener to overcome the candy-sweet notes of orange and lemon oil |
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Lluch Essence |
JAFFARAL |
Odor Description: | GRAPEFRUIT, RHUBARB , GREEN |
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Perfumery Laboratory |
CITROLATE ™ IFF (CITROLATE ™ IFF) |
Odor Description: | Fresh, citrus fragrance with notes of grapefruit, melon and bitter orange |
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Tadimety Aromatics |
Agrumenyl Acetate |
Odor Description: | Citrus, Neroli, Grape Fruit |
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Cosmetic Information:
Suppliers:
Augustus Oils |
Floralate
|
Services |
Azelis UK |
Citrolate™
|
Ernesto Ventós |
FLORALATE IFF
Odor: CITRUS, FRUITY, GRAPEFRUIT, DRY |
Global Essence |
Jaffaral
|
IFF |
Citrolate™
Odor: Citrus, grapefruit note also reminiscent of the dry notes of bitter orange oil and melon. Useful in colognes as a freshener to overcome the candy-sweet notes of orange and lemon oil |
Kun Shan P&A |
Floralate
|
Lluch Essence |
JAFFARAL
Odor: GRAPEFRUIT, RHUBARB , GREEN |
M&U International |
Citrolate (Floralate)
|
Penta International |
2,4-DIMETHYL-3-CYCLOHEXENE-1-METHANYL ACETATE
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Perfumery Laboratory |
CITROLATE ™ IFF (CITROLATE ™ IFF)
Odor: Fresh, citrus fragrance with notes of grapefruit, melon and bitter orange |
Tadimety Aromatics |
Agrumenyl Acetate
Odor: Citrus, Neroli, Grape Fruit |
Taytonn ASCC |
Floralate
|
The John D. Walsh Company |
Floralate
|
Tianjin Danjun International |
(3,5-Dimethyl-1-cyclohex-3-enyl)methyl acetat
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Safety Information:
European information : |
Most important hazard(s): | Xi - Irritant |
R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
Not determined
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for 2,4-dimethyl-3-cyclohexene-1-methanyl acetate usage levels up to: | | 5.0000 % in the fragrance concentrate.
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Recommendation for 2,4-dimethyl-3-cyclohexene-1-methanyl acetate flavor usage levels up to: |
| not for flavor use.
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Safety References:
References:
Other Information:
Potential Blenders and core components note
|
For Odor |
No odor group found for these |
2- | ethyl-N-methyl-N-(3-methyl phenyl) butyramide | FR |
aldehydic |
iso | butyraldehyde | FL/FR |
| decanal (aldehyde C-10) | FL/FR |
6,7,8- | decen-1-ol | FR |
| dodecanal (aldehyde C-12 lauric) | FL/FR |
(Z)-4- | dodecenal | FL/FR |
| mandarine undecenal | FL/FR |
3- | methyl-4-hexyl oxybutyraldehyde | FR |
| nonanal (aldehyde C-9) | FL/FR |
| TMH aldehyde | FR |
| tridecanal | FL/FR |
balsamic |
| abies alba cone oil | FR |
| cinnamyl formate | FL/FR |
citronella |
4,8- | dimethyl-7-nonen-2-ol | FR |
citrus |
| acetaldehyde citronellyl methyl acetal | FR |
| benzyl anthranilate | FR |
| bergamot oil | FL/FR |
| bergamot oil bergaptene reduced italy | FL/FR |
| bergamot oil turkey | FL/FR |
beta- | bisabolol | FL/FR |
| citral diethyl acetal | FL/FR |
