Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | yellow viscous liquid (est) |
Assay: | 97.00 to 100.00 %
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 1.02160 to 1.02730 @ 25.00 °C.
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Pounds per Gallon - (est).: | 8.501 to 8.548
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Refractive Index: | 1.50360 to 1.51090 @ 20.00 °C.
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Boiling Point: | 162.00 °C. @ 101.00 mm Hg
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Vapor Pressure: | 0.004000 mmHg @ 20.00 °C. |
Flash Point: | 201.00 °F. TCC ( 93.89 °C. )
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logP (o/w): | 5.417 (est) |
Shelf Life: | 24.00 month(s) or longer if stored properly. |
Soluble in: |
| alcohol | | water, 3.603 mg/L @ 25 °C (est) |
Insoluble in: |
| paraffin oil |
Organoleptic Properties:
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Odor Type: floral |
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Odor Strength: | medium , recommend smelling in a 50.00 % solution or less |
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Substantivity: | 400 hour(s) at 100.00 % |
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| floral lily orangeflower sweet |
Odor Description: at 50.00 % in dipropylene glycol. | floral lily orange blossom sweet Luebke, William tgsc, (1983) |
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Odor and/or flavor descriptions from others (if found). |
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Givaudan |
Aurantiol® Pure |
Odor Description: | Floral, Orange flower, Linden-Blossom Aurantiol is perhaps the best known Schiff base and is extensively used in a large variety of floral notes such as orange-blossom, linden-blossom and tuberose. Used in citrus cologne types, it acts as an excellent fixative as well as exalting the top notes. It gives an oriental character when used in amber an chypre compositions and blends particularly well with macrocyclic musks. |
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IFF |
Auralva |
Odor Description: | Neroli, orange, muguet and grape facets |
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Moellhausen |
AURANTIOL |
Odor Description: | neroli orange, muguet, grape character; sweet heavy, floral, orange-blossom type |
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PerfumersWorld |
Aurantiol Schiffs base MA Hydroxy |
Odor Description: | neroli orange muguet grape sweet heavy floral orange-blossom |
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Pell Wall Perfumes |
Aurantiol |
Odor Description: | Sweet, floral-orange-blossom, linden-blossom, neroli and lily, amber Aurantiol is perhaps the best-known Schiff’s base (hydroxycitronellal / methyl anthranilate); extensively used in a large variety of floral notes such as orange-blossom, linden-blossom and tuberose. Used in citrus cologne types, it acts as an excellent fixative as well as exalting the top notes. It gives an oriental character when used in amber and chypre compositions and blends particularly well with macrocyclic musks. |
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Prodasynth |
AURANTIOL (> 95%) |
Odor Description: | FLORAL,NEROLI,LINDEN,MANDARIN |
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Robertet |
Schiff hydroxy |
Odor Description: | Floral, orange flower, powerful, warm |
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Cosmetic Information:
Suppliers:
Apple Flavor & Fragrance |
Aurantion
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Associate Allied Chemicals |
Floxyl
|
About |
Augustus Oils |
Aurantiol
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Services |
Azelis UK |
Auralva BHT
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Berjé |
Aurantiol BJ
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Media |
BOC Sciences |
For experimental / research use only. |
Methyl 2-[(7-hydroxy-3,7-dimethyloctylidene)amino]benzoate
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Charabot |
Schiff hydroxy
Odor: Floral, orange flower, powerful, warm |
Creatingperfume.com |
Aurantia (Aurantiol)
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Ernesto Ventós |
AURANTIA 75% (ARGEOL SUBSTITUTE)
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Ernesto Ventós |
AURANTIA
Odor: FLORAL,NEROLI,LINDEN,MANDARIN |
Fleurchem |
hydroxycitronellal / methyl anthranilate schiff's base
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Fuzhou Farwell |
Aurantiol
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Givaudan |
Aurantiol® Pure
Odor: Floral, Orange flower, Linden-Blossom Use: Aurantiol is perhaps the best known Schiff base and is extensively used in a large variety of floral notes such as orange-blossom, linden-blossom and tuberose. Used in citrus cologne types, it acts as an excellent fixative as well as exalting the top notes. It gives an oriental character when used in amber an chypre compositions and blends particularly well with macrocyclic musks. |
IFF |
Auralva
Odor: Neroli, orange, muguet and grape facets |
Indukern F&F |
AURANTIOL
Odor: ORANGEFLOWER, LINDEN BLOSSOM, SWEET |
Inoue Perfumery |
AURANTINE
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K.L. Koh Enterprise |
AURANTIOL
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Lluch Essence |
AURANTIOL BHT
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Lluch Essence |
AURANTIOL
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M&U International |
Auralva
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Moellhausen |
AURANTIOL
Odor: neroli orange, muguet, grape character; sweet heavy, floral, orange-blossom type |
Pell Wall Perfumes |
Aurantiol
Odor: Sweet, floral-orange-blossom, linden-blossom, neroli and lily, amber Use: Aurantiol is perhaps the best-known Schiff’s base (hydroxycitronellal / methyl anthranilate); extensively used in a large variety of floral notes such as orange-blossom, linden-blossom and tuberose. Used in citrus cologne types, it acts as an excellent fixative as well as exalting the top notes. It gives an oriental character when used in amber and chypre compositions and blends particularly well with macrocyclic musks. |
Penta International |
AURANTIOL
