Category: fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | pale yellow clear liquid to crystals (est) |
Assay: | 45.00 to 55.00 %
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 1.01400 to 1.01800 @ 20.00 °C.
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Pounds per Gallon - (est).: | 8.447 to 8.481
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Refractive Index: | 1.47100 to 1.47500 @ 20.00 °C.
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Boiling Point: | 267.95 °C. @ 760.00 mm Hg (est)
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Acid Value: | 0.50 max. KOH/g
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Vapor Pressure: | 0.001000 mmHg @ 25.00 °C. (est) |
Flash Point: | > 212.00 °F. TCC ( > 100.00 °C. )
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logP (o/w): | 4.489 (est) |
Soluble in: |
| alcohol | | water, 11.14 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Stability: |
| aerosols | | antiperspirant | | cream | | deodorants | | deodorants | | detergent | | fabric softener | | soap | | spray cologne |
Organoleptic Properties:
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Odor Type: amber |
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Odor Strength: | medium |
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Substantivity: | 208 hour(s) at 100.00 % |
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| warm woody amber animal sage clary sage dry |
Odor Description: at 100.00 %. | warm woody amber animal clary dry Luebke, William tgsc, (1988) |
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Odor and/or flavor descriptions from others (if found). |
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Cosmetic Information:
Suppliers:
Safety Information:
European information : |
Most important hazard(s): | Xi - Irritant |
R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
Not determined
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
maximum skin levels for fine fragrances: | | 0.2600 % and are based on the assumption that the fragrance mixture is used at 20% in a consumer product (IFRA Use Level Survey). (IFRA, 2006)
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Recommendation for hydroxymethyl isolongifolene 50% in dpg usage levels up to: | | 10.0000 % in the fragrance concentrate.
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use level in formulae for use in cosmetics: | | 2.7200 %
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Dermal Systemic Exposure in Cosmetic Products: | | 0.0693 mg/kg/day (IFRA, 2006)
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Recommendation for hydroxymethyl isolongifolene 50% in dpg flavor usage levels up to: |
| not for flavor use.
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Safety References:
References:
| octahydro-7,7,8,8-tetramethyl-2,3b-methano-3bH-cyclopenta(1,3)cyclopropa(1,2)benzene-4-methanol |
NIST Chemistry WebBook: | Search Inchi |
Canada Domestic Sub. List: | 59056-64-3 |
Pubchem (cid): | 100939 |
Pubchem (sid): | 135059879 |
Other Information:
Potential Blenders and core components note
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For Odor |
No odor group found for these |
| satinaldehyde | FL/FR |
amber |
(Z)- | abienol | FL/FR |
| acetoxymethyl isolongifolene | FR |
| amber acetate | FR |
| amber butanol | FR |
| amber carane | FR |
| amber cyclohexanol | FR |
| amber furan | FR |
| amber naphthofuran | FL/FR |
| amber oxepin | FR |
| amber specialty | FR |
| ambermax 50 (Givaudan) | FR |
| ambroxan | FL/FR |
| ambroxide | FL/FR |
| formoxymethyl isolongifolene | FR |
| labdanum absolute | FL/FR |
animal |
| ambergris tincture replacer | FR |
| animal carbolactone | FR |
2- | methyl-4-(camphenyl-8) cyclohexanone | FR |
balsamic |
| fir carboxylate | FR |
| mastic gum resin | FR |
| methyl hydrogenated rosinate | FR |
| opoponax absolute (commiphora erythraea var. glabrescens engle) | FL/FR |