| citral dimethyl acetal | FL/FR |
| citrus floral green fragrance | FR |
| citrus ocimenol | FR |
| citrus specialty | FR |
| dihydromyrcenol | FL/FR |
| dimethyl octenone | FR |
| dodecane nitrile | FR |
2- | dodecanone | FL/FR |
citrus | floral fragrance | FR |
| grapefruit indene | FR |
| grapefruit mercaptan | FL/FR |
| grapefruit nitrile | FR |
| grapefruit oil c.p. (citrus paradisi var. red blush) | |
| grapefruit oil c.p. california | FL/FR |
| grapefruit oil CO2 extract (citrus paradisi macf. var. falvedo) | FL/FR |
| grapefruit oil terpeneless | FL/FR |
| grapefruit pentanol | FR |
| lime octadienal | FR |
| lime oil distilled mexico | FL/FR |
| mandarin oil | FL/FR |
| mandarin oil italy | FL/FR |
3- | methyl-4-(2-methyl butyl oxy) butyraldehyde | FR |
| myrmac aldehyde | FR |
| nonanal dimethyl acetal | FL/FR |
(+)- | nootkatone | FL/FR |
sweet | orange peel oil c.p. brazil | FL/FR |
sweet | orange peel oil terpeneless | FL/FR |
| rhubafuran | FR |
alpha- | terpinyl methyl ether | FL/FR |
(E)-2- | tetradecenal | FL/FR |
2- | tetradecenal | FL/FR |
(±)-2,4,8- | trimethyl-7-nonen-2-ol | FL/FR |
| valencene | FL/FR |
| verbena fragrance | FR |
ethereal |
| ethyl acetate | FL/FR |
fatty |
2- | decenal | FL/FR |
(Z)-3- | octen-1-ol | FL/FR |
floral |
| acetaldehyde dibutyl acetal | FL/FR |
| amyl benzoate | FL/FR |
| amyl salicylate | FL/FR |
| anisyl propanal / methyl anthranilate schiff's base | FR |
| bois de rose oil brazil | FL/FR |
| boronia concrete | FL/FR |
alpha- | butyl cinnamaldehyde | FL/FR |
| cassis oxime 10% | FR |
| citronellyl acetate | FL/FR |
| citronellyl propionate | FL/FR |
| coriander seed oil CO2 extract | FL/FR |
| cumin carbinol | FR |
| dictamnus hispanicus oil | FR |
| dihydrocarvyl acetate | FL/FR |
(±)-2,3- | dihydrofarnesol | FL/FR |
| dihydroisojasmonate methyl ester | FR |
| dimethyl benzyl carbinol | FL/FR |
| dimethyl benzyl carbinyl butyrate | FL/FR |
6,8- | dimethyl-2-nonanol | FR |
2,4- | dimethyl-3-cyclohexene-1-methanol | FR |
| ethyl phenoxyacetate | FR |
| farnesol | FL/FR |
| farnesyl acetate | FL/FR |
| floral butanal | FR |
| floral undecenone | FR |
| gardenia absolute | FR |
| gardenia acetal | FR |
| gardenia amide | FR |
| gardenia concrete | FR |
| gardenia decalone | FR |
| gardenia pentyl acetate | FR |
| geranium oil | FL/FR |
| geranium oil africa | FL/FR |
| geranyl acetone | FL/FR |
| geranyl formate | FL/FR |
(Z)-4- | hepten-2-yl salicylate | FR |
(Z)-3- | hexen-1-yl salicylate | FL/FR |
alpha- | hexyl cinnamaldehyde | FL/FR |
| hexyl lactate | FL/FR |
| hyacinth oil | FR |
| hydrangea fragrance | FR |
| hydroxycitronellal diethyl acetal | FL/FR |
| hydroxycitronellal propylene glycol acetal | FL/FR |
| jasmin cyclopentanol | FR |
| jonquil absolute | FR |
| lilac absolute | FR |
| lily fragrance | FR |
| lily propanol | FR |
| linalool | FL/FR |
| linalyl phenyl acetate | FL/FR |
| lotus fragrance | FR |
| magnolia indene | FR |
(2- | methoxy-1-methyl propyl) benzene | FR |
(3- | methoxy-2-methyl propyl) benzene | FR |
| methoxycitronellal | FR |
1-(2- | methyl allyl oxy)-2-methyl butane | FR |