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Penta International |
METHYL ANTHRANILATE/ HYDROXY CITRONELLAL
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Perfumer Supply House |
Aurantia (Aurantiol) aka Hydroxycitronellal/Methyl Anth Schiffs Base
Odor: heavy floral, orange blossom, sweet fruity aroma |
PerfumersWorld |
Aurantiol 50% in DPG Schiffs base MA Hydroxy
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PerfumersWorld |
Aurantiol Schiffs base MA Hydroxy
Odor: neroli orange muguet grape sweet heavy floral orange-blossom |
Perfumery Laboratory |
AURANTIOL (Aurantiol Schiffs base MA Hydroxycitronellal)
Odor: Heavy floral, orange blossom, sweet fruity |
Pfaltz & Bauer |
For experimental / research use only. |
Aurantiol
|
Prodasynth |
AURANTIOL
(> 95%) Odor: FLORAL,NEROLI,LINDEN,MANDARIN |
R C Treatt & Co Ltd |
Aurantiol
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Reincke & Fichtner |
Schiff Base, Hydroxycitronellal/methyl Anthranilate
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Robertet |
Schiff hydroxy
Odor: Floral, orange flower, powerful, warm |
Seasons and Harvest / Crop calendar |
SRS Aromatics |
HYDROXYCITRONELLYLIDENE METHYL ANTHRANILATE
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Taytonn ASCC |
Aurantine
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The John D. Walsh Company |
Auralva
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The Lermond Company |
AURALVA
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The Perfumers Apprentice |
Aurantiol Pure
Odor: very sweet heavy floral orange blossom to linden flowers |
U. K. Aromatics and Chemicals |
AURANTINE SUPER
Odor: floral,orange,blossom,linden blossom,neroli orange Flavor: Green, fruity |
Ungerer & Company |
Aurantiol Pure
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Vigon International |
Aurantiol Pure
Odor: FLORAL, ORANGE-BLOSSOM, LINDEN-BLOSSOM |
Vigon International |
Methyl Anthranilate / Hydroxycitronellal Schiff Base
Odor: Floral, Orange flower, Linden-Blossom |
Safety Information:
European information : |
Most important hazard(s): | None - None found. |
S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
Skin irritation (Category 2), H315 Eye irritation (Category 2A), H319 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Chronic aquatic toxicity (Category 2), H411
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GHS Label elements, including precautionary statements |
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Pictogram | |
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Signal word | Warning |
Hazard statement(s) |
H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H411 - Toxic to aquatic life with long lasting effects
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Precautionary statement(s) |
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash skin thouroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P302 + P352 - IF ON SKIN: wash with plenty of soap and water. P304 + P340 - IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P332 + P313 - IF SKIN irritation occurs: Get medical advice/attention. P337 + P313 - IF eye irritation persists: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P391 - Collect spillage. Hazardous to the aquatic environment P403 + P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/ container to an approved waste disposal plant.
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Oral/Parenteral Toxicity: |
oral-rat LD50 > 5000 mg/kg Dispose of contents/ container to an approved waste disposal plant.
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Dermal Toxicity: |
skin-rabbit LD50 > 10000 mg/kg Dispose of contents/ container to an approved waste disposal plant.
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
IFRA Critical Effect: | Sensitization |
IFRA fragrance material specification: | | The IFRA Scientific Committee examined the physicochemical properties of Schiff bases and concluded that, based on the available information, these materials should be considered under contributions from other sources. By default, the stoichiometric presence of the aldehydes of the Schiff bases is taken into account assuming 100% dissociation. An indicative list of Schiff bases incorporating aldehydes covered by an IFRA Standard of restriction is reported at page 2. These Schiff bases must be taken into account for determination of the maximum use level of the respective aldehydes. |
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only) |
hydroxycitronellal | Max. Found: 56.4 % and Reason: Sensitization |
Recommendation for hydroxycitronellal / methyl anthranilate schiff's base usage levels up to: | | 8.0000 % in the fragrance concentrate.
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Recommendation for hydroxycitronellal / methyl anthranilate schiff's base flavor usage levels up to: |
| not for flavor use.
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Safety References:
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| anthranilic acid N-(7-hydroxy-3,7-dimethyl octylidene) methyl ester | | anthranilic acid, N-(7-hydroxy-3,7-dimethyloctylidene)-, methyl ester | | auralva (IFF) | | aurantesin | | aurantha | | aurantia | | aurantine | | aurantiol (Givaudan) | | aurantiol BJ | | aurantiol pure | | aurantion (Quest) | | aurantium | | benzoic acid, 2-((7-hydroxy-3,7-dimethyloctylidene)amino)-, methyl ester | | benzoic acid, 2-[ (7-hydroxy-3, 7-dimethyloctylidene)amino]-, methyl ester | N-(7- | hydroxy-3, 7-dimethyloctylidene)anthranilic acid methyl ester | | hydroxycitronellylidene methyl anthranilate | | methyl 2-((7-hydroxy-3,7-dimethyl octylidene)amino) benzoate | | methyl 2-((7-hydroxy-3,7-dimethyl octylidene)amino)-1-benzene carboxylate | | methyl 2-((7-hydroxy-3,7-dimethyloctylidene)amino)benzoate | | methyl 2-[(7-hydroxy-3,7-dimethyloctylidene)amino]benzoate | | methyl anthranilate / hydroxycitronellal schiff base | | methyl anthranilate / hydroxycitronellal schiff's base | | methyl N-3, 7-dimethyl-7-hydroxyoctylideneanthranilate | | methyl N-3,7-dimethyl-7-hydroxyoctylideneanthranilate | | methyl,N-3,7-dimethyl-7-hydroxyoctylidene anthranilate | | orangeol | | orantha-L-super |
Articles:
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