Category: flavoring agents and cosmetic fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless to pale yellow clear liquid (est) |
Assay: | 97.00 to 100.00 %
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 0.88700 to 0.89200 @ 25.00 °C.
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Pounds per Gallon - (est).: | 7.381 to 7.422
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Refractive Index: | 1.48800 to 1.49200 @ 20.00 °C.
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Melting Point: | -83.00 °C. @ 760.00 mm Hg
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Boiling Point: | 138.00 to 139.00 °C. @ 760.00 mm Hg
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Vapor Pressure: | 9.220000 mmHg @ 25.00 °C. |
Vapor Density: | 3.9 ( Air = 1 ) |
Flash Point: | 113.00 °F. TCC ( 45.00 °C. )
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logP (o/w): | 2.610 |
Soluble in: |
| alcohol | | ether | | water, 620.5 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Similar Items: note |
allyl disulfide |
allyl trisulfide |
Organoleptic Properties:
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Odor Type: sulfurous |
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| sulfurous onion garlic horseradish metallic |
Odor Description: at 0.10 % in propylene glycol. | sulfurous onion garlic horseradish metallic |
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| pungent sulfurous onion garlic horseradish metallic |
Odor Description:
| Pungent, sulfurous, onion-garlic and horseradish-like with a metallic nuance Mosciano, Gerard P&F 22, No. 3, 47, (1997) |
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Flavor Type: sulfurous |
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| sulfurous onion garlic vegetable radish |
Taste Description: at 2.00 ppm. | Sulfurous, onion-garlic and vegetative radish-like with a slightly hot nuance Mosciano, Gerard P&F 22, No. 3, 47, (1997) |
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Odor and/or flavor descriptions from others (if found). |
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Sigma-Aldrich |
Allyl sulfide, ≥97%, FG |
Odor Description: | horseradish; green; alliaceous (onion, garlic) |
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Cosmetic Information:
Suppliers:
Ambles Nature et Chimie |
DIALLYL SULFIDE
|
Anhui Suzhou Jinli Aromatic Chemicals |
Diallyl Sulfide
|
Augustus Oils |
Diallyl Sulphide
|
Services |
Beijing Lys Chemicals |
Allyl sulfide
|
Charkit Chemical |
ALLYL SULPHIDE FEMA 2042
|
DeLong Chemicals America |
Allyl sulfide, Kosher
|
EMD Millipore |
For experimental / research use only. |
Diallyl sulfide
|
Endeavour Specialty Chemicals |
Diallyl sulphide
|
Speciality Chemical Product Groups |
FCI SAS |
DIALLYL SULFIDE
Odor: Garlic |
Frutarom |
ALLYL SULPHIDE (DIALLYL SULPHIDE)
KOSHER Flavor: Alliaceous, Garlic, Sulphurus |
CBD Offering |
IFF |
ALLYL SULPHIDE (DIALLYL SULPHIDE)
KOSHER Flavor: Alliaceous, Garlic, Sulphurus |
Jiangyin Healthway |
Dially sulphide
|
New functional food ingredients |
Jinan Enlighten Chemical Technology(Wutong Aroma ) |
Diallyl sulfide, Kosherk
|
M&U International |
Allyl Sulfide
|
M&U International |
DIALLYL SULFIDE, Kosher
|
Penta International |
DIALLYL SULFIDE
|
R C Treatt & Co Ltd |
Diallyl Sulphide
Halal, Kosher |
Reincke & Fichtner |
Allyl Sulfide
|
Robinson Brothers |
Diallyl sulphide
|
https://www.robinsonbrothers.uk/chemistry-competences |
Santa Cruz Biotechnology |
For experimental / research use only. |
Diallyl sulfide ≥97%
|
Shijiazhuang Donglian Nankai Aroma Chemicals |
Diallyl Sulfide
Odor: Sulfur, onion, garlic,vegetable horseradish, radish and metal |
Sigma-Aldrich |
Allyl sulfide, ≥97%, FG
Odor: horseradish; green; alliaceous (onion, garlic) |
Certified Food Grade Products |
Sunaux International |
Diallyl Sulfide
|
Synerzine |
Diallyl Sulfide
|
Taytonn ASCC |
Allyl Sulphide
Odor: Alliaceous, Garlic, Sulphurous |
TCI AMERICA |
For experimental / research use only. |
Allyl Sulfide >98.0%(GC)
|
Tengzhou Jitian Aroma Chemiclal |
Allyl Sulfide
|
Tengzhou Xiang Yuan Aroma Chemicals |
Allyl Sulfide
|
United International |
Allyl Sulfide
|
WholeChem |
Allyl sulfide
|
Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | Xn - Harmful. |
R 10 - Flammable. R 20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R 36/37 - Irritating to eyes and respiratory system. S 02 - Keep out of the reach of children. S 16 - Keep away from sources of ignition - No Smoking. S 23 - Do not breath vapour. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 3/7/9 - Keep container tightly closed in a cool well-ventilated place. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
oral-rat LD50 2980 mg/kg Food and Chemical Toxicology. Vol. 26, Pg. 299, 1988.
intravenous-rabbit LD50 330 mg/kg Biochemical Journal. Vol. 4, Pg. 107, 1909.
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Dermal Toxicity: |
skin-rabbit LD50 > 5000 mg/kg Food and Chemical Toxicology. Vol. 26, Pg. 299, 1988.