| mimosa absolute | FL/FR |
| mimosa absolute france | FL/FR |
| mimosa absolute india | FL/FR |
| muguet dienal | FR |
| muguet nitrile | FR |
| nerol | FL/FR |
| neroli oil CO2 extract | FL/FR |
| neroli oil tunisia | FL/FR |
| nerolidol | FL/FR |
(E)- | nerolidol | FL/FR |
| nerolidyl acetate | FL/FR |
| neryl acetate | FL/FR |
| neryl isovalerate | FL/FR |
| ocean propanal | FL/FR |
| ocean propanal / methyl anthranilate schiff's base | FR |
| orange leaf absolute | FL/FR |
bitter | orangeflower absolute tunisia | FL/FR |
| orchid specialty | FR |
| palmarosa oil | FL/FR |
| papaya isobutyrate | FL/FR |
| peony acetonitrile | FR |
| petitgrain concrete | FR |
| petitgrain lemon oil | FL/FR |
| petitgrain oil morocco | FL/FR |
| phenyl acetaldehyde dicitronellyl acetal | FR |
| phenyl acetaldehyde diisobutyl acetal | FL/FR |
2- | phenyl propionaldehyde ethylene glycol acetal | FR |
| rhodinyl formate | FL/FR |
| rose butanoate | FL/FR |
laevo- | rose oxide | FL/FR |
(Z)- | rose oxide | FL/FR |
| rose pyran | FR |
| styralyl formate | FL/FR |
| sweet pea absolute | FR |
| terpinyl formate | FL/FR |
| terpinyl isobutyrate | FL/FR |
| tetrahydrolinalyl acetate | FR |
5- | tricyclodecenyl acetate | FR |
(E)-2,5,9- | trimethyl-4,9-decadien-1-al | FR |
| undecanal dimethyl acetal | FR |
| verdyl acetate | FR |
| violet methyl carbonate | FR |
| ylang ylang flower oil III | FL/FR |
fresh |
3-(3- | propen-2-yl phenyl) butanal | FR |
fruity |
| benzyl methyl ether | FL/FR |
iso | butyl methyl anthranilate | FL/FR |
| citronellyl isobutyrate | FL/FR |
| cyclohexyl crotonate | FR |
| diethyl sebacate | FL/FR |
| dimethyl succinate | FL/FR |
| ethyl 3-hydroxyhexanoate | FL/FR |
| ethyl isobutyrate | FL/FR |
| ethyl methyl-para-tolyl glycidate | FL/FR |
| grape butyrate | FL/FR |
| grapefruit acetal | FR |
| heptanal cyclic ethylene acetal | FR |
| peach pivalate | FR |
| solanone | FL/FR |
| tropical ionone | FL/FR |
2- | undecenal | FL/FR |
(E)-2- | undecenal | FL/FR |
fungal |
| jasmin nonane | FR |
green |
iso | amyl 3-(2-furan) propionate | FL/FR |
iso | butyl benzyl carbinol | FL/FR |
| chrysanthemum oxide | FL/FR |
| citrus carbaldehyde / methyl anthranilate schiff's base | FR |
3,7- | dimethyl-6-octenoic acid | FL/FR |
| earthy acetal | FL/FR |
| flower hexene | FR |
| green carboxylate | FR |
| green cyclopropionate | FR |
(Z)-3- | hexen-1-yl acetoacetate | FL/FR |
(Z)-3- | hexen-1-yl angelate | FR |
| hexen-1-yl oxypropane nitrile | FR |
(Z)-3- | hexen-1-yl pyruvate | FL/FR |
| hexyl (Z)-tiglate | FL/FR |
| hyacinth absolute | FL/FR |
| ivy dioxolane | FR |
| melon acetal | FL/FR |
| melon nonenoate | FL/FR |
(2- | methoxy-1-methyl butyl) benzene | FR |
[(4E,4Z)-5- | methoxy-3-methyl-4-penten-1-yl] benzene | FR |
| methyl cyclocitrone (IFF) | FR |
para- | methyl hydratropaldehyde | FL/FR |
| methyl octine carbonate | FL/FR |
4- | methyl-4-phenyl pentanone | FR |
(Z)-5- | octen-1-ol | FL/FR |
| octyl oxyacetaldehyde | FR |
| pelargonium graveolens stem leaf extract | FR |
| phenyl acetaldehyde solution | FL/FR |
herbal |