| opoponax resin (commiphora erythraea var. glabrescens engler) | FL/FR |
| opoponax resinoid (commiphora erythraea var. glabrescens engle) | FR |
| opoponax resinoid replacer | FR |
| oriental specialty | FR |
| sclareol | FL/FR |
| styrax oil (liquidambar styraciflua) | FL/FR |
| styrax resin (liquidambar styraciflua) | FL/FR |
| styrax resinoid (liquidambar styraciflua) | FL/FR |
dusty |
| woody furan | FR |
floral |
| boronia butenal | FR |
| orris pyridine 25% IPM | FR |
| petitgrain oil paraguay | FL/FR |
fruity |
| balsam specialty | FR |
green |
| magnolia flower oil | FL/FR |
herbal |
| bergamot mint herb oil | FR |
(+)-alpha- | campholenic aldehyde | FL/FR |
| clary acetate | FR |
| clary propyl acetate | FR |
| clary sage resin america | FR |
| costmary oil (chrysanthemum balsamita) | FR |
| herbal carene | FR |
| ocimene oxirane | FR |
| romanal | FR |
| salvia sclarea oil | FL/FR |
mossy |
| moss specialty | FR |
musk |
homo | ambrinol | FR |
| ethylene dodecanoate | FR |
| juniper lactone | FL/FR |
| musk amberol | FR |
| musk lactone | FR |
| musk methyl ketone | FR |
oily |
| mcp acetate | FR |
powdery |
| midnight passion fragrance | FR |
spicy |
| angelica seed absolute | FL/FR |
terpenic |
| angelica seed oil | FL/FR |
woody |
| acetyl cedrene | FR |
| amber carbinol | FR |
| amber dioxane | FR |
| amber formate | FR |
| amber pentadecane | FR |
| ambrene acetal | FR |
| cedarwood oil texas fractions | FR |
alpha- | cedrene epoxide | FR |
| cedrol methyl ether | FR |
| cedryl formate | FR |
| cedryl methyl ether | FR |
| dihydro-beta-ionone | FL/FR |
| dragons blood fragrance | FR |
| frankincense resinoid replacer | FR |
| georgywood | FR |
| hydroxyambran | FR |
iso | longifolene ketone | FR |
2- | methoxy-4-vinyl phenol | FL/FR |
(4aR,5R,7aS,9R)- | octahydro-2,2,5,8,8,9a-hexamethyl-4h-4a,9-methanoazuleno(5,6-d)-1,3-dioxole | FR |
| patchouli woody amber fragrance | FR |
| sclareolide | FL/FR |
| tetramethyl-4-methylene-2-heptanol | FR |
| tobacarol (IFF) | FR |
| vetiver specialty | FR |
| woody cyclohexanone | FR |
| woody dioxolane | FR |
| woody nonane (ethoxy) | FR |
| woody propanol | FR |
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For Flavor |
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No flavor group found for these |
| ambroxide | FL/FR |
| magnolia flower oil | FL/FR |
amber |
| amber naphthofuran | FL/FR |
| angelica seed oil | FL/FR |
| labdanum absolute | FL/FR |
balsamic |
| opoponax absolute (commiphora erythraea var. glabrescens engle) | FL/FR |
| opoponax resin (commiphora erythraea var. glabrescens engler) | FL/FR |
| styrax oil (liquidambar styraciflua) | FL/FR |
| styrax resin (liquidambar styraciflua) | FL/FR |
| styrax resinoid (liquidambar styraciflua) | FL/FR |
floral |
| satinaldehyde | FL/FR |
green |
(+)-alpha- | campholenic aldehyde | FL/FR |
| petitgrain oil paraguay | FL/FR |
| salvia sclarea oil | FL/FR |
musk |
| juniper lactone | FL/FR |
smoky |
2- | methoxy-4-vinyl phenol | FL/FR |
spicy |
| angelica seed absolute | FL/FR |
woody |
(Z)- | abienol | FL/FR |
| ambroxan | FL/FR |
| dihydro-beta-ionone | FL/FR |
| sclareol | FL/FR |
| sclareolide | FL/FR |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| amborol 50 | | hydroxymethyl isolongifolene 50% in dipropylene glycol | | hydroxymethyl isolongifolene 50% in dpg | 2,3b- | methano-3bH-cyclopenta(1,3)cyclopropa(1,2)benzene-4-methanol, octahydro-7,7,8,8-tetramethyl- | | octahydro-7,7,8,8-tetramethyl-2,3b-methano-3bh-cyclopenta(1,3)cyclopropa(1,2)benzene-4-methanol | | octahydro-7,7,8,8-tetramethyl-2,3b-methano-3bH-cyclopenta(1,3)cyclopropa(1,2)benzene-4-methanol | | octahydro-7,7,8,8-tetramethyl-2,3b-methano-3bH-cyclopenta[1,3]cyclopropa[1,2]benzene-4-methanol | | octahydrotetramethyl methanocyclopentacyclopropabenzene-4-methanol |
Articles:
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