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavoring agents and cosmetic fragrance agents |
IFRA Purity Specification: | < 0.1% free allyl alcohol |
Recommendation for allyl sulfide usage levels up to: | | not for fragrance use.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 15.44 (μg/capita/day) |
Maximised Survey-derived Daily Intakes (MSDI-USA): | 0.40 (μg/capita/day) |
Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 1413 (μg/person/day) |
Threshold of Concern: | 540 (μg/person/day) |
Structure Class: | II |
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 3 |
Click here to view publication 3 |
| average usual ppm | average maximum ppm |
baked goods: | - | 0.05000 |
beverages(nonalcoholic): | - | 0.04000 |
beverages(alcoholic): | - | - |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | - | - |
condiments / relishes: | - | 13.00000 |
confectionery froastings: | - | - |
egg products: | - | - |
fats / oils: | - | - |
fish products: | - | - |
frozen dairy: | - | 0.06000 |
fruit ices: | - | 0.06000 |
gelatins / puddings: | - | - |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | - | 0.07000 |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | - |
meat products: | - | 3.70000 |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | - | - |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
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Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). |
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. |
| average usage mg/kg | maximum usage mg/kg |
Dairy products, excluding products of category 02.0 (01.0): | 0.01000 | 1.00000 |
Fats and oils, and fat emulsions (type water-in-oil) (02.0): | 0.01000 | 0.50000 |
Edible ices, including sherbet and sorbet (03.0): | 0.01000 | 1.00000 |
Processed fruit (04.1): | - | - |
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | 0.01000 | 1.00000 |
Confectionery (05.0): | 0.04000 | 1.00000 |
Chewing gum (05.0): | - | - |
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 0.01000 | 0.50000 |
Bakery wares (07.0): | 7.67000 | 10.00000 |
Meat and meat products, including poultry and game (08.0): | 9.22000 | 10.00000 |
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | 0.01000 | 0.20000 |
Eggs and egg products (10.0): | 0.01000 | 0.20000 |
Sweeteners, including honey (11.0): | 0.01000 | 0.20000 |
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 8.90000 | 10.00000 |
Foodstuffs intended for particular nutritional uses (13.0): | - | - |
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | 0.01000 | 0.50000 |
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 0.01000 | 0.10000 |
Ready-to-eat savouries (15.0): | - | - |
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | 0.01000 | 0.50000 |
Safety References:
European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 8 (FGE.08)[1]: Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical group 20 View page or View pdf |
Flavouring Group Evaluation 74 (FGE.74)[1]: Consideration of Simple Aliphatic Sulphides and Thiols evaluated by JECFA (61st meeting) Structurally related to Aliphatic and Alicyclic Mono-, Di-, Tri-, and Polysulphides with or without Additional Oxygenated Functional Groups from Chemical Group 20 evaluated by EFSA in FGE.08 (2008) View page or View pdf |
Flavouring Group Evaluation 8, Revision 1 (FGE.08Rev1): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Flavouring Group Evaluation 91 (FGE.91): Consideration of simple aliphatic and aromatic sulphides and thiols evaluated by JECFA (53rd and 68th meetings) structurally related to aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups evaluated by EFSA in FGE.08Rev1 (2009) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 8, Revision 3 (FGE.08Rev3): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 74, Revision 2 (FGE.74Rev2): Consideration of Simple Aliphatic Sulphides and Thiols evaluated by the JECFA (53rd and 61st meeting) Structurally related to Aliphatic and Alicyclic Mono-, Di-, Tri-, and Polysulphides with or without Additional Oxygenated Functional Groups from Chemical Group 20 evaluated by EFSA in FGE.08Rev3 (2011) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 08, Revision 4 (FGE.08Rev4): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on the safety and efficacy of aliphatic and aromatic mono- and di-thiols and mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups (chemical group 20) when used as flavourings for all animal species View page or View pdf |
EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 74, Revision 4 (FGE.74Rev4): Consideration of aliphatic sulphides and thiols evaluated by JECFA (53rd and 61st meeting) structurally related to aliphatic and alicyclic mono-, di-, tri- and polysulphides with or without additional oxygenated functional groups from chemical group 20 evaluated by EFSA in FGE.08Rev5 View page or View pdf |
EPI System: | View |
ClinicalTrials.gov: | search |
Chemical Carcinogenesis Research Information System: | Search |
AIDS Citations: | Search |
Cancer Citations: | Search |
Toxicology Citations: | Search |
EPA Substance Registry Services (TSCA): | 592-88-1 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 11617 |
National Institute of Allergy and Infectious Diseases: | Data |
WISER: | UN 1993 |
WGK Germany: | 2 |
| 3-prop-2-enylsulfanylprop-1-ene |
Chemidplus: | 0000592881 |
RTECS: | BC4900000 for cas# 592-88-1 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| allyl monosulfide | | allyl sulfide | | allyl sulfide mix natural | | allyl sulphide (diallyl sulphide) | 3- | allylsulfanyl-propene | 3-( | allylsulfanyl)-1-propene | 3-( | allylsulfanyl)prop-1-ene | | diallyl monosulfide | | diallyl sulfide | | diallyl sulphide | | diallyl thioather | | diallyl thioether | | diallylsulfide | | diprop-2-en-1-yl sulfide | 3-( | prop-2-en-1-ylsulfanyl)prop-1-ene | 3- | prop-2-enylsulfanylprop-1-ene | 1- | prop-2-enylthioprop-2-ene | 1- | propene, 3,3'-thiobis- | 2- | propenyl sulfide | 2- | propenyl sulphide | bis(2- | propenyl) sulfide | 3,3'- | sulfanediylbis(prop-1-ene) | | sulfide, diallyl | | thioallyl ether | 3,3'- | thiobis-1-propene | 3,3- | thiobis(1-propene) | 3,3'- | thiobis(prop-1-ene) | 3,3'- | thiobispropane |
Articles:
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