6- | acetoxydihydrotheaspirane | FL/FR |
| chrysanthemum ketone | FR |
| clary sage absolute | FL/FR |
| coriander oleoresin | FL/FR |
| dihexyl (E)-fumarate | FR |
| linalyl acetate | FL/FR |
2- | methyl butyl salicylate | FL/FR |
(1S,5R)- | myrtenyl acetate | FL/FR |
3- | octyl acetate | FL/FR |
| phenyl acetaldehyde diisoamyl acetal | FR |
alpha- | terpinyl acetate | FL/FR |
medicinal |
| kunzea ericoides leaf oil | FR |
(Z)-6- | nonen-1-yl acetate | FL/FR |
(Z)-6- | nonenal | FL/FR |
spicy |
| cinnamyl propionate | FL/FR |
iso | cyclogeraniol (IFF) | FR |
| spicy carbonate | FR |
sulfurous |
| grapefruit menthane | FL/FR |
tea |
| camellia oleifera leaf extract | FL/FR |
terpenic |
(E,E)-2,6-allo | ocimene | FL/FR |
waxy |
| decanal dimethyl acetal | FL/FR |
3- | decanone | FL/FR |
1- | undecanol | FL/FR |
|
For Flavor |
|
No flavor group found for these |
| acetaldehyde dibutyl acetal | FL/FR |
6- | acetoxydihydrotheaspirane | FL/FR |
| amyl benzoate | FL/FR |
| boronia concrete | FL/FR |
iso | butyl methyl anthranilate | FL/FR |
beta- | cubebene | FL |
| decanal dimethyl acetal | FL/FR |
3- | decanone | FL/FR |
| dihydronootkatone | FL |
(Z)-4- | dodecenal | FL/FR |
| earthy acetal | FL/FR |
| grapefruit oil c.p. (citrus paradisi var. red blush) | |
(Z)-3- | hexen-1-yl acetoacetate | FL/FR |
| hexyl (Z)-tiglate | FL/FR |
| hyacinth absolute | FL/FR |
| hydroxycitronellal propylene glycol acetal | FL/FR |
| linalyl phenyl acetate | FL/FR |
4- | mercapto-4-methyl-2-pentanol | FL |
2- | methyl butyl salicylate | FL/FR |
| nerolidyl acetate | FL/FR |
(E,E)-2,6-allo | ocimene | FL/FR |
| phenyl acetaldehyde solution | FL/FR |
| solanone | FL/FR |
| styralyl formate | FL/FR |
| terpinyl isobutyrate | FL/FR |
2- | tetradecenal | FL/FR |
|
iso | amyl 3-(2-furan) propionate | FL/FR |
alpha- | butyl cinnamaldehyde | FL/FR |
aldehydic |
iso | butyraldehyde | FL/FR |
| nonanal (aldehyde C-9) | FL/FR |
1- | undecanol | FL/FR |
amber |
iso | butyl benzyl carbinol | FL/FR |
aromatic |
| amyl salicylate | FL/FR |
citrus |
| bergamot oil | FL/FR |
| bergamot oil bergaptene reduced italy | FL/FR |
| bergamot oil turkey | FL/FR |
beta- | bisabolol | FL/FR |
| citral diethyl acetal | FL/FR |
| citral dimethyl acetal | FL/FR |
| dehydronootkatone | FL |
| grapefruit mercaptan | FL/FR |
| grapefruit oil c.p. california | FL/FR |
| grapefruit oil CO2 extract (citrus paradisi macf. var. falvedo) | FL/FR |
| grapefruit oil terpeneless | FL/FR |
| lime oil distilled mexico | FL/FR |
| linalool | FL/FR |
| mandarin oil | FL/FR |
| mandarin oil italy | FL/FR |
| nerol | FL/FR |
| neroli oil tunisia | FL/FR |
(+)- | nootkatone | FL/FR |
sweet | orange peel oil c.p. brazil | FL/FR |
sweet | orange peel oil terpeneless | FL/FR |
| petitgrain lemon oil | FL/FR |
| petitgrain oil morocco | FL/FR |
(±)-2,4,8- | trimethyl-7-nonen-2-ol | FL/FR |
| valencene | FL/FR |
ethereal |
| ethyl acetate | FL/FR |
| ethyl isobutyrate | FL/FR |
fatty |
2- | decenal | FL/FR |
(E,E)-2,4- | dodecadienal | FL |
2- | dodecanone | FL/FR |
(Z)-3- | octen-1-ol | FL/FR |
floral |
| bois de rose oil brazil | FL/FR |
| cinnamyl propionate | FL/FR |
| citronellyl acetate | FL/FR |
| citronellyl propionate | FL/FR |
| dihydrocarvyl acetate | FL/FR |
(±)-2,3- | dihydrofarnesol | FL/FR |
| dimethyl benzyl carbinyl butyrate | FL/FR |
3,7- | dimethyl-6-octenoic acid | FL/FR |
| farnesol | FL/FR |
| farnesyl acetate | FL/FR |
| geranium oil | FL/FR |
| geranium oil africa | FL/FR |
| geranyl acetone | FL/FR |
| linalyl acetate | FL/FR |
| neroli oil CO2 extract | FL/FR |
| neryl acetate | FL/FR |
| ocean propanal | FL/FR |
| orange leaf absolute | FL/FR |
bitter | orangeflower absolute tunisia | FL/FR |
laevo- | rose oxide | FL/FR |
| tropical ionone | FL/FR |
| ylang ylang flower oil III | FL/FR |
fruity |
| benzyl methyl ether | FL/FR |
| citronellyl isobutyrate | FL/FR |
| diethyl sebacate | FL/FR |
| dimethyl succinate | FL/FR |
| ethyl 3-hydroxyhexanoate | FL/FR |
| ethyl methyl-para-tolyl glycidate | FL/FR |
| hexyl lactate | FL/FR |
| neryl isovalerate | FL/FR |
| rhodinyl formate | FL/FR |
| rose butanoate | FL/FR |
| terpinyl formate | FL/FR |
grassy |
| palmarosa oil | FL/FR |
green |
| chrysanthemum oxide | FL/FR |
| dihydromyrcenol | FL/FR |
| geranyl formate | FL/FR |
| grape butyrate | FL/FR |
(Z)-3- | hexen-1-yl pyruvate | FL/FR |
(Z)-3- | hexen-1-yl salicylate | FL/FR |
| melon acetal | FL/FR |
| melon nonenoate | FL/FR |
para- | methyl hydratropaldehyde | FL/FR |
| methyl octine carbonate | FL/FR |
(E)- | nerolidol | FL/FR |
| nerolidol | FL/FR |
| nonanal dimethyl acetal | FL/FR |
(Z)-6- | nonen-1-yl acetate | FL/FR |
(Z)-6- | nonenal | FL/FR |
(Z)-5- | octen-1-ol | FL/FR |
3- | octyl acetate | FL/FR |
| papaya isobutyrate | FL/FR |
| phenyl acetaldehyde diisobutyl acetal | FL/FR |
(Z)- | rose oxide | FL/FR |
herbal |
| clary sage absolute | FL/FR |
| coriander oleoresin | FL/FR |
| coriander seed oil CO2 extract | FL/FR |
medicinal |
| dimethyl benzyl carbinol | FL/FR |
melon |
| hydroxycitronellal diethyl acetal | FL/FR |
soapy |
| dodecanal (aldehyde C-12 lauric) | FL/FR |
spicy |
| cinnamyl formate | FL/FR |
sulfurous |
| grapefruit menthane | FL/FR |
1- | methyl thio-2-propanone | FL |
tea |
| camellia oleifera leaf extract | FL/FR |
waxy |
| decanal (aldehyde C-10) | FL/FR |
alpha- | hexyl cinnamaldehyde | FL/FR |
| mandarine undecenal | FL/FR |
| mimosa absolute | FL/FR |
| mimosa absolute france | FL/FR |
| mimosa absolute india | FL/FR |
(E)-2- | tetradecenal | FL/FR |
| tridecanal | FL/FR |
(E)-2- | undecenal | FL/FR |
2- | undecenal | FL/FR |
woody |
(1S,5R)- | myrtenyl acetate | FL/FR |
alpha- | terpinyl acetate | FL/FR |
alpha- | terpinyl methyl ether | FL/FR |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| agrumenyl acetate (Tadimety) | | citrolate (IFF) | 3- | cyclohexene-1-methanol, 3,5-dimethyl-, acetate | 3,5- | dimethyl cyclohex-3-ene-1-methyl acetate | (3,5- | dimethyl-1-cyclohex-3-enyl)methyl acetate | 2,4- | dimethyl-3-cyclohexene-1-methanyl acetate | 3,5- | dimethyl-3-cyclohexene-1-methyl acetate | 3,5- | dimethylcyclohex-3-ene-1-methyl acetate | | floralate | | jaffaral |
Articles:
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